Heck, Suzuki and Sonogashira Cross-coupling Reactions using ppm level of SBA-16 supported Pd-complex
SBA-16 supported 1,2-diaminocyclohexane Pd-complex (100–500 mol ppm of Pd) was found to be an efficient catalyst in the palladium-catalyzed Mizoroki–Heck, Suzuki–Miyaura and copper-free Sonogashira cross-coupling reactions of aryl halides under mild reaction conditions. The Pd-complex efficiently pr...
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Royal Society of Chemistry
2015
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ump-127682018-02-14T04:00:41Z http://umpir.ump.edu.my/id/eprint/12768/ Heck, Suzuki and Sonogashira Cross-coupling Reactions using ppm level of SBA-16 supported Pd-complex Sarkar, Shaheen M. Lutfor, M. R. M. M., Yusoff QD Chemistry SBA-16 supported 1,2-diaminocyclohexane Pd-complex (100–500 mol ppm of Pd) was found to be an efficient catalyst in the palladium-catalyzed Mizoroki–Heck, Suzuki–Miyaura and copper-free Sonogashira cross-coupling reactions of aryl halides under mild reaction conditions. The Pd-complex efficiently promoted all of these coupling reactions with appropriate coupling partners to afford the corresponding coupling products with almost quantitative yield. The supported Pd-complex was readily recovered and used five times without a significant loss of its catalytic activity. Royal Society of Chemistry 2015 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/12768/1/New%20J%20Chem.pdf Sarkar, Shaheen M. and Lutfor, M. R. and M. M., Yusoff (2015) Heck, Suzuki and Sonogashira Cross-coupling Reactions using ppm level of SBA-16 supported Pd-complex. New Journal of Chemistry, 39 (5). pp. 3564-3570. ISSN 1144-0546 http://dx.doi.org/10.1039/C4NJ02319F DOI: 10.1039/C4NJ02319F |
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QD Chemistry Sarkar, Shaheen M. Lutfor, M. R. M. M., Yusoff Heck, Suzuki and Sonogashira Cross-coupling Reactions using ppm level of SBA-16 supported Pd-complex |
description |
SBA-16 supported 1,2-diaminocyclohexane Pd-complex (100–500 mol ppm of Pd) was found to be an efficient catalyst in the palladium-catalyzed Mizoroki–Heck, Suzuki–Miyaura and copper-free Sonogashira cross-coupling reactions of aryl halides under mild reaction conditions. The Pd-complex efficiently promoted all of these coupling reactions with appropriate coupling partners to afford the corresponding
coupling products with almost quantitative yield. The supported Pd-complex was readily recovered and
used five times without a significant loss of its catalytic activity. |
format |
Article |
author |
Sarkar, Shaheen M. Lutfor, M. R. M. M., Yusoff |
author_facet |
Sarkar, Shaheen M. Lutfor, M. R. M. M., Yusoff |
author_sort |
Sarkar, Shaheen M. |
title |
Heck, Suzuki and Sonogashira Cross-coupling Reactions using ppm level of SBA-16 supported Pd-complex |
title_short |
Heck, Suzuki and Sonogashira Cross-coupling Reactions using ppm level of SBA-16 supported Pd-complex |
title_full |
Heck, Suzuki and Sonogashira Cross-coupling Reactions using ppm level of SBA-16 supported Pd-complex |
title_fullStr |
Heck, Suzuki and Sonogashira Cross-coupling Reactions using ppm level of SBA-16 supported Pd-complex |
title_full_unstemmed |
Heck, Suzuki and Sonogashira Cross-coupling Reactions using ppm level of SBA-16 supported Pd-complex |
title_sort |
heck, suzuki and sonogashira cross-coupling reactions using ppm level of sba-16 supported pd-complex |
publisher |
Royal Society of Chemistry |
publishDate |
2015 |
url |
http://umpir.ump.edu.my/id/eprint/12768/ http://umpir.ump.edu.my/id/eprint/12768/ http://umpir.ump.edu.my/id/eprint/12768/ http://umpir.ump.edu.my/id/eprint/12768/1/New%20J%20Chem.pdf |
first_indexed |
2023-09-18T22:14:41Z |
last_indexed |
2023-09-18T22:14:41Z |
_version_ |
1777415258013433856 |