Insight observation into rapid discoloration of batik textile effluent by in situ formations of zero valent iron

This study aimed to investigate the discoloration of textile effluent from batik industrial wastewater by Fenton oxidation process using Fe(II), Fe(III) and in situ formation of zero valent iron (Fe(0)). The controlled parameters indicate the Fenton oxidation reaction is ideal on effluent at pH5, co...

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Main Authors: Mohd Shaiful Sajab, Nur Nadia Nazirah Ismail, Jude Santanaraj, Abdul Wahab Mohammad, Hassimi Abu Hassan, Chia, Chin Hua, Sarani Zakaria, An'amt Mohamed Noor
Format: Article
Language:English
Published: Penerbit Universiti Kebangsaan Malaysia 2019
Online Access:http://journalarticle.ukm.my/13092/
http://journalarticle.ukm.my/13092/
http://journalarticle.ukm.my/13092/1/17%20Mohd%20Shaiful%20Sajab.pdf
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spelling ukm-130922019-06-22T00:32:30Z http://journalarticle.ukm.my/13092/ Insight observation into rapid discoloration of batik textile effluent by in situ formations of zero valent iron Mohd Shaiful Sajab, Nur Nadia Nazirah Ismail, Jude Santanaraj, Abdul Wahab Mohammad, Hassimi Abu Hassan, Chia, Chin Hua Sarani Zakaria, An'amt Mohamed Noor, This study aimed to investigate the discoloration of textile effluent from batik industrial wastewater by Fenton oxidation process using Fe(II), Fe(III) and in situ formation of zero valent iron (Fe(0)). The controlled parameters indicate the Fenton oxidation reaction is ideal on effluent at pH5, concentration colour of 4005 mg/L Pt-Co units using 0.5 mg/mL of catalyst dosage to meet the regulation for Malaysian quality water standard. The optimization of Fe(0) precursors, Fe(II) shows a higher discoloration efficiency in comparison with Fe(III). The synthesized particles of Fe(0) shows a nano spherical structure in the diameter range of 20-70 nm, aggregated and into a chain-like formation. Subsequently, the performance of Fe(0) was improved up to 97% discoloration in comparison with 89% discoloration by Fe(II). Whereas, the in situ formation of Fe(0) in batik effluent shows a complete discoloration ascribable to higher reactivity than partially oxidized of synthesized ex situ Fe(0). On top of that, in situ Fe(0) performed at the expeditious reaction in less than five min. Additionally, the regeneration of Fe(0), Fe(II) and Fe(III) show a potential of catalyst recyclability up to three cycles of Fenton oxidation but with a tolerable reduction to 62.1% of effluent discoloration. Penerbit Universiti Kebangsaan Malaysia 2019-02 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/13092/1/17%20Mohd%20Shaiful%20Sajab.pdf Mohd Shaiful Sajab, and Nur Nadia Nazirah Ismail, and Jude Santanaraj, and Abdul Wahab Mohammad, and Hassimi Abu Hassan, and Chia, Chin Hua and Sarani Zakaria, and An'amt Mohamed Noor, (2019) Insight observation into rapid discoloration of batik textile effluent by in situ formations of zero valent iron. Sains Malaysiana, 48 (2). pp. 393-399. ISSN 0126-6039 http://www.ukm.my/jsm/malay_journals/jilid48bil2_2019/KandunganJilid48Bil2_2019.html
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institution Universiti Kebangasaan Malaysia
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collection Online Access
language English
description This study aimed to investigate the discoloration of textile effluent from batik industrial wastewater by Fenton oxidation process using Fe(II), Fe(III) and in situ formation of zero valent iron (Fe(0)). The controlled parameters indicate the Fenton oxidation reaction is ideal on effluent at pH5, concentration colour of 4005 mg/L Pt-Co units using 0.5 mg/mL of catalyst dosage to meet the regulation for Malaysian quality water standard. The optimization of Fe(0) precursors, Fe(II) shows a higher discoloration efficiency in comparison with Fe(III). The synthesized particles of Fe(0) shows a nano spherical structure in the diameter range of 20-70 nm, aggregated and into a chain-like formation. Subsequently, the performance of Fe(0) was improved up to 97% discoloration in comparison with 89% discoloration by Fe(II). Whereas, the in situ formation of Fe(0) in batik effluent shows a complete discoloration ascribable to higher reactivity than partially oxidized of synthesized ex situ Fe(0). On top of that, in situ Fe(0) performed at the expeditious reaction in less than five min. Additionally, the regeneration of Fe(0), Fe(II) and Fe(III) show a potential of catalyst recyclability up to three cycles of Fenton oxidation but with a tolerable reduction to 62.1% of effluent discoloration.
format Article
author Mohd Shaiful Sajab,
Nur Nadia Nazirah Ismail,
Jude Santanaraj,
Abdul Wahab Mohammad,
Hassimi Abu Hassan,
Chia, Chin Hua
Sarani Zakaria,
An'amt Mohamed Noor,
spellingShingle Mohd Shaiful Sajab,
Nur Nadia Nazirah Ismail,
Jude Santanaraj,
Abdul Wahab Mohammad,
Hassimi Abu Hassan,
Chia, Chin Hua
Sarani Zakaria,
An'amt Mohamed Noor,
Insight observation into rapid discoloration of batik textile effluent by in situ formations of zero valent iron
author_facet Mohd Shaiful Sajab,
Nur Nadia Nazirah Ismail,
Jude Santanaraj,
Abdul Wahab Mohammad,
Hassimi Abu Hassan,
Chia, Chin Hua
Sarani Zakaria,
An'amt Mohamed Noor,
author_sort Mohd Shaiful Sajab,
title Insight observation into rapid discoloration of batik textile effluent by in situ formations of zero valent iron
title_short Insight observation into rapid discoloration of batik textile effluent by in situ formations of zero valent iron
title_full Insight observation into rapid discoloration of batik textile effluent by in situ formations of zero valent iron
title_fullStr Insight observation into rapid discoloration of batik textile effluent by in situ formations of zero valent iron
title_full_unstemmed Insight observation into rapid discoloration of batik textile effluent by in situ formations of zero valent iron
title_sort insight observation into rapid discoloration of batik textile effluent by in situ formations of zero valent iron
publisher Penerbit Universiti Kebangsaan Malaysia
publishDate 2019
url http://journalarticle.ukm.my/13092/
http://journalarticle.ukm.my/13092/
http://journalarticle.ukm.my/13092/1/17%20Mohd%20Shaiful%20Sajab.pdf
first_indexed 2023-09-18T20:04:05Z
last_indexed 2023-09-18T20:04:05Z
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