Properties of ENR-50 based electrolyte system

In this work, epoxidized natural rubber 50 (ENR-50) has been used as a host polymer for the preparation of electrolyte system. Attenuated total reflection-fourier transform infrared spectroscopic analyses showed the presence of lithium salt-ENR interactions. The glass transition temperature displaye...

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Main Authors:	Zainal, N., Mohamed, N.S., Idris, R.
Format:	Article
Language:	English
Published:	Universiti Kebangsaan Malaysia 2013
Online Access:	http://journalarticle.ukm.my/6083/ http://journalarticle.ukm.my/6083/ http://journalarticle.ukm.my/6083/1/08_N._Zainal_indd.pdf

id	ukm-6083
recordtype	eprints
spelling	ukm-60832016-12-14T06:40:19Z http://journalarticle.ukm.my/6083/ Properties of ENR-50 based electrolyte system Zainal, N. Mohamed, N.S. Idris, R. In this work, epoxidized natural rubber 50 (ENR-50) has been used as a host polymer for the preparation of electrolyte system. Attenuated total reflection-fourier transform infrared spectroscopic analyses showed the presence of lithium salt-ENR interactions. The glass transition temperature displayed an increasing trend with the increase in salt concentration indicating that the ionic conductivity was not influenced by segmental motion of the ENR-50 chains. The increase in glass transition temperature with the addition of salt was due to the formation of transient cross-linking between ENR-50 chains via the coordinated interaction between ENR-50 chains and salt. The highest room temperature ionic conductivity obtained was in the order of 10-5 S cm-1 for the film containing 50 wt% of lithium salt. The ionic conductivity of this electrolyte system increased with increasing temperature and obeyed the Vogel-Tamman-Fulcher behavior. The increase in ionic conductivity of the electrolyte system with salt concentration could also be correlated to the charge carriers concentration and/or migration rate of charge carriers. Universiti Kebangsaan Malaysia 2013-04 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/6083/1/08_N._Zainal_indd.pdf Zainal, N. and Mohamed, N.S. and Idris, R. (2013) Properties of ENR-50 based electrolyte system. Sains Malaysiana, 42 (4). pp. 481-485. ISSN 0126-6039 http://www.ukm.my/jsm/
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Kebangasaan Malaysia
building	UKM Institutional Repository
collection	Online Access
language	English
description	In this work, epoxidized natural rubber 50 (ENR-50) has been used as a host polymer for the preparation of electrolyte system. Attenuated total reflection-fourier transform infrared spectroscopic analyses showed the presence of lithium salt-ENR interactions. The glass transition temperature displayed an increasing trend with the increase in salt concentration indicating that the ionic conductivity was not influenced by segmental motion of the ENR-50 chains. The increase in glass transition temperature with the addition of salt was due to the formation of transient cross-linking between ENR-50 chains via the coordinated interaction between ENR-50 chains and salt. The highest room temperature ionic conductivity obtained was in the order of 10-5 S cm-1 for the film containing 50 wt% of lithium salt. The ionic conductivity of this electrolyte system increased with increasing temperature and obeyed the Vogel-Tamman-Fulcher behavior. The increase in ionic conductivity of the electrolyte system with salt concentration could also be correlated to the charge carriers concentration and/or migration rate of charge carriers.
format	Article
author	Zainal, N. Mohamed, N.S. Idris, R.
spellingShingle	Zainal, N. Mohamed, N.S. Idris, R. Properties of ENR-50 based electrolyte system
author_facet	Zainal, N. Mohamed, N.S. Idris, R.
author_sort	Zainal, N.
title	Properties of ENR-50 based electrolyte system
title_short	Properties of ENR-50 based electrolyte system
title_full	Properties of ENR-50 based electrolyte system
title_fullStr	Properties of ENR-50 based electrolyte system
title_full_unstemmed	Properties of ENR-50 based electrolyte system
title_sort	properties of enr-50 based electrolyte system
publisher	Universiti Kebangsaan Malaysia
publishDate	2013
url	http://journalarticle.ukm.my/6083/ http://journalarticle.ukm.my/6083/ http://journalarticle.ukm.my/6083/1/08_N._Zainal_indd.pdf
first_indexed	2023-09-18T19:45:56Z
last_indexed	2023-09-18T19:45:56Z
_version_	1777405899796643840

Properties of ENR-50 based electrolyte system

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