Zinc-air cell employing laccase as the oxygen reduction catalyst

Zinc-air cell employing laccase enzyme as the oxygen reduction catalyst has been investigated. Laccase is an oxidoreductase, belongs to the copper-containing enzyme family which attracts many due to its ability to reduce molecular oxygen to water. The test cell consisted of zinc metal foil as the an...

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Bibliographic Details
Main Authors: Ahmad, Abdul Aziz, Yusof, Faridah, Abd. Wahab, Mohd. Firdaus, Othman, Raihan
Format: Conference or Workshop Item
Language:English
Published: 2010
Subjects:
Online Access:http://irep.iium.edu.my/6711/
http://irep.iium.edu.my/6711/
http://irep.iium.edu.my/6711/1/ICFMD2010_Aziz_6711.pdf
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Summary:Zinc-air cell employing laccase enzyme as the oxygen reduction catalyst has been investigated. Laccase is an oxidoreductase, belongs to the copper-containing enzyme family which attracts many due to its ability to reduce molecular oxygen to water. The test cell consisted of zinc metal foil as the anode and a carbon-based air electrode as the cathode, encapsulated in a single chamber, home-made acrylic board casing. The electrolyte composed of laccase and syringaldazine in a potassium dihydrogen phosphate buffer. The performance of the cell was also evaluated using sodium citrate buffer and potassium citrate buffer. Zinc-air cell utilizing laccase biocatalyst registered an open circuit voltage of 1.2 V and was able to sustain a discharge load of 500 A.