Conductivity and structural studies of plasticized polyacrylonitrile (PAN) – lithium triflate polymer electrolyte Films

The effect of different plasticizers on the properties of PAN–LiCF3SO3 polymer electrolytes has been studied. Propylene carbonate (PC) and ethylene carbonate (EC) having different values of donor numbers, dielectric constant and viscosity have been used as plasticizers. The highest room temperature...

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Main Authors:	Ahmad .A, Md. Isa .K.B, Osman .Z
Format:	Article
Language:	English
Published:	Universiti Kebangsaan Malaysia 2011
Online Access:	http://journalarticle.ukm.my/2534/ http://journalarticle.ukm.my/2534/ http://journalarticle.ukm.my/2534/1/03_A._Ahmad.pdf

id	ukm-2534
recordtype	eprints
spelling	ukm-25342016-12-14T06:31:54Z http://journalarticle.ukm.my/2534/ Conductivity and structural studies of plasticized polyacrylonitrile (PAN) – lithium triflate polymer electrolyte Films Ahmad .A, Md. Isa .K.B, Osman .Z, The effect of different plasticizers on the properties of PAN–LiCF3SO3 polymer electrolytes has been studied. Propylene carbonate (PC) and ethylene carbonate (EC) having different values of donor numbers, dielectric constant and viscosity have been used as plasticizers. The highest room temperature conductivity for the film in the PAN–LiCF3SO3 system was 3.04 × 10-4 S cm-1. The highest room temperature conductivity for the films in the PAN–EC–LiCF3SO3 system and the PAN–PC–LiCF3SO3 system was 1.32 × 10-3 and 8.64 × 10-4 S cm-1. The addition of plasticizers has been found to enhance the conductivity of polymer electrolytes by increasing the amorphous content as well as by dissociating the ion aggregates present in polymer electrolyte. Conductivity temperature-dependence studies of these plasticized PAN-salt systems were carried out in the temperature range of 303 to 373 K. The conductivity versus temperature plots obeyed an Arrhenius type variation. The structural and complex formations were studied by X-ray diffraction (XRD) and Fourier Transform Infrared (FTIR) spectroscopy. Universiti Kebangsaan Malaysia 2011-07 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/2534/1/03_A._Ahmad.pdf Ahmad .A, and Md. Isa .K.B, and Osman .Z, (2011) Conductivity and structural studies of plasticized polyacrylonitrile (PAN) – lithium triflate polymer electrolyte Films. Sains Malaysiana, 40 (7). pp. 691-694. ISSN 0126-6039 http://www.ukm.my/jsm/
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Kebangasaan Malaysia
building	UKM Institutional Repository
collection	Online Access
language	English
description	The effect of different plasticizers on the properties of PAN–LiCF3SO3 polymer electrolytes has been studied. Propylene carbonate (PC) and ethylene carbonate (EC) having different values of donor numbers, dielectric constant and viscosity have been used as plasticizers. The highest room temperature conductivity for the film in the PAN–LiCF3SO3 system was 3.04 × 10-4 S cm-1. The highest room temperature conductivity for the films in the PAN–EC–LiCF3SO3 system and the PAN–PC–LiCF3SO3 system was 1.32 × 10-3 and 8.64 × 10-4 S cm-1. The addition of plasticizers has been found to enhance the conductivity of polymer electrolytes by increasing the amorphous content as well as by dissociating the ion aggregates present in polymer electrolyte. Conductivity temperature-dependence studies of these plasticized PAN-salt systems were carried out in the temperature range of 303 to 373 K. The conductivity versus temperature plots obeyed an Arrhenius type variation. The structural and complex formations were studied by X-ray diffraction (XRD) and Fourier Transform Infrared (FTIR) spectroscopy.
format	Article
author	Ahmad .A, Md. Isa .K.B, Osman .Z,
spellingShingle	Ahmad .A, Md. Isa .K.B, Osman .Z, Conductivity and structural studies of plasticized polyacrylonitrile (PAN) – lithium triflate polymer electrolyte Films
author_facet	Ahmad .A, Md. Isa .K.B, Osman .Z,
author_sort	Ahmad .A,
title	Conductivity and structural studies of plasticized polyacrylonitrile (PAN) – lithium triflate polymer electrolyte Films
title_short	Conductivity and structural studies of plasticized polyacrylonitrile (PAN) – lithium triflate polymer electrolyte Films
title_full	Conductivity and structural studies of plasticized polyacrylonitrile (PAN) – lithium triflate polymer electrolyte Films
title_fullStr	Conductivity and structural studies of plasticized polyacrylonitrile (PAN) – lithium triflate polymer electrolyte Films
title_full_unstemmed	Conductivity and structural studies of plasticized polyacrylonitrile (PAN) – lithium triflate polymer electrolyte Films
title_sort	conductivity and structural studies of plasticized polyacrylonitrile (pan) – lithium triflate polymer electrolyte films
publisher	Universiti Kebangsaan Malaysia
publishDate	2011
url	http://journalarticle.ukm.my/2534/ http://journalarticle.ukm.my/2534/ http://journalarticle.ukm.my/2534/1/03_A._Ahmad.pdf
first_indexed	2023-09-18T19:36:19Z
last_indexed	2023-09-18T19:36:19Z
_version_	1777405295300968448

Conductivity and structural studies of plasticized polyacrylonitrile (PAN) – lithium triflate polymer electrolyte Films

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