Study of structural and luminescence properties of lead lithium borophosphate glass system doped with Ti Ions

Study of a series of lead lithium borophosphate glass samples was performed to determine the structural and luminescence properties. The glass samples containing the composition of 20PbO-xLi2O-30B2O3-(50-x)P2O5-2TiO2 (where x = 0, 5, 10, 15, 20) system were prepared using melt-quenching technique. T...

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Main Authors: T.Q., Leow, P.M., Leong, T.Y., Eeu, Ibrahim, Z., Hussin, R.
Format: Article
Language:English
Published: Universiti Kebangsaan Malaysia 2014
Online Access:http://journalarticle.ukm.my/7184/
http://journalarticle.ukm.my/7184/
http://journalarticle.ukm.my/7184/1/17_T.Q._Leow.pdf
id ukm-7184
recordtype eprints
spelling ukm-71842016-12-14T06:43:20Z http://journalarticle.ukm.my/7184/ Study of structural and luminescence properties of lead lithium borophosphate glass system doped with Ti Ions T.Q., Leow P.M., Leong T.Y., Eeu Ibrahim, Z. Hussin, R. Study of a series of lead lithium borophosphate glass samples was performed to determine the structural and luminescence properties. The glass samples containing the composition of 20PbO-xLi2O-30B2O3-(50-x)P2O5-2TiO2 (where x = 0, 5, 10, 15, 20) system were prepared using melt-quenching technique. The PbO-Li2O-B2O3-P2O5-TiO2 samples were investigated for structural properties using Fourier transform infrared and photoluminescence spectroscopy for studies of luminescence properties. The results from FT-IR showed the presence of trigonal and tetrahedral PO4, PO3, BO4 and BO3 groups within the host network structure. The samples exhibit luminescence emission centered at 420, 482 and 496 nm when excited at 300 nm wavelength. The emission peak at 420 nm were assigned to F center emission and charge-transfer transition of Ti4+ ions. The results showed that emission intensity was dependent on lithium contents in Ti-doped lead lithium borophosphate glass composition. Universiti Kebangsaan Malaysia 2014-06 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/7184/1/17_T.Q._Leow.pdf T.Q., Leow and P.M., Leong and T.Y., Eeu and Ibrahim, Z. and Hussin, R. (2014) Study of structural and luminescence properties of lead lithium borophosphate glass system doped with Ti Ions. Sains Malaysiana, 43 (6). pp. 929-934. ISSN 0126-6039 http://www.ukm.my/jsm/
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language English
description Study of a series of lead lithium borophosphate glass samples was performed to determine the structural and luminescence properties. The glass samples containing the composition of 20PbO-xLi2O-30B2O3-(50-x)P2O5-2TiO2 (where x = 0, 5, 10, 15, 20) system were prepared using melt-quenching technique. The PbO-Li2O-B2O3-P2O5-TiO2 samples were investigated for structural properties using Fourier transform infrared and photoluminescence spectroscopy for studies of luminescence properties. The results from FT-IR showed the presence of trigonal and tetrahedral PO4, PO3, BO4 and BO3 groups within the host network structure. The samples exhibit luminescence emission centered at 420, 482 and 496 nm when excited at 300 nm wavelength. The emission peak at 420 nm were assigned to F center emission and charge-transfer transition of Ti4+ ions. The results showed that emission intensity was dependent on lithium contents in Ti-doped lead lithium borophosphate glass composition.
format Article
author T.Q., Leow
P.M., Leong
T.Y., Eeu
Ibrahim, Z.
Hussin, R.
spellingShingle T.Q., Leow
P.M., Leong
T.Y., Eeu
Ibrahim, Z.
Hussin, R.
Study of structural and luminescence properties of lead lithium borophosphate glass system doped with Ti Ions
author_facet T.Q., Leow
P.M., Leong
T.Y., Eeu
Ibrahim, Z.
Hussin, R.
author_sort T.Q., Leow
title Study of structural and luminescence properties of lead lithium borophosphate glass system doped with Ti Ions
title_short Study of structural and luminescence properties of lead lithium borophosphate glass system doped with Ti Ions
title_full Study of structural and luminescence properties of lead lithium borophosphate glass system doped with Ti Ions
title_fullStr Study of structural and luminescence properties of lead lithium borophosphate glass system doped with Ti Ions
title_full_unstemmed Study of structural and luminescence properties of lead lithium borophosphate glass system doped with Ti Ions
title_sort study of structural and luminescence properties of lead lithium borophosphate glass system doped with ti ions
publisher Universiti Kebangsaan Malaysia
publishDate 2014
url http://journalarticle.ukm.my/7184/
http://journalarticle.ukm.my/7184/
http://journalarticle.ukm.my/7184/1/17_T.Q._Leow.pdf
first_indexed 2023-09-18T19:48:58Z
last_indexed 2023-09-18T19:48:58Z
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