Stability of SPEEK-triaminopyrimide polymer electrolyte membrane for direct methanol fuel cell application

Modification of sulfonated poly (ether ether ketone) (SPEEK) membrane was conducted by incorporating Cloisite 15A® clay and 2,4,6-triaminopyrimidine (TAP) via solution intercalation method. The effect of the Closite and TAP introduction was evaluated in terms of the membrane’s physicochemical and hy...

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Main Authors:	Juhana Jaafar, Ismail, A.F., Matsuura, T., Mohd Norddin, M.N.A.
Format:	Article
Language:	English
Published:	Universiti Kebangsaan Malaysia 2013
Online Access:	http://journalarticle.ukm.my/6634/ http://journalarticle.ukm.my/6634/ http://journalarticle.ukm.my/6634/1/19_Juhana_Jaafar.pdf

id	ukm-6634
recordtype	eprints
spelling	ukm-66342016-12-14T06:41:45Z http://journalarticle.ukm.my/6634/ Stability of SPEEK-triaminopyrimide polymer electrolyte membrane for direct methanol fuel cell application Juhana Jaafar, Ismail, A.F. Matsuura, T. Mohd Norddin, M.N.A. Modification of sulfonated poly (ether ether ketone) (SPEEK) membrane was conducted by incorporating Cloisite 15A® clay and 2,4,6-triaminopyrimidine (TAP) via solution intercalation method. The effect of the Closite and TAP introduction was evaluated in terms of the membrane’s physicochemical and hydration properties. The membrane’s properties were compared among the SPEEK based membranes, including parent SPEEK, SPEEK/Cloisite and SPEEK/Cloisite 15A®/TAP. The uniform dispersion of Cloisite 15A® particles in SPEEK polymer matrices was confirmed by SEM analysis. The stability in water; in terms of dimensional change and dissolution, of the modified membrane was investigated and compared to the parent SPEEK membrane. SPEEK/Cloisite 15A®/TAP nanocomposite membrane exhibited the highest selectivity by means of the ratio of proton conductivity to methanol permeability. Owing to its higher proton conductivity and significantly lower methanol permeabilities and high stability in water environment, SPEEK/Cloisite 15A®/TAP nanocomposite membrane was found to be a potential alternative polymer electrolyte membrane for DMFC applications. Universiti Kebangsaan Malaysia 2013-11 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/6634/1/19_Juhana_Jaafar.pdf Juhana Jaafar, and Ismail, A.F. and Matsuura, T. and Mohd Norddin, M.N.A. (2013) Stability of SPEEK-triaminopyrimide polymer electrolyte membrane for direct methanol fuel cell application. Sains Malaysiana, 42 (11). pp. 1671-1677. ISSN 0126-6039 http://www.ukm.my/jsm/
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Kebangasaan Malaysia
building	UKM Institutional Repository
collection	Online Access
language	English
description	Modification of sulfonated poly (ether ether ketone) (SPEEK) membrane was conducted by incorporating Cloisite 15A® clay and 2,4,6-triaminopyrimidine (TAP) via solution intercalation method. The effect of the Closite and TAP introduction was evaluated in terms of the membrane’s physicochemical and hydration properties. The membrane’s properties were compared among the SPEEK based membranes, including parent SPEEK, SPEEK/Cloisite and SPEEK/Cloisite 15A®/TAP. The uniform dispersion of Cloisite 15A® particles in SPEEK polymer matrices was confirmed by SEM analysis. The stability in water; in terms of dimensional change and dissolution, of the modified membrane was investigated and compared to the parent SPEEK membrane. SPEEK/Cloisite 15A®/TAP nanocomposite membrane exhibited the highest selectivity by means of the ratio of proton conductivity to methanol permeability. Owing to its higher proton conductivity and significantly lower methanol permeabilities and high stability in water environment, SPEEK/Cloisite 15A®/TAP nanocomposite membrane was found to be a potential alternative polymer electrolyte membrane for DMFC applications.
format	Article
author	Juhana Jaafar, Ismail, A.F. Matsuura, T. Mohd Norddin, M.N.A.
spellingShingle	Juhana Jaafar, Ismail, A.F. Matsuura, T. Mohd Norddin, M.N.A. Stability of SPEEK-triaminopyrimide polymer electrolyte membrane for direct methanol fuel cell application
author_facet	Juhana Jaafar, Ismail, A.F. Matsuura, T. Mohd Norddin, M.N.A.
author_sort	Juhana Jaafar,
title	Stability of SPEEK-triaminopyrimide polymer electrolyte membrane for direct methanol fuel cell application
title_short	Stability of SPEEK-triaminopyrimide polymer electrolyte membrane for direct methanol fuel cell application
title_full	Stability of SPEEK-triaminopyrimide polymer electrolyte membrane for direct methanol fuel cell application
title_fullStr	Stability of SPEEK-triaminopyrimide polymer electrolyte membrane for direct methanol fuel cell application
title_full_unstemmed	Stability of SPEEK-triaminopyrimide polymer electrolyte membrane for direct methanol fuel cell application
title_sort	stability of speek-triaminopyrimide polymer electrolyte membrane for direct methanol fuel cell application
publisher	Universiti Kebangsaan Malaysia
publishDate	2013
url	http://journalarticle.ukm.my/6634/ http://journalarticle.ukm.my/6634/ http://journalarticle.ukm.my/6634/1/19_Juhana_Jaafar.pdf
first_indexed	2023-09-18T19:47:28Z
last_indexed	2023-09-18T19:47:28Z
_version_	1777405996631588864

Stability of SPEEK-triaminopyrimide polymer electrolyte membrane for direct methanol fuel cell application

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