Tailoring Base Catalyzed Synthesis of Palm Oil Based Alkyd Resin Through CuO Nanoparticles

Tailoring Base Catalyzed Synthesis of Palm Oil Based Alkyd Resin Through CuO Nanoparticles

Palm oil based alkyd resin was synthesized by an alcoholysis–polyesterification process over a base catalyst tailored by copper oxide (CuO) nanoparticles. In the present paper we synthesized CuO sol in glycerol and subsequently used it in alkyd resin synthesis. The formation of the alkyd resin was c...

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Main Authors: Ong, Huei Ruey, Khan, Maksudur R., Ridzuan, Ramli, Rahman, Md. Wasikur, R. M., Yunus
Format: Article
Language:English
Published: Royal Society of Chemistry 2015
Subjects:
TP Chemical technology
Online Access:http://umpir.ump.edu.my/id/eprint/11128/
http://umpir.ump.edu.my/id/eprint/11128/
http://umpir.ump.edu.my/id/eprint/11128/
http://umpir.ump.edu.my/id/eprint/11128/1/Tailoring%20Base%20Catalyzed%20Synthesis%20of%20Palm%20Oil%20Based%20Alkyd%20Resin%20Through%20CuO%20Nanoparticles.pdf
id ump-11128
recordtype eprints
spelling ump-111282018-01-15T02:04:47Z http://umpir.ump.edu.my/id/eprint/11128/ Tailoring Base Catalyzed Synthesis of Palm Oil Based Alkyd Resin Through CuO Nanoparticles Ong, Huei Ruey Khan, Maksudur R. Ridzuan, Ramli Rahman, Md. Wasikur R. M., Yunus TP Chemical technology Palm oil based alkyd resin was synthesized by an alcoholysis–polyesterification process over a base catalyst tailored by copper oxide (CuO) nanoparticles. In the present paper we synthesized CuO sol in glycerol and subsequently used it in alkyd resin synthesis. The formation of the alkyd resin was confirmed by FTIR, Raman, 1H-NMR and 13C-NMR methods and its molecular weight was determined by gel permeation chromatography (GPC). The antimicrobial activity of the pseudo-homogeneous additive was determined via the Kirby–Bauer method and the stability of the CuO was determined by X-ray absorption near edge structure spectroscopy (XANES). The addition of CuO nano-sol to the conventional homogeneous base catalyzed system explored a new catalytic route for the preparation of bioresin from vegetable oil, reducing the reaction time as well as adding antimicrobial properties to the resin. Royal Society of Chemistry 2015 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/11128/1/Tailoring%20Base%20Catalyzed%20Synthesis%20of%20Palm%20Oil%20Based%20Alkyd%20Resin%20Through%20CuO%20Nanoparticles.pdf Ong, Huei Ruey and Khan, Maksudur R. and Ridzuan, Ramli and Rahman, Md. Wasikur and R. M., Yunus (2015) Tailoring Base Catalyzed Synthesis of Palm Oil Based Alkyd Resin Through CuO Nanoparticles. RSC Advances, 5 (116). pp. 95894-95902. ISSN 2046-2069 http://dx.doi.org/10.1039/C5RA19575F DOI: 10.1039/C5RA19575F
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
topic TP Chemical technology
spellingShingle TP Chemical technology
Ong, Huei Ruey
Khan, Maksudur R.
Ridzuan, Ramli
Rahman, Md. Wasikur
R. M., Yunus
Tailoring Base Catalyzed Synthesis of Palm Oil Based Alkyd Resin Through CuO Nanoparticles
description Palm oil based alkyd resin was synthesized by an alcoholysis–polyesterification process over a base catalyst tailored by copper oxide (CuO) nanoparticles. In the present paper we synthesized CuO sol in glycerol and subsequently used it in alkyd resin synthesis. The formation of the alkyd resin was confirmed by FTIR, Raman, 1H-NMR and 13C-NMR methods and its molecular weight was determined by gel permeation chromatography (GPC). The antimicrobial activity of the pseudo-homogeneous additive was determined via the Kirby–Bauer method and the stability of the CuO was determined by X-ray absorption near edge structure spectroscopy (XANES). The addition of CuO nano-sol to the conventional homogeneous base catalyzed system explored a new catalytic route for the preparation of bioresin from vegetable oil, reducing the reaction time as well as adding antimicrobial properties to the resin.
format Article
author Ong, Huei Ruey
Khan, Maksudur R.
Ridzuan, Ramli
Rahman, Md. Wasikur
R. M., Yunus
author_facet Ong, Huei Ruey
Khan, Maksudur R.
Ridzuan, Ramli
Rahman, Md. Wasikur
R. M., Yunus
author_sort Ong, Huei Ruey
title Tailoring Base Catalyzed Synthesis of Palm Oil Based Alkyd Resin Through CuO Nanoparticles
title_short Tailoring Base Catalyzed Synthesis of Palm Oil Based Alkyd Resin Through CuO Nanoparticles
title_full Tailoring Base Catalyzed Synthesis of Palm Oil Based Alkyd Resin Through CuO Nanoparticles
title_fullStr Tailoring Base Catalyzed Synthesis of Palm Oil Based Alkyd Resin Through CuO Nanoparticles
title_full_unstemmed Tailoring Base Catalyzed Synthesis of Palm Oil Based Alkyd Resin Through CuO Nanoparticles
title_sort tailoring base catalyzed synthesis of palm oil based alkyd resin through cuo nanoparticles
publisher Royal Society of Chemistry
publishDate 2015
url http://umpir.ump.edu.my/id/eprint/11128/
http://umpir.ump.edu.my/id/eprint/11128/
http://umpir.ump.edu.my/id/eprint/11128/
http://umpir.ump.edu.my/id/eprint/11128/1/Tailoring%20Base%20Catalyzed%20Synthesis%20of%20Palm%20Oil%20Based%20Alkyd%20Resin%20Through%20CuO%20Nanoparticles.pdf
first_indexed 2023-09-18T22:11:33Z
last_indexed 2023-09-18T22:11:33Z
_version_ 1777415061622489088

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