Development of a methane-free, continuous biohydrogen production system from palm oil mill effluent (Pome) in cstr
This study aimed to develop the start-up experiment for producing biological hydrogen in 2 L continuous stirred tank reactor (CSTR) from palm oil mill effluent (POME) by the use of mixed culture sludge under non-sterile conditions. Besides using different source of starter culture, the effects of ac...
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iium-588362017-10-20T04:14:36Z http://irep.iium.edu.my/58836/ Development of a methane-free, continuous biohydrogen production system from palm oil mill effluent (Pome) in cstr Mansor, Mariatul Fadzillah Md Jahim, Jamaliah Mumtaz, Tabassum Abd Rahman, Rakmi Abd Mutalib, Sahilah TD Environmental technology. Sanitary engineering TP315 Fuel TP670 Oils, fats, waxes This study aimed to develop the start-up experiment for producing biological hydrogen in 2 L continuous stirred tank reactor (CSTR) from palm oil mill effluent (POME) by the use of mixed culture sludge under non-sterile conditions. Besides using different source of starter culture, the effects of acid treated culture and various operating temperature from 35 °C to 55 °C were studied against the evolved gas in terms of volumetric H2production rate (VHPR) and soluble metabolite products (SMPs). The formation of methane was closely observed throughout the run. Within the studied temperature, VHPR was found as low as 0.71 L/L.d and ethanol was the main by-products (70-80% of total soluble metabolites). Attempts were made to produce biohydrogen without methane formation at higher thermophilic temperature (45-55 °C) than the previous range. The average of 1.7 L H2of 2 L working volume per day was produced at 55oC with VHPR of 1.16 L/L.d. The results of soluble metabolites also are in agreement with the volatile fatty acids (VFAs) which is higher than ethanol. Higher VFAs of 2269 mg/L was obtained with acetic acid being the main by-product. At this time methanogen has been deactivated and no methane was produced. From this study, it can be concluded that thermophilic environment may offer a better option in a way to eliminate methane from the biogas and at the same time improving hydrogen production rate as well. Taylor's University College 2016-08 Article PeerReviewed application/pdf en http://irep.iium.edu.my/58836/1/58836_DEVELOPMENT%20OF%20A%20METHANE-FREE_article.pdf application/pdf en http://irep.iium.edu.my/58836/2/58836_DEVELOPMENT%20OF%20A%20METHANE-FREE_scopus.pdf application/pdf en http://irep.iium.edu.my/58836/3/58836_DEVELOPMENT%20OF%20A%20METHANE-FREE_wos.pdf Mansor, Mariatul Fadzillah and Md Jahim, Jamaliah and Mumtaz, Tabassum and Abd Rahman, Rakmi and Abd Mutalib, Sahilah (2016) Development of a methane-free, continuous biohydrogen production system from palm oil mill effluent (Pome) in cstr. Journal of Engineering Science and Technology, 11 (8). pp. 1174-1182. ISSN 1823-4690 http://jestec.taylors.edu.my/Vol%2011%20issue%208%20August%202016/11_8_9.pdf |
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TD Environmental technology. Sanitary engineering TP315 Fuel TP670 Oils, fats, waxes |
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TD Environmental technology. Sanitary engineering TP315 Fuel TP670 Oils, fats, waxes Mansor, Mariatul Fadzillah Md Jahim, Jamaliah Mumtaz, Tabassum Abd Rahman, Rakmi Abd Mutalib, Sahilah Development of a methane-free, continuous biohydrogen production system from palm oil mill effluent (Pome) in cstr |
description |
This study aimed to develop the start-up experiment for producing biological hydrogen in 2 L continuous stirred tank reactor (CSTR) from palm oil mill effluent (POME) by the use of mixed culture sludge under non-sterile conditions. Besides using different source of starter culture, the effects of acid treated culture and various operating temperature from 35 °C to 55 °C were studied against the evolved gas in terms of volumetric H2production rate (VHPR) and soluble metabolite products (SMPs). The formation of methane was closely observed throughout the run. Within the studied temperature, VHPR was found as low as 0.71 L/L.d and ethanol was the main by-products (70-80% of total soluble metabolites). Attempts were made to produce biohydrogen without methane formation at higher thermophilic temperature (45-55 °C) than the previous range. The average of 1.7 L H2of 2 L working volume per day was produced at 55oC with VHPR of 1.16 L/L.d. The results of soluble metabolites also are in agreement with the volatile fatty acids (VFAs) which is higher than ethanol. Higher VFAs of 2269 mg/L was obtained with acetic acid being the main by-product. At this time methanogen has been deactivated and no methane was produced. From this study, it can be concluded that thermophilic environment may offer a better option in a way to eliminate methane from the biogas and at the same time improving hydrogen production rate as well. |
format |
Article |
author |
Mansor, Mariatul Fadzillah Md Jahim, Jamaliah Mumtaz, Tabassum Abd Rahman, Rakmi Abd Mutalib, Sahilah |
author_facet |
Mansor, Mariatul Fadzillah Md Jahim, Jamaliah Mumtaz, Tabassum Abd Rahman, Rakmi Abd Mutalib, Sahilah |
author_sort |
Mansor, Mariatul Fadzillah |
title |
Development of a methane-free, continuous biohydrogen production system from palm oil mill effluent (Pome) in cstr |
title_short |
Development of a methane-free, continuous biohydrogen production system from palm oil mill effluent (Pome) in cstr |
title_full |
Development of a methane-free, continuous biohydrogen production system from palm oil mill effluent (Pome) in cstr |
title_fullStr |
Development of a methane-free, continuous biohydrogen production system from palm oil mill effluent (Pome) in cstr |
title_full_unstemmed |
Development of a methane-free, continuous biohydrogen production system from palm oil mill effluent (Pome) in cstr |
title_sort |
development of a methane-free, continuous biohydrogen production system from palm oil mill effluent (pome) in cstr |
publisher |
Taylor's University College |
publishDate |
2016 |
url |
http://irep.iium.edu.my/58836/ http://irep.iium.edu.my/58836/ http://irep.iium.edu.my/58836/1/58836_DEVELOPMENT%20OF%20A%20METHANE-FREE_article.pdf http://irep.iium.edu.my/58836/2/58836_DEVELOPMENT%20OF%20A%20METHANE-FREE_scopus.pdf http://irep.iium.edu.my/58836/3/58836_DEVELOPMENT%20OF%20A%20METHANE-FREE_wos.pdf |
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2023-09-18T21:23:15Z |
last_indexed |
2023-09-18T21:23:15Z |
_version_ |
1777412022468608000 |