The effect of alumina as filler in waste cooking oil-based polyurethane solid polymer electrolyte / Rosnasuha Mohd Nasir

In the present study, polyurethane (PU) had been prepared by using a different content of Aluminium Oxide (Ah03) filler, in order to examine the filler addition effect on the (SPE). The SPE has low ionic conductivity, so to enhance the conductivity, the filler was added. The solid polymer electro...

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Main Author: Mohd Nasir, Rosnasuha
Format: Student Project
Language:English
Published: Faculty Of Applied Sciences 2016
Subjects:
Online Access:http://ir.uitm.edu.my/id/eprint/23100/
http://ir.uitm.edu.my/id/eprint/23100/1/PPb_ROSNASUHA%20MOHD%20NASIR%20AS%20C%2016_5.PDF
id uitm-23100
recordtype eprints
spelling uitm-231002020-03-19T14:57:20Z http://ir.uitm.edu.my/id/eprint/23100/ The effect of alumina as filler in waste cooking oil-based polyurethane solid polymer electrolyte / Rosnasuha Mohd Nasir Mohd Nasir, Rosnasuha Polymers and polymer manufacture Oils, fats, and waxes In the present study, polyurethane (PU) had been prepared by using a different content of Aluminium Oxide (Ah03) filler, in order to examine the filler addition effect on the (SPE). The SPE has low ionic conductivity, so to enhance the conductivity, the filler was added. The solid polymer electrolyte is synthesized by solution casting technique. The SPE uses polyurethane (PU) as a host then doped with lithium perchlorate (LiCI04), ethylene carbonate (EC) as plasticizer, and aluminium oxide (Ah03) as filler. All solution use acetone as solvent. To determine the ionic conductivity of SPE, the Electrochemical Impedance Spectroscopy (EIS) was used. The highest conductivity is observed for the composition PU-LiCI04-EC-30% Ah03 with a value of2.379xlO-7 S/cm at room temperature. This is show that adding of filler can improved the ionic conductivity because the formation of adhance sites and conduction pathways are improve the for ionic transport by Lewis acid/base type interactions between the filler surface groups and the ionic species. Then to determine the functional group of the compound that contain in the SPE, its was characterized by using FTIR instrument. Thermal analysis (TGA) proved the occurence of chemical interaction of segmented PU solid polymer electrolyte. The conductivity is improve by mix of plasticizer (EC) to decrease the crystallinity and increasing the amorphous phase content of the SPE. The filler such as Ah03 is used to improve the conductivity by encouraging the structure in the SPE. These properties exhibited promising potential for ehhancement of SPE that giving focus on polyurethane Faculty Of Applied Sciences 2016-07 Student Project NonPeerReviewed text en http://ir.uitm.edu.my/id/eprint/23100/1/PPb_ROSNASUHA%20MOHD%20NASIR%20AS%20C%2016_5.PDF Mohd Nasir, Rosnasuha (2016) The effect of alumina as filler in waste cooking oil-based polyurethane solid polymer electrolyte / Rosnasuha Mohd Nasir. [Student Project] (Unpublished)
repository_type Digital Repository
institution_category Local University
institution Universiti Teknologi MARA
building UiTM Institutional Repository
collection Online Access
language English
topic Polymers and polymer manufacture
Oils, fats, and waxes
spellingShingle Polymers and polymer manufacture
Oils, fats, and waxes
Mohd Nasir, Rosnasuha
The effect of alumina as filler in waste cooking oil-based polyurethane solid polymer electrolyte / Rosnasuha Mohd Nasir
description In the present study, polyurethane (PU) had been prepared by using a different content of Aluminium Oxide (Ah03) filler, in order to examine the filler addition effect on the (SPE). The SPE has low ionic conductivity, so to enhance the conductivity, the filler was added. The solid polymer electrolyte is synthesized by solution casting technique. The SPE uses polyurethane (PU) as a host then doped with lithium perchlorate (LiCI04), ethylene carbonate (EC) as plasticizer, and aluminium oxide (Ah03) as filler. All solution use acetone as solvent. To determine the ionic conductivity of SPE, the Electrochemical Impedance Spectroscopy (EIS) was used. The highest conductivity is observed for the composition PU-LiCI04-EC-30% Ah03 with a value of2.379xlO-7 S/cm at room temperature. This is show that adding of filler can improved the ionic conductivity because the formation of adhance sites and conduction pathways are improve the for ionic transport by Lewis acid/base type interactions between the filler surface groups and the ionic species. Then to determine the functional group of the compound that contain in the SPE, its was characterized by using FTIR instrument. Thermal analysis (TGA) proved the occurence of chemical interaction of segmented PU solid polymer electrolyte. The conductivity is improve by mix of plasticizer (EC) to decrease the crystallinity and increasing the amorphous phase content of the SPE. The filler such as Ah03 is used to improve the conductivity by encouraging the structure in the SPE. These properties exhibited promising potential for ehhancement of SPE that giving focus on polyurethane
format Student Project
author Mohd Nasir, Rosnasuha
author_facet Mohd Nasir, Rosnasuha
author_sort Mohd Nasir, Rosnasuha
title The effect of alumina as filler in waste cooking oil-based polyurethane solid polymer electrolyte / Rosnasuha Mohd Nasir
title_short The effect of alumina as filler in waste cooking oil-based polyurethane solid polymer electrolyte / Rosnasuha Mohd Nasir
title_full The effect of alumina as filler in waste cooking oil-based polyurethane solid polymer electrolyte / Rosnasuha Mohd Nasir
title_fullStr The effect of alumina as filler in waste cooking oil-based polyurethane solid polymer electrolyte / Rosnasuha Mohd Nasir
title_full_unstemmed The effect of alumina as filler in waste cooking oil-based polyurethane solid polymer electrolyte / Rosnasuha Mohd Nasir
title_sort effect of alumina as filler in waste cooking oil-based polyurethane solid polymer electrolyte / rosnasuha mohd nasir
publisher Faculty Of Applied Sciences
publishDate 2016
url http://ir.uitm.edu.my/id/eprint/23100/
http://ir.uitm.edu.my/id/eprint/23100/1/PPb_ROSNASUHA%20MOHD%20NASIR%20AS%20C%2016_5.PDF
first_indexed 2023-09-18T23:10:03Z
last_indexed 2023-09-18T23:10:03Z
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