Synthesis, characterization and antioxidant studies of copper(II) complex with schiff bases derived from 4-hydroxybenzaldehyde / Illuni Hayaty Ahmad

Three Schiff base ligands were suscesssfully synthesized by condensation reaction of 4-hydroxybenzaldehye with benzylamine, o-phenylenediamine and ethylenediamine in 1:1 and 2:1 ratio yielding 4-hbba, 4-hbopd and 4-hben, respectively. Metal complex of Cu(II) has been isolated with the 4-hbba ligand...

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Main Author: Ahmad, Illuni Hayaty
Format: Student Project
Language:English
Published: Faculty of Applied Sciences 2009
Subjects:
Online Access:http://ir.uitm.edu.my/id/eprint/23249/
http://ir.uitm.edu.my/id/eprint/23249/1/PPb_ILLUNI%20HAYATY%20AHMAD%20AS%2009_5.pdf
id uitm-23249
recordtype eprints
spelling uitm-232492019-02-22T02:21:01Z http://ir.uitm.edu.my/id/eprint/23249/ Synthesis, characterization and antioxidant studies of copper(II) complex with schiff bases derived from 4-hydroxybenzaldehyde / Illuni Hayaty Ahmad Ahmad, Illuni Hayaty Organic chemistry Three Schiff base ligands were suscesssfully synthesized by condensation reaction of 4-hydroxybenzaldehye with benzylamine, o-phenylenediamine and ethylenediamine in 1:1 and 2:1 ratio yielding 4-hbba, 4-hbopd and 4-hben, respectively. Metal complex of Cu(II) has been isolated with the 4-hbba ligand and all of the synthesized compounds are characterized by infrared spectroscopy, ¹H NMR, magnetic susceptibility and molar conductivity. It is proposed that the synthesized complex [Cu(4-hbba)(OAc)₂]₂.xH₂O, has a tetrahedral geometry. The synthesized compounds have been screened for antioxidant properties by comparing their activities with vitamin C, where the ligands 4-hben and 4-hbopd are found to possess some antioxidation activities. Faculty of Applied Sciences 2009 Student Project NonPeerReviewed text en http://ir.uitm.edu.my/id/eprint/23249/1/PPb_ILLUNI%20HAYATY%20AHMAD%20AS%2009_5.pdf Ahmad, Illuni Hayaty (2009) Synthesis, characterization and antioxidant studies of copper(II) complex with schiff bases derived from 4-hydroxybenzaldehyde / Illuni Hayaty Ahmad. [Student Project] (Unpublished)
repository_type Digital Repository
institution_category Local University
institution Universiti Teknologi MARA
building UiTM Institutional Repository
collection Online Access
language English
topic Organic chemistry
spellingShingle Organic chemistry
Ahmad, Illuni Hayaty
Synthesis, characterization and antioxidant studies of copper(II) complex with schiff bases derived from 4-hydroxybenzaldehyde / Illuni Hayaty Ahmad
description Three Schiff base ligands were suscesssfully synthesized by condensation reaction of 4-hydroxybenzaldehye with benzylamine, o-phenylenediamine and ethylenediamine in 1:1 and 2:1 ratio yielding 4-hbba, 4-hbopd and 4-hben, respectively. Metal complex of Cu(II) has been isolated with the 4-hbba ligand and all of the synthesized compounds are characterized by infrared spectroscopy, ¹H NMR, magnetic susceptibility and molar conductivity. It is proposed that the synthesized complex [Cu(4-hbba)(OAc)₂]₂.xH₂O, has a tetrahedral geometry. The synthesized compounds have been screened for antioxidant properties by comparing their activities with vitamin C, where the ligands 4-hben and 4-hbopd are found to possess some antioxidation activities.
format Student Project
author Ahmad, Illuni Hayaty
author_facet Ahmad, Illuni Hayaty
author_sort Ahmad, Illuni Hayaty
title Synthesis, characterization and antioxidant studies of copper(II) complex with schiff bases derived from 4-hydroxybenzaldehyde / Illuni Hayaty Ahmad
title_short Synthesis, characterization and antioxidant studies of copper(II) complex with schiff bases derived from 4-hydroxybenzaldehyde / Illuni Hayaty Ahmad
title_full Synthesis, characterization and antioxidant studies of copper(II) complex with schiff bases derived from 4-hydroxybenzaldehyde / Illuni Hayaty Ahmad
title_fullStr Synthesis, characterization and antioxidant studies of copper(II) complex with schiff bases derived from 4-hydroxybenzaldehyde / Illuni Hayaty Ahmad
title_full_unstemmed Synthesis, characterization and antioxidant studies of copper(II) complex with schiff bases derived from 4-hydroxybenzaldehyde / Illuni Hayaty Ahmad
title_sort synthesis, characterization and antioxidant studies of copper(ii) complex with schiff bases derived from 4-hydroxybenzaldehyde / illuni hayaty ahmad
publisher Faculty of Applied Sciences
publishDate 2009
url http://ir.uitm.edu.my/id/eprint/23249/
http://ir.uitm.edu.my/id/eprint/23249/1/PPb_ILLUNI%20HAYATY%20AHMAD%20AS%2009_5.pdf
first_indexed 2023-09-18T23:10:23Z
last_indexed 2023-09-18T23:10:23Z
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