Synthesis and characterization of bis(N-benzyl-Nisopropyldithiocarbamato) zinc(II) with bidentate nitrogen ligands: crystal structure of Zn[S2CN (C7H7) (iC3H7)]2(bipy)

Two adducts of bis(N-benzyl-N-isopropyldithiocarbamato) zinc(II) with 2,2'-bipyridine and 1,10-phenanthroline have been successfully synthesized and characterized by elemental analysis and spectroscopic studies. The IR spectra of these adducts showed the thioureide band, v(C---- N) which occu...

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Main Authors:	Normah Awang, Ibrahim Baba., Y. Farina Abd. Aziz, Bohari M. Yamin
Format:	Article
Published:	Universiti Kebangsaan Malaysia 2004
Online Access:	http://journalarticle.ukm.my/3885/ http://journalarticle.ukm.my/3885/

id	ukm-3885
recordtype	eprints
spelling	ukm-38852012-03-23T01:10:07Z http://journalarticle.ukm.my/3885/ Synthesis and characterization of bis(N-benzyl-Nisopropyldithiocarbamato) zinc(II) with bidentate nitrogen ligands: crystal structure of Zn[S2CN (C7H7) (iC3H7)]2(bipy) Normah Awang, Ibrahim Baba., Y. Farina Abd. Aziz , Bohari M. Yamin, Two adducts of bis(N-benzyl-N-isopropyldithiocarbamato) zinc(II) with 2,2'-bipyridine and 1,10-phenanthroline have been successfully synthesized and characterized by elemental analysis and spectroscopic studies. The IR spectra of these adducts showed the thioureide band, v(C---- N) which occurred at 1440 and 1438 cm-1 respectively, lower than the parent compound at 1471 cm-1. The 13C NMR spectroscopic data for these compounds showed that the carbon signal from CS2 moiety shifted slightly downfield to 206.6 and 208.5 ppm compared to the parent compound at 205.1 ppm. The single crystal structure of bis (N-benzyl-N-isopropyldithiocarbamato )zinc(II)(bipy) has been determined. The structure of this compound showed monomeric nature with hexacoordination of the metal in a highly distorted octahedral geometry. Universiti Kebangsaan Malaysia 2004 Article PeerReviewed Normah Awang, and Ibrahim Baba., and Y. Farina Abd. Aziz , and Bohari M. Yamin, (2004) Synthesis and characterization of bis(N-benzyl-Nisopropyldithiocarbamato) zinc(II) with bidentate nitrogen ligands: crystal structure of Zn[S2CN (C7H7) (iC3H7)]2(bipy). Sains Malaysiana, 33 (2). pp. 45-53. ISSN 0126-6039 http://www.ukm.my/jsm/english_journals/vol33num2_2004/vol33num2_04page45-53.html
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Kebangasaan Malaysia
building	UKM Institutional Repository
collection	Online Access
description	Two adducts of bis(N-benzyl-N-isopropyldithiocarbamato) zinc(II) with 2,2'-bipyridine and 1,10-phenanthroline have been successfully synthesized and characterized by elemental analysis and spectroscopic studies. The IR spectra of these adducts showed the thioureide band, v(C---- N) which occurred at 1440 and 1438 cm-1 respectively, lower than the parent compound at 1471 cm-1. The 13C NMR spectroscopic data for these compounds showed that the carbon signal from CS2 moiety shifted slightly downfield to 206.6 and 208.5 ppm compared to the parent compound at 205.1 ppm. The single crystal structure of bis (N-benzyl-N-isopropyldithiocarbamato )zinc(II)(bipy) has been determined. The structure of this compound showed monomeric nature with hexacoordination of the metal in a highly distorted octahedral geometry.
format	Article
author	Normah Awang, Ibrahim Baba., Y. Farina Abd. Aziz , Bohari M. Yamin,
spellingShingle	Normah Awang, Ibrahim Baba., Y. Farina Abd. Aziz , Bohari M. Yamin, Synthesis and characterization of bis(N-benzyl-Nisopropyldithiocarbamato) zinc(II) with bidentate nitrogen ligands: crystal structure of Zn[S2CN (C7H7) (iC3H7)]2(bipy)
author_facet	Normah Awang, Ibrahim Baba., Y. Farina Abd. Aziz , Bohari M. Yamin,
author_sort	Normah Awang,
title	Synthesis and characterization of bis(N-benzyl-Nisopropyldithiocarbamato) zinc(II) with bidentate nitrogen ligands: crystal structure of Zn[S2CN (C7H7) (iC3H7)]2(bipy)
title_short	Synthesis and characterization of bis(N-benzyl-Nisopropyldithiocarbamato) zinc(II) with bidentate nitrogen ligands: crystal structure of Zn[S2CN (C7H7) (iC3H7)]2(bipy)
title_full	Synthesis and characterization of bis(N-benzyl-Nisopropyldithiocarbamato) zinc(II) with bidentate nitrogen ligands: crystal structure of Zn[S2CN (C7H7) (iC3H7)]2(bipy)
title_fullStr	Synthesis and characterization of bis(N-benzyl-Nisopropyldithiocarbamato) zinc(II) with bidentate nitrogen ligands: crystal structure of Zn[S2CN (C7H7) (iC3H7)]2(bipy)
title_full_unstemmed	Synthesis and characterization of bis(N-benzyl-Nisopropyldithiocarbamato) zinc(II) with bidentate nitrogen ligands: crystal structure of Zn[S2CN (C7H7) (iC3H7)]2(bipy)
title_sort	synthesis and characterization of bis(n-benzyl-nisopropyldithiocarbamato) zinc(ii) with bidentate nitrogen ligands: crystal structure of zn[s2cn (c7h7) (ic3h7)]2(bipy)
publisher	Universiti Kebangsaan Malaysia
publishDate	2004
url	http://journalarticle.ukm.my/3885/ http://journalarticle.ukm.my/3885/
first_indexed	2023-09-18T19:40:02Z
last_indexed	2023-09-18T19:40:02Z
_version_	1777405529162776576

Synthesis and characterization of bis(N-benzyl-Nisopropyldithiocarbamato) zinc(II) with bidentate nitrogen ligands: crystal structure of Zn[S2CN (C7H7) (iC3H7)]2(bipy)

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