Synthesis and structural studies of lanthanum (III) dialkyldithiocarbamate, 1,10-phenantrolien
A new series of lanthanum dialkyldithiocarbamate complexes with 1,10-phenantroline were successfully synthesized using in situ methods. These complexes were characterized using elemental analysis, infrared, thermogravimetric analysis and conductivity. Microelemental analysis data were in agreement...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Universiti Kebangsaan Malaysia
2009
|
| Online Access: | http://journalarticle.ukm.my/59/ http://journalarticle.ukm.my/59/ http://journalarticle.ukm.my/59/1/ |
| id |
ukm-59 |
|---|---|
| recordtype |
eprints |
| spelling |
ukm-592016-12-14T06:26:17Z http://journalarticle.ukm.my/59/ Synthesis and structural studies of lanthanum (III) dialkyldithiocarbamate, 1,10-phenantrolien Ibrahim Baba, Indah Raya, Bohari Mohd Yamin, A new series of lanthanum dialkyldithiocarbamate complexes with 1,10-phenantroline were successfully synthesized using in situ methods. These complexes were characterized using elemental analysis, infrared, thermogravimetric analysis and conductivity. Microelemental analysis data were in agreement with the general formula La(S2CNR’R”)3phen (R’=ethyl, methyl; R”=butyl, heptyl, isopropyl, isobutyl, benzyl and cyclohexyl; phen = 1,10-phenantroline). Infrared spectra of complexes showed the thioureide ν(C-N) bands were in the region of 1450 - 1482 cm-1. The single ν(C-S) bands appeared in the region of 959 – 997 cm-1 and ν(C-H) bands in the region of 2918-2955 cm-1. The crystal structure of tris(N,Nethylbenzyldithiocarbamate)( 1,10-phenantroline)lantanum(III) adopts an orthorombic system (space group Pccn) with a distorted dodecahedron geometry with a = 19.865(5) Å , b = 42.803(10) Å, c = 10.657(3) Å, α = β = γ= 90o and Z = 9. Three dithiocarbamates and one phenanthroline ligands were coordinated to the central La atom in bidentate manner. Universiti Kebangsaan Malaysia 2009-04 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/59/1/ Ibrahim Baba, and Indah Raya, and Bohari Mohd Yamin, (2009) Synthesis and structural studies of lanthanum (III) dialkyldithiocarbamate, 1,10-phenantrolien. Sains Malaysiana, 38 (2). pp. 185-190. ISSN 0126-6039 http://www.ukm.my/~jsm/utama.html |
| repository_type |
Digital Repository |
| institution_category |
Local University |
| institution |
Universiti Kebangasaan Malaysia |
| building |
UKM Institutional Repository |
| collection |
Online Access |
| language |
English |
| description |
A new series of lanthanum dialkyldithiocarbamate complexes with 1,10-phenantroline were successfully synthesized using
in situ methods. These complexes were characterized using elemental analysis, infrared, thermogravimetric analysis and
conductivity. Microelemental analysis data were in agreement with the general formula La(S2CNR’R”)3phen (R’=ethyl, methyl; R”=butyl, heptyl, isopropyl, isobutyl, benzyl and cyclohexyl; phen = 1,10-phenantroline). Infrared spectra of complexes showed the thioureide ν(C-N) bands were in the region of 1450 - 1482 cm-1. The single ν(C-S) bands appeared in the region of 959 – 997 cm-1 and ν(C-H) bands in the region of 2918-2955 cm-1. The crystal structure of tris(N,Nethylbenzyldithiocarbamate)(
1,10-phenantroline)lantanum(III) adopts an orthorombic system (space group Pccn) with a distorted dodecahedron geometry with a = 19.865(5) Å , b = 42.803(10) Å, c = 10.657(3) Å, α = β = γ= 90o and Z = 9. Three dithiocarbamates and one phenanthroline ligands were coordinated to the central La atom in bidentate manner. |
| format |
Article |
| author |
Ibrahim Baba, Indah Raya, Bohari Mohd Yamin, |
| spellingShingle |
Ibrahim Baba, Indah Raya, Bohari Mohd Yamin, Synthesis and structural studies of lanthanum (III) dialkyldithiocarbamate, 1,10-phenantrolien |
| author_facet |
Ibrahim Baba, Indah Raya, Bohari Mohd Yamin, |
| author_sort |
Ibrahim Baba, |
| title |
Synthesis and structural studies of lanthanum (III) dialkyldithiocarbamate, 1,10-phenantrolien |
| title_short |
Synthesis and structural studies of lanthanum (III) dialkyldithiocarbamate, 1,10-phenantrolien |
| title_full |
Synthesis and structural studies of lanthanum (III) dialkyldithiocarbamate, 1,10-phenantrolien |
| title_fullStr |
Synthesis and structural studies of lanthanum (III) dialkyldithiocarbamate, 1,10-phenantrolien |
| title_full_unstemmed |
Synthesis and structural studies of lanthanum (III) dialkyldithiocarbamate, 1,10-phenantrolien |
| title_sort |
synthesis and structural studies of lanthanum (iii) dialkyldithiocarbamate, 1,10-phenantrolien |
| publisher |
Universiti Kebangsaan Malaysia |
| publishDate |
2009 |
| url |
http://journalarticle.ukm.my/59/ http://journalarticle.ukm.my/59/ http://journalarticle.ukm.my/59/1/ |
| first_indexed |
2023-09-18T19:01:08Z |
| last_indexed |
2023-09-18T19:01:08Z |
| _version_ |
1777403081721380864 |