Synthesis, characterisation and anti-corrosion screening of co(ii) n-butylmethyl and co(ii) n-ethylbenzyl dithiocarbamate / Muhammad Faiz Abd Latif
Nowdays, industrial sectors facing a major problem of corrosion on materials due to condition that cause by degradation on the surface of material by electrochemical reaction. The industrial sector are usually exposed to condition that can promote corrosion process, but the used of inhibitor is more...
| Main Author: | |
|---|---|
| Format: | Student Project |
| Language: | English |
| Published: |
Faculty of Applied Sciences
2017
|
| Subjects: | |
| Online Access: | http://ir.uitm.edu.my/id/eprint/26092/ http://ir.uitm.edu.my/id/eprint/26092/1/PPb_MUHAMMAD%20FAIZ%20ABD%20LATIF%20AS%20N%2017_5.pdf |
| id |
uitm-26092 |
|---|---|
| recordtype |
eprints |
| spelling |
uitm-260922019-11-20T07:24:02Z http://ir.uitm.edu.my/id/eprint/26092/ Synthesis, characterisation and anti-corrosion screening of co(ii) n-butylmethyl and co(ii) n-ethylbenzyl dithiocarbamate / Muhammad Faiz Abd Latif Abd Latif, Muhammad Faiz QD Chemistry Electrochemical analysis Electrochemistry. Electrolysis Nowdays, industrial sectors facing a major problem of corrosion on materials due to condition that cause by degradation on the surface of material by electrochemical reaction. The industrial sector are usually exposed to condition that can promote corrosion process, but the used of inhibitor is more likeable to prevent this problem. The new series of cobalt (II) dithiocarbamate complexes were successfully synthesised by using in situ method which are Co(II) Nbutylmethyldithiocarbamate and Co(II) N-ethylbenzyldithiocarbamate. The compounds were characterised by FT-IR, UV-Vis, gravimetric analysis, molar conductivity, and melting point measurement. Infrared spectra of the complexes showed that the thiouride band .υ(C N) appeared at 1480-1470 cm-1. The stretching band of υ(C S) was unsplitting and appeared between 1013-1010 cm-1 indicates the coordination mode of dithiocarbamate complexes is a bidentate. The melting points of the complexes were higher than the raw materials, as expected. The UV-Vis analysis showed two types of transitions, which are n→π* and π→π* in complexes. UV-Vis spectra are showed that the Co(II) complexes undergo d-d transition as can be seen from the presence of absorption peak at > 400 nm. The molar conductivity showed the both complexes were a non electrolyte. The gravimetric analysis showed the percentage of Co[BuMedtc]2 was 7.59 % and the percentage of Co[EtBenzdtc]2 was 4.33 %. The corrosion inhibition study showed that the inhibition efficiency increases in the sequence [Co[BuMedtc]2] >[Co[EtBenzdtc]2]. The inhibitor efficiency tends to increase as inhibitor concentration increase. Faculty of Applied Sciences 2017 Student Project NonPeerReviewed text en http://ir.uitm.edu.my/id/eprint/26092/1/PPb_MUHAMMAD%20FAIZ%20ABD%20LATIF%20AS%20N%2017_5.pdf Abd Latif, Muhammad Faiz (2017) Synthesis, characterisation and anti-corrosion screening of co(ii) n-butylmethyl and co(ii) n-ethylbenzyl dithiocarbamate / Muhammad Faiz Abd Latif. [Student Project] (Unpublished) |
| repository_type |
Digital Repository |
| institution_category |
Local University |
| institution |
Universiti Teknologi MARA |
| building |
UiTM Institutional Repository |
| collection |
Online Access |
| language |
English |
| topic |
QD Chemistry Electrochemical analysis Electrochemistry. Electrolysis |
| spellingShingle |
QD Chemistry Electrochemical analysis Electrochemistry. Electrolysis Abd Latif, Muhammad Faiz Synthesis, characterisation and anti-corrosion screening of co(ii) n-butylmethyl and co(ii) n-ethylbenzyl dithiocarbamate / Muhammad Faiz Abd Latif |
| description |
Nowdays, industrial sectors facing a major problem of corrosion on materials due to condition that cause by degradation on the surface of material by electrochemical reaction. The industrial sector are usually exposed to condition that can promote corrosion process, but the used of inhibitor is more likeable to prevent this problem. The new series of cobalt (II) dithiocarbamate complexes
were successfully synthesised by using in situ method which are Co(II) Nbutylmethyldithiocarbamate and Co(II) N-ethylbenzyldithiocarbamate. The compounds were characterised by FT-IR, UV-Vis, gravimetric analysis, molar
conductivity, and melting point measurement. Infrared spectra of the complexes showed that the thiouride band .υ(C N) appeared at 1480-1470 cm-1. The stretching band of υ(C S) was unsplitting and appeared between 1013-1010 cm-1 indicates the coordination mode of dithiocarbamate complexes is a bidentate. The melting points of the complexes were higher than the raw materials, as expected.
The UV-Vis analysis showed two types of transitions, which are n→π* and π→π* in complexes. UV-Vis spectra are showed that the Co(II) complexes undergo d-d transition as can be seen from the presence of absorption peak at > 400 nm. The molar conductivity showed the both complexes were a non electrolyte. The gravimetric analysis showed the percentage of Co[BuMedtc]2 was 7.59 % and the percentage of Co[EtBenzdtc]2 was 4.33 %. The corrosion inhibition study showed that the inhibition efficiency increases in the sequence [Co[BuMedtc]2]
>[Co[EtBenzdtc]2]. The inhibitor efficiency tends to increase as inhibitor concentration increase. |
| format |
Student Project |
| author |
Abd Latif, Muhammad Faiz |
| author_facet |
Abd Latif, Muhammad Faiz |
| author_sort |
Abd Latif, Muhammad Faiz |
| title |
Synthesis, characterisation and anti-corrosion screening of co(ii) n-butylmethyl and co(ii) n-ethylbenzyl dithiocarbamate / Muhammad Faiz Abd Latif |
| title_short |
Synthesis, characterisation and anti-corrosion screening of co(ii) n-butylmethyl and co(ii) n-ethylbenzyl dithiocarbamate / Muhammad Faiz Abd Latif |
| title_full |
Synthesis, characterisation and anti-corrosion screening of co(ii) n-butylmethyl and co(ii) n-ethylbenzyl dithiocarbamate / Muhammad Faiz Abd Latif |
| title_fullStr |
Synthesis, characterisation and anti-corrosion screening of co(ii) n-butylmethyl and co(ii) n-ethylbenzyl dithiocarbamate / Muhammad Faiz Abd Latif |
| title_full_unstemmed |
Synthesis, characterisation and anti-corrosion screening of co(ii) n-butylmethyl and co(ii) n-ethylbenzyl dithiocarbamate / Muhammad Faiz Abd Latif |
| title_sort |
synthesis, characterisation and anti-corrosion screening of co(ii) n-butylmethyl and co(ii) n-ethylbenzyl dithiocarbamate / muhammad faiz abd latif |
| publisher |
Faculty of Applied Sciences |
| publishDate |
2017 |
| url |
http://ir.uitm.edu.my/id/eprint/26092/ http://ir.uitm.edu.my/id/eprint/26092/1/PPb_MUHAMMAD%20FAIZ%20ABD%20LATIF%20AS%20N%2017_5.pdf |
| first_indexed |
2023-09-18T23:16:09Z |
| last_indexed |
2023-09-18T23:16:09Z |
| _version_ |
1777419125667135488 |