Effects of yttria doping on some properties of YBa2Cu3O7-δ superconductor

Samples of Y-Ba-Cu-O superconductor with nominal compositions of YBa2Cu3O7-d + x (weight %) Y2O3 (x = 0 - 15) were prepared by solid state reaction method using the Y2Cu2O5 and BaCuO2 precursors as the starting reagents. The X-ray diffraction (XRD) diffractograms for the doped samples (x> 0) show...

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Main Authors: Mustaffa Hj. Abdullah, Tan , Tuan Keat
Format: Article
Published: Universiti Kebangsaan Malaysia 1997
Online Access:http://journalarticle.ukm.my/3739/
http://journalarticle.ukm.my/3739/
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spelling ukm-37392012-03-19T01:20:02Z http://journalarticle.ukm.my/3739/ Effects of yttria doping on some properties of YBa2Cu3O7-δ superconductor Mustaffa Hj. Abdullah, Tan , Tuan Keat Samples of Y-Ba-Cu-O superconductor with nominal compositions of YBa2Cu3O7-d + x (weight %) Y2O3 (x = 0 - 15) were prepared by solid state reaction method using the Y2Cu2O5 and BaCuO2 precursors as the starting reagents. The X-ray diffraction (XRD) diffractograms for the doped samples (x> 0) show an additional non-superconducting Y2BaCuO5 (211) phase. The scanning electron microscope (SEM) micrographs show that the smaller Y2BaCuO5 grains are precipitated on the surface of the larger YBa2Cu3O7-d (YBCO) crystals. The grain size of the YBCO decreases with increasing yttria. The superconducting zero resistivity critical temperature (Tco) of the doped samples is very close to the Tco of the YBCO for x < 5, but it seems to be significantly decreasing for larger x. The transport critical current density (J) for x < 5 is enhanced due to magnetic flux pinning process by the 211 phase. However, Jc decreased for larger x due to the increase of weak links at the grain boundaries of the YBCO phase. Universiti Kebangsaan Malaysia 1997-06 Article PeerReviewed Mustaffa Hj. Abdullah, and Tan , Tuan Keat (1997) Effects of yttria doping on some properties of YBa2Cu3O7-δ superconductor. Sains Malaysiana, 26 (2). pp. 15-26. ISSN 0126-6039 http://www.ukm.my/jsm/english_journals/vol26um2_1997/vol26num2_97page15-26.html
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description Samples of Y-Ba-Cu-O superconductor with nominal compositions of YBa2Cu3O7-d + x (weight %) Y2O3 (x = 0 - 15) were prepared by solid state reaction method using the Y2Cu2O5 and BaCuO2 precursors as the starting reagents. The X-ray diffraction (XRD) diffractograms for the doped samples (x> 0) show an additional non-superconducting Y2BaCuO5 (211) phase. The scanning electron microscope (SEM) micrographs show that the smaller Y2BaCuO5 grains are precipitated on the surface of the larger YBa2Cu3O7-d (YBCO) crystals. The grain size of the YBCO decreases with increasing yttria. The superconducting zero resistivity critical temperature (Tco) of the doped samples is very close to the Tco of the YBCO for x < 5, but it seems to be significantly decreasing for larger x. The transport critical current density (J) for x < 5 is enhanced due to magnetic flux pinning process by the 211 phase. However, Jc decreased for larger x due to the increase of weak links at the grain boundaries of the YBCO phase.
format Article
author Mustaffa Hj. Abdullah,
Tan , Tuan Keat
spellingShingle Mustaffa Hj. Abdullah,
Tan , Tuan Keat
Effects of yttria doping on some properties of YBa2Cu3O7-δ superconductor
author_facet Mustaffa Hj. Abdullah,
Tan , Tuan Keat
author_sort Mustaffa Hj. Abdullah,
title Effects of yttria doping on some properties of YBa2Cu3O7-δ superconductor
title_short Effects of yttria doping on some properties of YBa2Cu3O7-δ superconductor
title_full Effects of yttria doping on some properties of YBa2Cu3O7-δ superconductor
title_fullStr Effects of yttria doping on some properties of YBa2Cu3O7-δ superconductor
title_full_unstemmed Effects of yttria doping on some properties of YBa2Cu3O7-δ superconductor
title_sort effects of yttria doping on some properties of yba2cu3o7-δ superconductor
publisher Universiti Kebangsaan Malaysia
publishDate 1997
url http://journalarticle.ukm.my/3739/
http://journalarticle.ukm.my/3739/
first_indexed 2023-09-18T19:39:38Z
last_indexed 2023-09-18T19:39:38Z
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