Synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(III) ethylbutyldithiocarbamate
A new series of ethylbutyldithiocarbamate compounds have been synthesized. The compounds made of Zn(II), Cu(II), Ni(II), Pb(II), Sb(III) and Bi(III) were prepared by reacting the respective metal salts with ethylbutylamine and carbon disulphide using "in situ" method. Results of elemental...
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Universiti Kebangsaan Malaysia
2002
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ukm-38272012-05-04T04:14:55Z http://journalarticle.ukm.my/3827/ Synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(III) ethylbutyldithiocarbamate Karimah Kassim, Ibrahim Baba, Yang Farina , Abdul Hamid Othman, H.K. Fun, A new series of ethylbutyldithiocarbamate compounds have been synthesized. The compounds made of Zn(II), Cu(II), Ni(II), Pb(II), Sb(III) and Bi(III) were prepared by reacting the respective metal salts with ethylbutylamine and carbon disulphide using "in situ" method. Results of elemental analysis showed that the isolated compounds have the general formula, M[S2CNR1RZ2]n (n = 2; M = Zn(II), Cu(II), Ni(II), Pb(II), and n = 3; M = Sb(III) and Bi(III)). Infrared spectra of the compounds showed the thioureido v(C-N) bands in the regions 1468 – 1497 cm-1. The (C-S) bands appeared in the region 956 – 997 cm-1 while the v(M-S) bands appeared in the region 300 – 400 cm-1. The 1H NMR signals indicated ethyl- and butyl- in the region 0.40 – 3.85 ppm. The 13C NMR spectra of zinc(II) and lead(II) showed a resonance in the region 202.0 ppm, which attributed to the carbon atom of NCS2 group. Tris(N-ethyl-N-butyldithiocarbamato-S) bismuth(III) is pentagonal pyramid distorted with triclinic system with P1, a = 10.5120(1)Å, b = 10.5128(1)Å, b = 10.5128(1)Å, c = 14.5755(1)Å, α = 99.927(1)o, γ = 103.3383(1) and Z = 2. Universiti Kebangsaan Malaysia 2002 Article PeerReviewed Karimah Kassim, and Ibrahim Baba, and Yang Farina , and Abdul Hamid Othman, and H.K. Fun, (2002) Synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(III) ethylbutyldithiocarbamate. Sains Malaysiana, 31 . pp. 101-108. ISSN 0126-6039 http://www.ukm.my/jsm/english_journals/vol31_2002/vol31_02page101-108.html |
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A new series of ethylbutyldithiocarbamate compounds have been synthesized. The compounds made of Zn(II), Cu(II), Ni(II), Pb(II), Sb(III) and Bi(III) were prepared by reacting the respective metal salts with ethylbutylamine and carbon disulphide using "in situ" method. Results of elemental analysis showed that the isolated compounds have the general formula, M[S2CNR1RZ2]n (n = 2; M = Zn(II), Cu(II), Ni(II), Pb(II), and n = 3; M = Sb(III) and Bi(III)). Infrared spectra of the compounds showed the thioureido v(C-N) bands in the regions 1468 – 1497 cm-1. The (C-S) bands appeared in the region 956 – 997 cm-1 while the v(M-S) bands appeared in the region 300 – 400 cm-1. The 1H NMR signals indicated ethyl- and butyl- in the region 0.40 – 3.85 ppm. The 13C NMR spectra of zinc(II) and lead(II) showed a resonance in the region 202.0 ppm, which attributed to the carbon atom of NCS2 group. Tris(N-ethyl-N-butyldithiocarbamato-S) bismuth(III) is pentagonal pyramid distorted with triclinic system with P1, a = 10.5120(1)Å, b = 10.5128(1)Å, b = 10.5128(1)Å, c = 14.5755(1)Å, α = 99.927(1)o, γ = 103.3383(1) and Z = 2. |
| format |
Article |
| author |
Karimah Kassim, Ibrahim Baba, Yang Farina , Abdul Hamid Othman, H.K. Fun, |
| spellingShingle |
Karimah Kassim, Ibrahim Baba, Yang Farina , Abdul Hamid Othman, H.K. Fun, Synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(III) ethylbutyldithiocarbamate |
| author_facet |
Karimah Kassim, Ibrahim Baba, Yang Farina , Abdul Hamid Othman, H.K. Fun, |
| author_sort |
Karimah Kassim, |
| title |
Synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(III) ethylbutyldithiocarbamate |
| title_short |
Synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(III) ethylbutyldithiocarbamate |
| title_full |
Synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(III) ethylbutyldithiocarbamate |
| title_fullStr |
Synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(III) ethylbutyldithiocarbamate |
| title_full_unstemmed |
Synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(III) ethylbutyldithiocarbamate |
| title_sort |
synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(iii) ethylbutyldithiocarbamate |
| publisher |
Universiti Kebangsaan Malaysia |
| publishDate |
2002 |
| url |
http://journalarticle.ukm.my/3827/ http://journalarticle.ukm.my/3827/ |
| first_indexed |
2023-09-18T19:39:52Z |
| last_indexed |
2023-09-18T19:39:52Z |
| _version_ |
1777405518505050112 |