Surface functionalisation of Microfibrillated Cellulose (MFC) of cocoa pod husk with Ƴ-Methacryloxypropyltrimethoxysilane (MPS)

Significant growing on environmental awareness has led researchers to study the surface functionalisation of cellulose nanofiber using natural renewable resources. This study aims to improve the percentage swelling of microfibrillated cellulose (MFC) of cocoa pod husks, crops-by product with Ƴ- meth...

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Main Authors:	Syed Putra, Sharifah Shahira, Jimat, Dzun Noraini, Wan Nawawi, Wan Mohd Fazli, Sulaiman, Sarina, Jamal, Parveen, Ahmad Nor, Yusilawati
Format:	Conference or Workshop Item
Language:	English English English
Published:	Elsevier Doyma 2018
Subjects:	TA401 Materials of engineering and construction TP1080 Polymers, plastics and their manufacture
Online Access:	http://irep.iium.edu.my/59637/ http://irep.iium.edu.my/59637/ http://irep.iium.edu.my/59637/13/59637_Surface%20Functionalisation.pdf http://irep.iium.edu.my/59637/19/59637_Surface%20functionalisation%20of%20Microfibrillated%20Cellulose.pdf http://irep.iium.edu.my/59637/25/59637_Surface%20functionalisation%20of%20microfibrillated%20cellulose%20%28MFC%29%20_scopus.pdf

id	iium-59637
recordtype	eprints
spelling	iium-596372018-12-31T05:51:23Z http://irep.iium.edu.my/59637/ Surface functionalisation of Microfibrillated Cellulose (MFC) of cocoa pod husk with Ƴ-Methacryloxypropyltrimethoxysilane (MPS) Syed Putra, Sharifah Shahira Jimat, Dzun Noraini Wan Nawawi, Wan Mohd Fazli Sulaiman, Sarina Jamal, Parveen Ahmad Nor, Yusilawati TA401 Materials of engineering and construction TP1080 Polymers, plastics and their manufacture Significant growing on environmental awareness has led researchers to study the surface functionalisation of cellulose nanofiber using natural renewable resources. This study aims to improve the percentage swelling of microfibrillated cellulose (MFC) of cocoa pod husks, crops-by product with Ƴ- methacryloxypropyltrimethoxysilane (MPS). Investigation on the effect of cocoa pod husk (CPH) microfibrillated cellulose (MFC-CPH) amount, MPS amount, MPS concentration and the reaction time to the percentage of swelling property of MFC-CPH treated with MPS was carried out. Composition amount of CPH -MFC, MPS, MPS concentration and the reaction time were varied from range of 0.5-6 gram, 1-9 mL, 5-15 w/w % and 2-24 hours respectively. Based on evaluation of percentage swelling obtained, it showed that the surface hydrophobicity of MFC-CPH treated with MPS could be increased due to the chemical bonds interaction that formed during silane treatment. The lowest percentage swelling of treated MFC-CPH-MPS is 14.96 % and the highest is 94.87 %. The untreated and treated MFC-CPH were then observed using fourier transform infrared (FT-IR) and field emission scanning electron microscopy (FESEM) for any change of structural and morphology. FT-IR results shows that there is reduction of OH groups in cellulose and addition of Si groups after silane treatment. There is also a change on the surface of MFC-CPH fibers after silane treatment as MFC-CPH fibers surface become rough due to deposited of MPS on MFC-CPH fibers. Elsevier Doyma 2018-03-04 Conference or Workshop Item PeerReviewed application/pdf en http://irep.iium.edu.my/59637/13/59637_Surface%20Functionalisation.pdf application/pdf en http://irep.iium.edu.my/59637/19/59637_Surface%20functionalisation%20of%20Microfibrillated%20Cellulose.pdf application/pdf en http://irep.iium.edu.my/59637/25/59637_Surface%20functionalisation%20of%20microfibrillated%20cellulose%20%28MFC%29%20_scopus.pdf Syed Putra, Sharifah Shahira and Jimat, Dzun Noraini and Wan Nawawi, Wan Mohd Fazli and Sulaiman, Sarina and Jamal, Parveen and Ahmad Nor, Yusilawati (2018) Surface functionalisation of Microfibrillated Cellulose (MFC) of cocoa pod husk with Ƴ-Methacryloxypropyltrimethoxysilane (MPS). In: The 3rd International Conference on Green Chemical Engineering and Technology (GCET 2017), 7th-8th Nov. 2017, Swiss-Garden Hotel Melaka. https://www.journals.elsevier.com/materials-today-proceedings/special-issues
repository_type	Digital Repository
institution_category	Local University
institution	International Islamic University Malaysia
building	IIUM Repository
collection	Online Access
language	English English English
topic	TA401 Materials of engineering and construction TP1080 Polymers, plastics and their manufacture
spellingShingle	TA401 Materials of engineering and construction TP1080 Polymers, plastics and their manufacture Syed Putra, Sharifah Shahira Jimat, Dzun Noraini Wan Nawawi, Wan Mohd Fazli Sulaiman, Sarina Jamal, Parveen Ahmad Nor, Yusilawati Surface functionalisation of Microfibrillated Cellulose (MFC) of cocoa pod husk with Ƴ-Methacryloxypropyltrimethoxysilane (MPS)
description	Significant growing on environmental awareness has led researchers to study the surface functionalisation of cellulose nanofiber using natural renewable resources. This study aims to improve the percentage swelling of microfibrillated cellulose (MFC) of cocoa pod husks, crops-by product with Ƴ- methacryloxypropyltrimethoxysilane (MPS). Investigation on the effect of cocoa pod husk (CPH) microfibrillated cellulose (MFC-CPH) amount, MPS amount, MPS concentration and the reaction time to the percentage of swelling property of MFC-CPH treated with MPS was carried out. Composition amount of CPH -MFC, MPS, MPS concentration and the reaction time were varied from range of 0.5-6 gram, 1-9 mL, 5-15 w/w % and 2-24 hours respectively. Based on evaluation of percentage swelling obtained, it showed that the surface hydrophobicity of MFC-CPH treated with MPS could be increased due to the chemical bonds interaction that formed during silane treatment. The lowest percentage swelling of treated MFC-CPH-MPS is 14.96 % and the highest is 94.87 %. The untreated and treated MFC-CPH were then observed using fourier transform infrared (FT-IR) and field emission scanning electron microscopy (FESEM) for any change of structural and morphology. FT-IR results shows that there is reduction of OH groups in cellulose and addition of Si groups after silane treatment. There is also a change on the surface of MFC-CPH fibers after silane treatment as MFC-CPH fibers surface become rough due to deposited of MPS on MFC-CPH fibers.
format	Conference or Workshop Item
author	Syed Putra, Sharifah Shahira Jimat, Dzun Noraini Wan Nawawi, Wan Mohd Fazli Sulaiman, Sarina Jamal, Parveen Ahmad Nor, Yusilawati
author_facet	Syed Putra, Sharifah Shahira Jimat, Dzun Noraini Wan Nawawi, Wan Mohd Fazli Sulaiman, Sarina Jamal, Parveen Ahmad Nor, Yusilawati
author_sort	Syed Putra, Sharifah Shahira
title	Surface functionalisation of Microfibrillated Cellulose (MFC) of cocoa pod husk with Ƴ-Methacryloxypropyltrimethoxysilane (MPS)
title_short	Surface functionalisation of Microfibrillated Cellulose (MFC) of cocoa pod husk with Ƴ-Methacryloxypropyltrimethoxysilane (MPS)
title_full	Surface functionalisation of Microfibrillated Cellulose (MFC) of cocoa pod husk with Ƴ-Methacryloxypropyltrimethoxysilane (MPS)
title_fullStr	Surface functionalisation of Microfibrillated Cellulose (MFC) of cocoa pod husk with Ƴ-Methacryloxypropyltrimethoxysilane (MPS)
title_full_unstemmed	Surface functionalisation of Microfibrillated Cellulose (MFC) of cocoa pod husk with Ƴ-Methacryloxypropyltrimethoxysilane (MPS)
title_sort	surface functionalisation of microfibrillated cellulose (mfc) of cocoa pod husk with ƴ-methacryloxypropyltrimethoxysilane (mps)
publisher	Elsevier Doyma
publishDate	2018
url	http://irep.iium.edu.my/59637/ http://irep.iium.edu.my/59637/ http://irep.iium.edu.my/59637/13/59637_Surface%20Functionalisation.pdf http://irep.iium.edu.my/59637/19/59637_Surface%20functionalisation%20of%20Microfibrillated%20Cellulose.pdf http://irep.iium.edu.my/59637/25/59637_Surface%20functionalisation%20of%20microfibrillated%20cellulose%20%28MFC%29%20_scopus.pdf
first_indexed	2023-09-18T21:24:30Z
last_indexed	2023-09-18T21:24:30Z
_version_	1777412100848615424

Surface functionalisation of Microfibrillated Cellulose (MFC) of cocoa pod husk with Ƴ-Methacryloxypropyltrimethoxysilane (MPS)

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