Effect of synthesis condition on the structural features of ni-ce bimetallic catalysts supported on functionalized multi-walled carbon nanotubes

Effect of synthesis condition on the structural features of ni-ce bimetallic catalysts supported on functionalized multi-walled carbon nanotubes

In this paper, screening study in regards to preparation of functionalized multi-walled carbon nanotubes (FMWNT)-supported bi-metallic catalyst is discussed. Functional groups such as hydroxyl and carboxylic acid are introduced on multi-walled carbon nanotubes (MWCNT) surface using acid treatment me...

Full description

Bibliographic Details
Main Authors: Nur Syahidah Afandi, Mehrnoush Khavarian, Abdul Rahman Mohamed
Format: Article
Language:English
Published: Penerbit Universiti Kebangsaan Malaysia 2019
Online Access:http://journalarticle.ukm.my/13713/
http://journalarticle.ukm.my/13713/
http://journalarticle.ukm.my/13713/1/08%20Nur%20Syahidah%20Afandi.pdf
id ukm-13713
recordtype eprints
spelling ukm-137132019-11-29T09:00:37Z http://journalarticle.ukm.my/13713/ Effect of synthesis condition on the structural features of ni-ce bimetallic catalysts supported on functionalized multi-walled carbon nanotubes Nur Syahidah Afandi, Mehrnoush Khavarian, Abdul Rahman Mohamed, In this paper, screening study in regards to preparation of functionalized multi-walled carbon nanotubes (FMWNT)-supported bi-metallic catalyst is discussed. Functional groups such as hydroxyl and carboxylic acid are introduced on multi-walled carbon nanotubes (MWCNT) surface using acid treatment method with the aid of probe-type ultrasonication. It is done by varying the concentration of nitric acid (HNO3) and sulphuric acid (H2SO4), acid volume ratio and treatment duration. Catalysts with different ratios of cerium and nickel nanoparticles which are either loaded inside or outside of MWCNT were prepared via ultrasonic-assisted co-precipitation method (NiCe/CNT). This is done to study the effect of cerium loadings. The characterization of the FMWNT and catalysts are carried out using transmission electron micrographs (TEM), Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), Brunauer-Emmett-Teller (BET), X-ray diffraction (XRD), and Raman spectroscopy. The results showed that the treatment in concentrated HNO3/H2SO4 with volume ratio of 3:1 for 8 h was the most suitable condition to generate large amount of surface oxygen group with minimal defects. The observations for each used condition were discussed thoroughly. Decoration of MWCNT with different metal loadings resulted in different distribution and dispersion of metal on nanotubes surface. Penerbit Universiti Kebangsaan Malaysia 2019-06 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/13713/1/08%20Nur%20Syahidah%20Afandi.pdf Nur Syahidah Afandi, and Mehrnoush Khavarian, and Abdul Rahman Mohamed, (2019) Effect of synthesis condition on the structural features of ni-ce bimetallic catalysts supported on functionalized multi-walled carbon nanotubes. Sains Malaysiana, 48 (6). pp. 1209-1219. ISSN 0126-6039 http://www.ukm.my/jsm/malay_journals/jilid48bil6_2019/KandunganJilid48Bil6_2019.html
repository_type Digital Repository
institution_category Local University
institution Universiti Kebangasaan Malaysia
building UKM Institutional Repository
collection Online Access
language English
description In this paper, screening study in regards to preparation of functionalized multi-walled carbon nanotubes (FMWNT)-supported bi-metallic catalyst is discussed. Functional groups such as hydroxyl and carboxylic acid are introduced on multi-walled carbon nanotubes (MWCNT) surface using acid treatment method with the aid of probe-type ultrasonication. It is done by varying the concentration of nitric acid (HNO3) and sulphuric acid (H2SO4), acid volume ratio and treatment duration. Catalysts with different ratios of cerium and nickel nanoparticles which are either loaded inside or outside of MWCNT were prepared via ultrasonic-assisted co-precipitation method (NiCe/CNT). This is done to study the effect of cerium loadings. The characterization of the FMWNT and catalysts are carried out using transmission electron micrographs (TEM), Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), Brunauer-Emmett-Teller (BET), X-ray diffraction (XRD), and Raman spectroscopy. The results showed that the treatment in concentrated HNO3/H2SO4 with volume ratio of 3:1 for 8 h was the most suitable condition to generate large amount of surface oxygen group with minimal defects. The observations for each used condition were discussed thoroughly. Decoration of MWCNT with different metal loadings resulted in different distribution and dispersion of metal on nanotubes surface.
format Article
author Nur Syahidah Afandi,
Mehrnoush Khavarian,
Abdul Rahman Mohamed,
spellingShingle Nur Syahidah Afandi,
Mehrnoush Khavarian,
Abdul Rahman Mohamed,
Effect of synthesis condition on the structural features of ni-ce bimetallic catalysts supported on functionalized multi-walled carbon nanotubes
author_facet Nur Syahidah Afandi,
Mehrnoush Khavarian,
Abdul Rahman Mohamed,
author_sort Nur Syahidah Afandi,
title Effect of synthesis condition on the structural features of ni-ce bimetallic catalysts supported on functionalized multi-walled carbon nanotubes
title_short Effect of synthesis condition on the structural features of ni-ce bimetallic catalysts supported on functionalized multi-walled carbon nanotubes
title_full Effect of synthesis condition on the structural features of ni-ce bimetallic catalysts supported on functionalized multi-walled carbon nanotubes
title_fullStr Effect of synthesis condition on the structural features of ni-ce bimetallic catalysts supported on functionalized multi-walled carbon nanotubes
title_full_unstemmed Effect of synthesis condition on the structural features of ni-ce bimetallic catalysts supported on functionalized multi-walled carbon nanotubes
title_sort effect of synthesis condition on the structural features of ni-ce bimetallic catalysts supported on functionalized multi-walled carbon nanotubes
publisher Penerbit Universiti Kebangsaan Malaysia
publishDate 2019
url http://journalarticle.ukm.my/13713/
http://journalarticle.ukm.my/13713/
http://journalarticle.ukm.my/13713/1/08%20Nur%20Syahidah%20Afandi.pdf
first_indexed 2023-09-18T20:05:28Z
last_indexed 2023-09-18T20:05:28Z
_version_ 1777407128846204928

Similar Items