Adsortion of lead onto Xanthated modified Rubber (Hevea Brasiliensis) powder

Rubber (Hevea brasiliensis) leaf powder was modified by xanthation process and its potential in removing toxic Pb(II) ion from aqueous solutions was investigated in batch experiments. Pb(II) adsorption efficiency was found to be affected by several physicochemical parameters such as adsorbent dosage...

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Main Authors: Wan Mohd Khalir, Wan Khaima Azira, Megat Hanafiah, Megat Ahmad Kamal, Mat So'ad, Siti Zaiton, Wan Ngah, Wan Saime, Abdul Majid, Zafri Azran
Format: Conference or Workshop Item
Language:English
Published: Asian Network for Scientific Information 2011
Subjects:
Online Access:http://irep.iium.edu.my/8033/
http://irep.iium.edu.my/8033/1/KHALIR_ET_AL_110811.pdf
id iium-8033
recordtype eprints
spelling iium-80332013-08-03T23:27:21Z http://irep.iium.edu.my/8033/ Adsortion of lead onto Xanthated modified Rubber (Hevea Brasiliensis) powder Wan Mohd Khalir, Wan Khaima Azira Megat Hanafiah, Megat Ahmad Kamal Mat So'ad, Siti Zaiton Wan Ngah, Wan Saime Abdul Majid, Zafri Azran QD Chemistry Rubber (Hevea brasiliensis) leaf powder was modified by xanthation process and its potential in removing toxic Pb(II) ion from aqueous solutions was investigated in batch experiments. Pb(II) adsorption efficiency was found to be affected by several physicochemical parameters such as adsorbent dosage, shaking rate and temperature. The optimum adsorbent dosage was found to be at 0.02 g with more than 80 % Pb(II) removal. The amount of Pb(II) adsorbed (mg/g) increased with increasing agitation rate but decreased with increasing adsorbent dosage and temperature. Thermodynamic parameters such as enthalpy change (ΔHº), free energy change (ΔGº) and entropy change (ΔSº) were computed and Pb(II) adsorption process was found to be exothermic. Fixed-bed column fitted well the Thomas and Yoon-Nelson models with correlation coefficients of R2 > 0.95. Key words: Adsorption; Lead; Rubber leaf powder; Thermodynamic; Xanthation Asian Network for Scientific Information 2011 Conference or Workshop Item PeerReviewed application/pdf en http://irep.iium.edu.my/8033/1/KHALIR_ET_AL_110811.pdf Wan Mohd Khalir, Wan Khaima Azira and Megat Hanafiah, Megat Ahmad Kamal and Mat So'ad, Siti Zaiton and Wan Ngah, Wan Saime and Abdul Majid, Zafri Azran (2011) Adsortion of lead onto Xanthated modified Rubber (Hevea Brasiliensis) powder. In: ICCEIB -SOMChE 2011, 28 Nov. - 1 Dec., 2011, Universiti Malaysia Pahang.
repository_type Digital Repository
institution_category Local University
institution International Islamic University Malaysia
building IIUM Repository
collection Online Access
language English
topic QD Chemistry
spellingShingle QD Chemistry
Wan Mohd Khalir, Wan Khaima Azira
Megat Hanafiah, Megat Ahmad Kamal
Mat So'ad, Siti Zaiton
Wan Ngah, Wan Saime
Abdul Majid, Zafri Azran
Adsortion of lead onto Xanthated modified Rubber (Hevea Brasiliensis) powder
description Rubber (Hevea brasiliensis) leaf powder was modified by xanthation process and its potential in removing toxic Pb(II) ion from aqueous solutions was investigated in batch experiments. Pb(II) adsorption efficiency was found to be affected by several physicochemical parameters such as adsorbent dosage, shaking rate and temperature. The optimum adsorbent dosage was found to be at 0.02 g with more than 80 % Pb(II) removal. The amount of Pb(II) adsorbed (mg/g) increased with increasing agitation rate but decreased with increasing adsorbent dosage and temperature. Thermodynamic parameters such as enthalpy change (ΔHº), free energy change (ΔGº) and entropy change (ΔSº) were computed and Pb(II) adsorption process was found to be exothermic. Fixed-bed column fitted well the Thomas and Yoon-Nelson models with correlation coefficients of R2 > 0.95. Key words: Adsorption; Lead; Rubber leaf powder; Thermodynamic; Xanthation
format Conference or Workshop Item
author Wan Mohd Khalir, Wan Khaima Azira
Megat Hanafiah, Megat Ahmad Kamal
Mat So'ad, Siti Zaiton
Wan Ngah, Wan Saime
Abdul Majid, Zafri Azran
author_facet Wan Mohd Khalir, Wan Khaima Azira
Megat Hanafiah, Megat Ahmad Kamal
Mat So'ad, Siti Zaiton
Wan Ngah, Wan Saime
Abdul Majid, Zafri Azran
author_sort Wan Mohd Khalir, Wan Khaima Azira
title Adsortion of lead onto Xanthated modified Rubber (Hevea Brasiliensis) powder
title_short Adsortion of lead onto Xanthated modified Rubber (Hevea Brasiliensis) powder
title_full Adsortion of lead onto Xanthated modified Rubber (Hevea Brasiliensis) powder
title_fullStr Adsortion of lead onto Xanthated modified Rubber (Hevea Brasiliensis) powder
title_full_unstemmed Adsortion of lead onto Xanthated modified Rubber (Hevea Brasiliensis) powder
title_sort adsortion of lead onto xanthated modified rubber (hevea brasiliensis) powder
publisher Asian Network for Scientific Information
publishDate 2011
url http://irep.iium.edu.my/8033/
http://irep.iium.edu.my/8033/1/KHALIR_ET_AL_110811.pdf
first_indexed 2023-09-18T20:17:38Z
last_indexed 2023-09-18T20:17:38Z
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