Sulfuric Disazo Dye Stabilized Copper Nanoparticle Composite Mixture: Synthesis and Characterization

Sulfuric Disazo Dye Stabilized Copper Nanoparticle Composite Mixture: Synthesis and Characterization

A copper nanoparticle–sulfuric disazo dye (Cu–SD1) composite was synthesized using the sol–gel method. Cu–SD1 nanocomposite formation was monitored by ultraviolet-visible spectroscopy (UV-vis). The acquired experimental results suggested that 8 h of reaction is needed for the synthesis Cu0 nanoparti...

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Main Authors: Huei, Ruey Ong, Hegde, Gurumurthy, Vladimir, G. Chigrinov, Khan, Maksudur R.
Format: Article
Language:English
Published: Royal Society of Chemistry 2016
Subjects:
TP Chemical technology
Online Access:http://umpir.ump.edu.my/id/eprint/13432/
http://umpir.ump.edu.my/id/eprint/13432/
http://umpir.ump.edu.my/id/eprint/13432/
http://umpir.ump.edu.my/id/eprint/13432/1/Sulfuric%20Disazo%20Dye%20Stabilized%20Copper%20Nanoparticle%20Composite%20Mixture-%20Synthesis%20and%20Characterization.pdf
id ump-13432
recordtype eprints
spelling ump-134322018-01-17T01:45:35Z http://umpir.ump.edu.my/id/eprint/13432/ Sulfuric Disazo Dye Stabilized Copper Nanoparticle Composite Mixture: Synthesis and Characterization Huei, Ruey Ong Hegde, Gurumurthy Vladimir, G. Chigrinov Khan, Maksudur R. TP Chemical technology A copper nanoparticle–sulfuric disazo dye (Cu–SD1) composite was synthesized using the sol–gel method. Cu–SD1 nanocomposite formation was monitored by ultraviolet-visible spectroscopy (UV-vis). The acquired experimental results suggested that 8 h of reaction is needed for the synthesis Cu0 nanoparticles. Transmission electron microcopy (TEM) and atomic force microscopy (AFM) were employed to elucidate the morphology of the Cu–SD1 nanocomposite. It was found that the diameter of particle sizes were in the range of 2–4 nm. The interaction of SD1 with copper was confirmed by Fourier transform infrared spectroscopy (FTIR). The peak shift of O–H and C–OH functional groups indicated the interaction between SD1 and copper nanoparticles. Moreover, the azo group (N[double bond, length as m-dash]N) peaks were suppressed after the formation of the nanocomposite, suggesting that a strong linkage was formed between the functional groups and the copper nanoparticles. The surface composition and chemical states of the as-synthesized copper nanoparticles were elucidated by X-ray photoelectron spectroscopy (XPS). In addition, photo-switching of the composites was elucidated in the solution state. It was found that the Cu–SD1 nanocomposite has a faster switching response compared to the parent, SD1, in a solution. Royal Society of Chemistry 2016 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/13432/1/Sulfuric%20Disazo%20Dye%20Stabilized%20Copper%20Nanoparticle%20Composite%20Mixture-%20Synthesis%20and%20Characterization.pdf Huei, Ruey Ong and Hegde, Gurumurthy and Vladimir, G. Chigrinov and Khan, Maksudur R. (2016) Sulfuric Disazo Dye Stabilized Copper Nanoparticle Composite Mixture: Synthesis and Characterization. RSC Advances, 6 (18). pp. 15094-15100. ISSN 2046-2069 http://pubs.rsc.org/is/content/articlelanding/2016/ra/c5ra26492h/unauth#!divAbstract DOI: 10.1039/C5RA26492H
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
topic TP Chemical technology
spellingShingle TP Chemical technology
Huei, Ruey Ong
Hegde, Gurumurthy
Vladimir, G. Chigrinov
Khan, Maksudur R.
Sulfuric Disazo Dye Stabilized Copper Nanoparticle Composite Mixture: Synthesis and Characterization
description A copper nanoparticle–sulfuric disazo dye (Cu–SD1) composite was synthesized using the sol–gel method. Cu–SD1 nanocomposite formation was monitored by ultraviolet-visible spectroscopy (UV-vis). The acquired experimental results suggested that 8 h of reaction is needed for the synthesis Cu0 nanoparticles. Transmission electron microcopy (TEM) and atomic force microscopy (AFM) were employed to elucidate the morphology of the Cu–SD1 nanocomposite. It was found that the diameter of particle sizes were in the range of 2–4 nm. The interaction of SD1 with copper was confirmed by Fourier transform infrared spectroscopy (FTIR). The peak shift of O–H and C–OH functional groups indicated the interaction between SD1 and copper nanoparticles. Moreover, the azo group (N[double bond, length as m-dash]N) peaks were suppressed after the formation of the nanocomposite, suggesting that a strong linkage was formed between the functional groups and the copper nanoparticles. The surface composition and chemical states of the as-synthesized copper nanoparticles were elucidated by X-ray photoelectron spectroscopy (XPS). In addition, photo-switching of the composites was elucidated in the solution state. It was found that the Cu–SD1 nanocomposite has a faster switching response compared to the parent, SD1, in a solution.
format Article
author Huei, Ruey Ong
Hegde, Gurumurthy
Vladimir, G. Chigrinov
Khan, Maksudur R.
author_facet Huei, Ruey Ong
Hegde, Gurumurthy
Vladimir, G. Chigrinov
Khan, Maksudur R.
author_sort Huei, Ruey Ong
title Sulfuric Disazo Dye Stabilized Copper Nanoparticle Composite Mixture: Synthesis and Characterization
title_short Sulfuric Disazo Dye Stabilized Copper Nanoparticle Composite Mixture: Synthesis and Characterization
title_full Sulfuric Disazo Dye Stabilized Copper Nanoparticle Composite Mixture: Synthesis and Characterization
title_fullStr Sulfuric Disazo Dye Stabilized Copper Nanoparticle Composite Mixture: Synthesis and Characterization
title_full_unstemmed Sulfuric Disazo Dye Stabilized Copper Nanoparticle Composite Mixture: Synthesis and Characterization
title_sort sulfuric disazo dye stabilized copper nanoparticle composite mixture: synthesis and characterization
publisher Royal Society of Chemistry
publishDate 2016
url http://umpir.ump.edu.my/id/eprint/13432/
http://umpir.ump.edu.my/id/eprint/13432/
http://umpir.ump.edu.my/id/eprint/13432/
http://umpir.ump.edu.my/id/eprint/13432/1/Sulfuric%20Disazo%20Dye%20Stabilized%20Copper%20Nanoparticle%20Composite%20Mixture-%20Synthesis%20and%20Characterization.pdf
first_indexed 2023-09-18T22:16:03Z
last_indexed 2023-09-18T22:16:03Z
_version_ 1777415344858595328

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