Pyridinyl Functionalized MCM-48 Supported Highly Active Heterogeneous Palladium Catalyst for Crosscoupling Reactions

Pyridinyl Functionalized MCM-48 Supported Highly Active Heterogeneous Palladium Catalyst for Crosscoupling Reactions

An MCM-48 supported 2-pyridinylmethanimine Pd-catalyst was found to be a highly efficient catalyst in the Mizoroki–Heck, Suzuki–Miyaura and copper-free Sonogashira cross-coupling reactions of aryl halides under aqueous reaction conditions. The catalyst efficiently promoted these coupling reactions...

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Main Authors: Sarkar, Shaheen M., Lutfor, M. R., M. M., Yusoff
Format: Article
Language:English
Published: Royal Society of Chemistry 2015
Subjects:
QD Chemistry
Online Access:http://umpir.ump.edu.my/id/eprint/12769/
http://umpir.ump.edu.my/id/eprint/12769/
http://umpir.ump.edu.my/id/eprint/12769/
http://umpir.ump.edu.my/id/eprint/12769/1/RSC%20Adv%20MCM-48.pdf
id ump-12769
recordtype eprints
spelling ump-127692018-02-14T04:08:29Z http://umpir.ump.edu.my/id/eprint/12769/ Pyridinyl Functionalized MCM-48 Supported Highly Active Heterogeneous Palladium Catalyst for Crosscoupling Reactions Sarkar, Shaheen M. Lutfor, M. R. M. M., Yusoff QD Chemistry An MCM-48 supported 2-pyridinylmethanimine Pd-catalyst was found to be a highly efficient catalyst in the Mizoroki–Heck, Suzuki–Miyaura and copper-free Sonogashira cross-coupling reactions of aryl halides under aqueous reaction conditions. The catalyst efficiently promoted these coupling reactions with ppm levels of palladium to afford the corresponding coupling products in up to 98% yield. The supported Pdcatalyst was readily recovered and reused several times without significant loss of its catalytic activity. Royal Society of Chemistry 2015 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/12769/1/RSC%20Adv%20MCM-48.pdf Sarkar, Shaheen M. and Lutfor, M. R. and M. M., Yusoff (2015) Pyridinyl Functionalized MCM-48 Supported Highly Active Heterogeneous Palladium Catalyst for Crosscoupling Reactions. RSC Advances, 5 (25). pp. 19630-19637. ISSN 2046-2069 http://dx.doi.org/10.1039/C4RA16677A DOI: 10.1039/C4RA16677A
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
topic QD Chemistry
spellingShingle QD Chemistry
Sarkar, Shaheen M.
Lutfor, M. R.
M. M., Yusoff
Pyridinyl Functionalized MCM-48 Supported Highly Active Heterogeneous Palladium Catalyst for Crosscoupling Reactions
description An MCM-48 supported 2-pyridinylmethanimine Pd-catalyst was found to be a highly efficient catalyst in the Mizoroki–Heck, Suzuki–Miyaura and copper-free Sonogashira cross-coupling reactions of aryl halides under aqueous reaction conditions. The catalyst efficiently promoted these coupling reactions with ppm levels of palladium to afford the corresponding coupling products in up to 98% yield. The supported Pdcatalyst was readily recovered and reused several times without significant loss of its catalytic activity.
format Article
author Sarkar, Shaheen M.
Lutfor, M. R.
M. M., Yusoff
author_facet Sarkar, Shaheen M.
Lutfor, M. R.
M. M., Yusoff
author_sort Sarkar, Shaheen M.
title Pyridinyl Functionalized MCM-48 Supported Highly Active Heterogeneous Palladium Catalyst for Crosscoupling Reactions
title_short Pyridinyl Functionalized MCM-48 Supported Highly Active Heterogeneous Palladium Catalyst for Crosscoupling Reactions
title_full Pyridinyl Functionalized MCM-48 Supported Highly Active Heterogeneous Palladium Catalyst for Crosscoupling Reactions
title_fullStr Pyridinyl Functionalized MCM-48 Supported Highly Active Heterogeneous Palladium Catalyst for Crosscoupling Reactions
title_full_unstemmed Pyridinyl Functionalized MCM-48 Supported Highly Active Heterogeneous Palladium Catalyst for Crosscoupling Reactions
title_sort pyridinyl functionalized mcm-48 supported highly active heterogeneous palladium catalyst for crosscoupling reactions
publisher Royal Society of Chemistry
publishDate 2015
url http://umpir.ump.edu.my/id/eprint/12769/
http://umpir.ump.edu.my/id/eprint/12769/
http://umpir.ump.edu.my/id/eprint/12769/
http://umpir.ump.edu.my/id/eprint/12769/1/RSC%20Adv%20MCM-48.pdf
first_indexed 2023-09-18T22:14:41Z
last_indexed 2023-09-18T22:14:41Z
_version_ 1777415258159185920

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