Tio2 powder photocatalyst from sol-gel route and its immobilisation with cement for photocatalytic phenol removal
Two types of TiO2 powders of water-to-TPT ratios (Powder 1: water/TPT = 1 and Powder 2: water/TPT= 2) were synthesized via sol-gel method. The effect of hydrolysis degree on the formation of TiO2 powder particles was investigated using various physical-chemical characterization methods. The synthesi...
Main Authors: | , , , |
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Format: | Article |
Language: | English |
Published: |
The Instituition of Engineers Malaysia
2009
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Subjects: | |
Online Access: | http://irep.iium.edu.my/918/ http://irep.iium.edu.my/918/ http://irep.iium.edu.my/918/1/TiO2_POWDER_PHOTOCATALYST_FROM_SOL-GEL_ROUTE_AND_ITS_IMMOBILIsATION_WITH_CEMENT_FOR.pdf |
Summary: | Two types of TiO2 powders of water-to-TPT ratios (Powder 1: water/TPT = 1 and Powder 2: water/TPT= 2) were synthesized via sol-gel method. The effect of hydrolysis degree on the formation of TiO2 powder particles was investigated using various physical-chemical characterization methods. The synthesized powders were then immobilised by mixing them with cement to be cement-bonded TiO2 photocatalyst. For photocatalytic measurement, phenol solution was selected as a model of pollutant to be degraded by both cement-bonded TiO2 photocatalysts to analyse their photocatalytic efficiency. The photodegradation of phenol test revealed cement-bonded TiO2 Powder 2 was more efficient than Powder 1 due to its high crystallinity which can lead to faster charge separation and the increased number of phenol molecules adsorbed. |
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