Solid State Perovskite Solar Modules by Vacuum-vapor Assisted Sequential Deposition on Nd:YVO4 Laser Patterned Rutile TiO2 Nanorods

The past few years have witnessed remarkable progress in solution-processed methylammonium lead halide (CH3NH3PbX3,X - halide) perovskite solar cells (PSCs) with reported photoconversion efﬁciency (η) exceeding 20% in laboratory-scale devices and reaching up to 13% in their large area perovskite sol...

Full description

Bibliographic Details
Main Authors:	Azhar, Fakharuddin, Palma, Alessandro L., Giacomo, Francesco Di, Casaluci, Simone, Matteocci, Fabio, Wali, Qamar, Rauf, Muhammad, Carlo, Aldo Di, Brown, Thomas M., Rajan, Jose
Format:	Article
Language:	English
Published:	IOP Publishing Ltd 2015
Subjects:	QC Physics TK Electrical engineering. Electronics Nuclear engineering
Online Access:	http://umpir.ump.edu.my/id/eprint/12564/ http://umpir.ump.edu.my/id/eprint/12564/ http://umpir.ump.edu.my/id/eprint/12564/ http://umpir.ump.edu.my/id/eprint/12564/1/Solid%20State%20Perovskite%20Solar%20Modules%20By%20Vacuum-Vapor%20Assisted%20Sequential%20Deposition%20On%20Nd-Yvo4%20Laser%20Patterned%20Rutile%20TiO2%20Nanorods.pdf

id	ump-12564
recordtype	eprints
spelling	ump-125642018-02-08T01:18:07Z http://umpir.ump.edu.my/id/eprint/12564/ Solid State Perovskite Solar Modules by Vacuum-vapor Assisted Sequential Deposition on Nd:YVO4 Laser Patterned Rutile TiO2 Nanorods Azhar, Fakharuddin Palma, Alessandro L. Giacomo, Francesco Di Casaluci, Simone Matteocci, Fabio Wali, Qamar Rauf, Muhammad Carlo, Aldo Di Brown, Thomas M. Rajan, Jose QC Physics TK Electrical engineering. Electronics Nuclear engineering The past few years have witnessed remarkable progress in solution-processed methylammonium lead halide (CH3NH3PbX3,X - halide) perovskite solar cells (PSCs) with reported photoconversion efﬁciency (η) exceeding 20% in laboratory-scale devices and reaching up to 13% in their large area perovskite solar modules (PSMs). These devices mostly employ mesoporous TiO2 nanoparticles (NPs) as an electron transport layer (ETL) which provides a scaffold on which the perovskite semiconductor can grow. However, limitations exist which are due to trap-limited electron transport and non-complete pore ﬁlling. Herein, we have employed TiO2 nanorods (NRs), a material offering a two-fold higher electronic mobility and higher poreﬁling compared to their particle analogues, as an ETL. A crucial issue in NRs’ patterning over substrates is resolved by using precise Nd:YVO4 laser ablation, and a champion device with η∼8.1% is reported via a simple and low cost vacuum-vapor assisted sequential processing (VVASP) of a CH3NH3PbI3 ﬁlm. Our experiments showed a successful demonstration of NRsbased PSMs via the V-VASP technique which can be applied to fabricate large area modules with a pin-hole free, smooth and dense perovskite layer which is required to build high efﬁciency devices. IOP Publishing Ltd 2015-11-17 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/12564/1/Solid%20State%20Perovskite%20Solar%20Modules%20By%20Vacuum-Vapor%20Assisted%20Sequential%20Deposition%20On%20Nd-Yvo4%20Laser%20Patterned%20Rutile%20TiO2%20Nanorods.pdf Azhar, Fakharuddin and Palma, Alessandro L. and Giacomo, Francesco Di and Casaluci, Simone and Matteocci, Fabio and Wali, Qamar and Rauf, Muhammad and Carlo, Aldo Di and Brown, Thomas M. and Rajan, Jose (2015) Solid State Perovskite Solar Modules by Vacuum-vapor Assisted Sequential Deposition on Nd:YVO4 Laser Patterned Rutile TiO2 Nanorods. Nanotechnology, 26. 494002 . ISSN 09574484 http://dx.doi.org/10.1088/0957-4484/26/49/494002 DOI: 10.1088/0957-4484/26/49/494002
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	QC Physics TK Electrical engineering. Electronics Nuclear engineering
spellingShingle	QC Physics TK Electrical engineering. Electronics Nuclear engineering Azhar, Fakharuddin Palma, Alessandro L. Giacomo, Francesco Di Casaluci, Simone Matteocci, Fabio Wali, Qamar Rauf, Muhammad Carlo, Aldo Di Brown, Thomas M. Rajan, Jose Solid State Perovskite Solar Modules by Vacuum-vapor Assisted Sequential Deposition on Nd:YVO4 Laser Patterned Rutile TiO2 Nanorods
description	The past few years have witnessed remarkable progress in solution-processed methylammonium lead halide (CH3NH3PbX3,X - halide) perovskite solar cells (PSCs) with reported photoconversion efﬁciency (η) exceeding 20% in laboratory-scale devices and reaching up to 13% in their large area perovskite solar modules (PSMs). These devices mostly employ mesoporous TiO2 nanoparticles (NPs) as an electron transport layer (ETL) which provides a scaffold on which the perovskite semiconductor can grow. However, limitations exist which are due to trap-limited electron transport and non-complete pore ﬁlling. Herein, we have employed TiO2 nanorods (NRs), a material offering a two-fold higher electronic mobility and higher poreﬁling compared to their particle analogues, as an ETL. A crucial issue in NRs’ patterning over substrates is resolved by using precise Nd:YVO4 laser ablation, and a champion device with η∼8.1% is reported via a simple and low cost vacuum-vapor assisted sequential processing (VVASP) of a CH3NH3PbI3 ﬁlm. Our experiments showed a successful demonstration of NRsbased PSMs via the V-VASP technique which can be applied to fabricate large area modules with a pin-hole free, smooth and dense perovskite layer which is required to build high efﬁciency devices.
format	Article
author	Azhar, Fakharuddin Palma, Alessandro L. Giacomo, Francesco Di Casaluci, Simone Matteocci, Fabio Wali, Qamar Rauf, Muhammad Carlo, Aldo Di Brown, Thomas M. Rajan, Jose
author_facet	Azhar, Fakharuddin Palma, Alessandro L. Giacomo, Francesco Di Casaluci, Simone Matteocci, Fabio Wali, Qamar Rauf, Muhammad Carlo, Aldo Di Brown, Thomas M. Rajan, Jose
author_sort	Azhar, Fakharuddin
title	Solid State Perovskite Solar Modules by Vacuum-vapor Assisted Sequential Deposition on Nd:YVO4 Laser Patterned Rutile TiO2 Nanorods
title_short	Solid State Perovskite Solar Modules by Vacuum-vapor Assisted Sequential Deposition on Nd:YVO4 Laser Patterned Rutile TiO2 Nanorods
title_full	Solid State Perovskite Solar Modules by Vacuum-vapor Assisted Sequential Deposition on Nd:YVO4 Laser Patterned Rutile TiO2 Nanorods
title_fullStr	Solid State Perovskite Solar Modules by Vacuum-vapor Assisted Sequential Deposition on Nd:YVO4 Laser Patterned Rutile TiO2 Nanorods
title_full_unstemmed	Solid State Perovskite Solar Modules by Vacuum-vapor Assisted Sequential Deposition on Nd:YVO4 Laser Patterned Rutile TiO2 Nanorods
title_sort	solid state perovskite solar modules by vacuum-vapor assisted sequential deposition on nd:yvo4 laser patterned rutile tio2 nanorods
publisher	IOP Publishing Ltd
publishDate	2015
url	http://umpir.ump.edu.my/id/eprint/12564/ http://umpir.ump.edu.my/id/eprint/12564/ http://umpir.ump.edu.my/id/eprint/12564/ http://umpir.ump.edu.my/id/eprint/12564/1/Solid%20State%20Perovskite%20Solar%20Modules%20By%20Vacuum-Vapor%20Assisted%20Sequential%20Deposition%20On%20Nd-Yvo4%20Laser%20Patterned%20Rutile%20TiO2%20Nanorods.pdf
first_indexed	2023-09-18T22:14:20Z
last_indexed	2023-09-18T22:14:20Z
_version_	1777415236524965888

Solid State Perovskite Solar Modules by Vacuum-vapor Assisted Sequential Deposition on Nd:YVO4 Laser Patterned Rutile TiO2 Nanorods

Similar Items