Characterization of Plasticized CMC-NH4BR Based Biopolymer Electrolyte and Electrochemical Studies on the Solid-State Batteries

Much research has been devoted to the preparation of solid polymer electrolytes made of various materials. Some of the wellknown are synthetic polymer materials (petroleum resources) but these polymers are high in cost and the depletion of petroleum resources coupled with increasing environmental...

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Main Authors:	M. I. N., Isa, A. S., Samsudin
Format:	Conference or Workshop Item
Language:	English
Published:	2015
Subjects:	Q Science (General)
Online Access:	http://umpir.ump.edu.my/id/eprint/11164/ http://umpir.ump.edu.my/id/eprint/11164/1/Characterization%20Of%20Plasticized%20Cmc-Nh4br%20Based%20Biopolymer%20Electrolyte%20And%20Electrochemical%20Studies%20On%20The%20Solid-State%20Batteries.pdf

id	ump-11164
recordtype	eprints
spelling	ump-111642015-11-24T03:58:35Z http://umpir.ump.edu.my/id/eprint/11164/ Characterization of Plasticized CMC-NH4BR Based Biopolymer Electrolyte and Electrochemical Studies on the Solid-State Batteries M. I. N., Isa A. S., Samsudin Q Science (General) Much research has been devoted to the preparation of solid polymer electrolytes made of various materials. Some of the wellknown are synthetic polymer materials (petroleum resources) but these polymers are high in cost and the depletion of petroleum resources coupled with increasing environmental regulation. For these reasons, a lot of effort has been made to develop the electrolytes using natural biopolymer materials. The increasing interest in green energy storage materials for electrochemical devices with the development of polymer as electrolytes candidate has attracted great attention recently. It can offer a number of high-value opportunities, provided that lower costs can be obtained besides environmental friendly. Due to this matter, the development of plasticized biodegradable polymer electrolytes (BPEs) has been accomplished in this work by incorporating various composition of EC with carboxy methylcellulose doped NH4Br via solution casting method. The plasticized polymer– salt complex formation and ionic conduction of BPEs have been analyzed through infrared spectroscopy and impedance measurement. Plasticization using EC in BPEs system helps the enhancement of NH4Br dissociation and therefore increases the protonation process in the system. The highest ionic conductivity obtained for CMC−NH4Br containing with 25 wt. % NH4Br was achieved at 1.12 x 10-4 S cm-1 and enhanced to 3.31 x 10-3 S cm-1 with addition of EC. The conductivity-temperature for BPEs system obeys the Arrhenius relation where the ionic conductivity increases with temperature. The electrochemical cell were fabricated with the configuration of Zn + ZnSO4.7H2O \| BPEs system \| MnO2 for the highest conductivity and produced a maximum open circuit voltage of 1.48 V at ambient temperature and showed good rechargeability. 2015 Conference or Workshop Item PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/11164/1/Characterization%20Of%20Plasticized%20Cmc-Nh4br%20Based%20Biopolymer%20Electrolyte%20And%20Electrochemical%20Studies%20On%20The%20Solid-State%20Batteries.pdf M. I. N., Isa and A. S., Samsudin (2015) Characterization of Plasticized CMC-NH4BR Based Biopolymer Electrolyte and Electrochemical Studies on the Solid-State Batteries. In: 5th International Conference on Functional Materials and Devices (ICFMD 2015), 4-6 Aug 2015 , Johor Bahru. . (Unpublished)
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	Q Science (General)
spellingShingle	Q Science (General) M. I. N., Isa A. S., Samsudin Characterization of Plasticized CMC-NH4BR Based Biopolymer Electrolyte and Electrochemical Studies on the Solid-State Batteries
description	Much research has been devoted to the preparation of solid polymer electrolytes made of various materials. Some of the wellknown are synthetic polymer materials (petroleum resources) but these polymers are high in cost and the depletion of petroleum resources coupled with increasing environmental regulation. For these reasons, a lot of effort has been made to develop the electrolytes using natural biopolymer materials. The increasing interest in green energy storage materials for electrochemical devices with the development of polymer as electrolytes candidate has attracted great attention recently. It can offer a number of high-value opportunities, provided that lower costs can be obtained besides environmental friendly. Due to this matter, the development of plasticized biodegradable polymer electrolytes (BPEs) has been accomplished in this work by incorporating various composition of EC with carboxy methylcellulose doped NH4Br via solution casting method. The plasticized polymer– salt complex formation and ionic conduction of BPEs have been analyzed through infrared spectroscopy and impedance measurement. Plasticization using EC in BPEs system helps the enhancement of NH4Br dissociation and therefore increases the protonation process in the system. The highest ionic conductivity obtained for CMC−NH4Br containing with 25 wt. % NH4Br was achieved at 1.12 x 10-4 S cm-1 and enhanced to 3.31 x 10-3 S cm-1 with addition of EC. The conductivity-temperature for BPEs system obeys the Arrhenius relation where the ionic conductivity increases with temperature. The electrochemical cell were fabricated with the configuration of Zn + ZnSO4.7H2O \| BPEs system \| MnO2 for the highest conductivity and produced a maximum open circuit voltage of 1.48 V at ambient temperature and showed good rechargeability.
format	Conference or Workshop Item
author	M. I. N., Isa A. S., Samsudin
author_facet	M. I. N., Isa A. S., Samsudin
author_sort	M. I. N., Isa
title	Characterization of Plasticized CMC-NH4BR Based Biopolymer Electrolyte and Electrochemical Studies on the Solid-State Batteries
title_short	Characterization of Plasticized CMC-NH4BR Based Biopolymer Electrolyte and Electrochemical Studies on the Solid-State Batteries
title_full	Characterization of Plasticized CMC-NH4BR Based Biopolymer Electrolyte and Electrochemical Studies on the Solid-State Batteries
title_fullStr	Characterization of Plasticized CMC-NH4BR Based Biopolymer Electrolyte and Electrochemical Studies on the Solid-State Batteries
title_full_unstemmed	Characterization of Plasticized CMC-NH4BR Based Biopolymer Electrolyte and Electrochemical Studies on the Solid-State Batteries
title_sort	characterization of plasticized cmc-nh4br based biopolymer electrolyte and electrochemical studies on the solid-state batteries
publishDate	2015
url	http://umpir.ump.edu.my/id/eprint/11164/ http://umpir.ump.edu.my/id/eprint/11164/1/Characterization%20Of%20Plasticized%20Cmc-Nh4br%20Based%20Biopolymer%20Electrolyte%20And%20Electrochemical%20Studies%20On%20The%20Solid-State%20Batteries.pdf
first_indexed	2023-09-18T22:11:37Z
last_indexed	2023-09-18T22:11:37Z
_version_	1777415065800015872

Characterization of Plasticized CMC-NH4BR Based Biopolymer Electrolyte and Electrochemical Studies on the Solid-State Batteries

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