Khaya Cellulose Supported Copper Nanoparticles for Chemo Selective Aza-Michael Reactions

We prepared a highly active Khaya cellulose supported poly(hydroxamic acid) copper nanoparticles by the surface modification of Khaya cellulose through graft copolymerization and subsequently amidoximation. The Cunanoparticle (0.05 mol% to 50 mol ppm) was selectively promoted Aza-Michael reaction...

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Bibliographic Details
Main Authors: Sarkar, Shaheen M., Lutfor, M. R., M. M., Yusoff
Format: Conference or Workshop Item
Language:English
Published: 2016
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/14061/
http://umpir.ump.edu.my/id/eprint/14061/1/Khaya%20Cellulose%20Supported%20Copper%20Nanoparticles%20for%20Chemo%20Selective%20Aza-Michael%20Reactions.pdf
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Summary:We prepared a highly active Khaya cellulose supported poly(hydroxamic acid) copper nanoparticles by the surface modification of Khaya cellulose through graft copolymerization and subsequently amidoximation. The Cunanoparticle (0.05 mol% to 50 mol ppm) was selectively promoted Aza-Michael reaction of aliphatic amines to give the corresponding alkylated products at room temperature in methanol. The supported nanoparticle was easy to recover and reused seven times without significance loss of its activity.