The optimization of RBD palm oil epoxidation process using D-optimal design

The epoxidation process of RBD palm oil was carried out using in situ generated performic acid. The effect of various process variables such as the formic acid towards hydrogen peroxide mole ratio, the reaction temperature and the reaction time were optimized by using response surface methodology (R...

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Main Authors: Nurazira Mohd Nor, Darfizzi Derawi, Jumat Salimon
Format: Article
Language:English
Published: Penerbit Universiti Kebangsaan Malaysia 2018
Online Access:http://journalarticle.ukm.my/12150/
http://journalarticle.ukm.my/12150/
http://journalarticle.ukm.my/12150/1/02%20Nurazira%20Mohd%20Nor.pdf
id ukm-12150
recordtype eprints
spelling ukm-121502018-10-08T13:40:32Z http://journalarticle.ukm.my/12150/ The optimization of RBD palm oil epoxidation process using D-optimal design Nurazira Mohd Nor, Darfizzi Derawi, Jumat Salimon, The epoxidation process of RBD palm oil was carried out using in situ generated performic acid. The effect of various process variables such as the formic acid towards hydrogen peroxide mole ratio, the reaction temperature and the reaction time were optimized by using response surface methodology (RSM). The D-optimal design was used to evaluate the influence of process variables and their interaction in order to obtain the process optimum conditions. The results showed that the optimum conditions of the epoxidation process were at 5.91 mole ratio of formic acid towards 3.60 mole of hydrogen peroxide, reaction temperature of 40ºC and reaction time of 2.55 h. At the optimum condition, the epoxidised RBD palm oil (EPO) yield was 86% with oxirane oxygen content (OOC) of 3.46%. The results showed in good agreement with the predicted values from the RSM model. Penerbit Universiti Kebangsaan Malaysia 2018-07 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/12150/1/02%20Nurazira%20Mohd%20Nor.pdf Nurazira Mohd Nor, and Darfizzi Derawi, and Jumat Salimon, (2018) The optimization of RBD palm oil epoxidation process using D-optimal design. Sains Malaysiana, 47 (7). pp. 1359-1367. ISSN 0126-6039 http://www.ukm.my/jsm/english_journals/vol47num7_2018/contentsVol47num7_2018.html
repository_type Digital Repository
institution_category Local University
institution Universiti Kebangasaan Malaysia
building UKM Institutional Repository
collection Online Access
language English
description The epoxidation process of RBD palm oil was carried out using in situ generated performic acid. The effect of various process variables such as the formic acid towards hydrogen peroxide mole ratio, the reaction temperature and the reaction time were optimized by using response surface methodology (RSM). The D-optimal design was used to evaluate the influence of process variables and their interaction in order to obtain the process optimum conditions. The results showed that the optimum conditions of the epoxidation process were at 5.91 mole ratio of formic acid towards 3.60 mole of hydrogen peroxide, reaction temperature of 40ºC and reaction time of 2.55 h. At the optimum condition, the epoxidised RBD palm oil (EPO) yield was 86% with oxirane oxygen content (OOC) of 3.46%. The results showed in good agreement with the predicted values from the RSM model.
format Article
author Nurazira Mohd Nor,
Darfizzi Derawi,
Jumat Salimon,
spellingShingle Nurazira Mohd Nor,
Darfizzi Derawi,
Jumat Salimon,
The optimization of RBD palm oil epoxidation process using D-optimal design
author_facet Nurazira Mohd Nor,
Darfizzi Derawi,
Jumat Salimon,
author_sort Nurazira Mohd Nor,
title The optimization of RBD palm oil epoxidation process using D-optimal design
title_short The optimization of RBD palm oil epoxidation process using D-optimal design
title_full The optimization of RBD palm oil epoxidation process using D-optimal design
title_fullStr The optimization of RBD palm oil epoxidation process using D-optimal design
title_full_unstemmed The optimization of RBD palm oil epoxidation process using D-optimal design
title_sort optimization of rbd palm oil epoxidation process using d-optimal design
publisher Penerbit Universiti Kebangsaan Malaysia
publishDate 2018
url http://journalarticle.ukm.my/12150/
http://journalarticle.ukm.my/12150/
http://journalarticle.ukm.my/12150/1/02%20Nurazira%20Mohd%20Nor.pdf
first_indexed 2023-09-18T20:01:58Z
last_indexed 2023-09-18T20:01:58Z
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