The influence of irradiated recycled polypropylene compatibilizer on the impact fracture behavior of recycled polypropylene/microcrystalline cellulose composites
The poor compatibility between a thermoplastic matrix and natural fiber reinforcement has been a limitation in the optimization of natural fiber-filled composites. Electron beam irradiation is used to modify the structure of materials. However, most researches have focused on the effect of irradiati...
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John Wiley and Sons Inc.
2019
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iium-581912019-05-13T06:13:00Z http://irep.iium.edu.my/58191/ The influence of irradiated recycled polypropylene compatibilizer on the impact fracture behavior of recycled polypropylene/microcrystalline cellulose composites Lazim, Nurul Hakimah Samat, Noorasikin TP1080 Polymers, plastics and their manufacture The poor compatibility between a thermoplastic matrix and natural fiber reinforcement has been a limitation in the optimization of natural fiber-filled composites. Electron beam irradiation is used to modify the structure of materials. However, most researches have focused on the effect of irradiation after the fabrication of composites. Hence, this study was aimed at investigating the effect of irradiated recycled polypropylene (i-rPP) as a compatibilizer in recycled polypropylene (rPP) composites. The rPP were irradiated at different doses before the compounding process. The rPP matrices were prepared by mixing the unirradiated and irradiated rPP at ratios of 90:10 and 50:50, before they were compounded with different amounts of microcrystalline cellulose (MCC) fibers (5, 20, and 40 wt%). Radiation crosslinking, functional groups, radical formations, thermal, and impact strength characterizations were carried out. The results showed that the simultaneous incorporation of the i-rPP and MCC fibers significantly improved the impact resistance of the rPP. The synergistic combination of a higher MCC content (40 wt%) and low irradiation dose (10 kGy) at a ratio of 50:50 caused a higher degree of crosslinking and a lower radical concentration. The thermal stability was acceptable and the sub-impact fracture surface analysis revealed the effects of crack blunting. John Wiley and Sons Inc. 2019-01 Article PeerReviewed application/pdf en http://irep.iium.edu.my/58191/1/58191_The%20influence%20of%20irradiated%20recycled%20polypropylene_article.pdf application/pdf en http://irep.iium.edu.my/58191/2/58191_The%20influence%20of%20irradiated%20recycled%20polypropylene_wos.pdf application/pdf en http://irep.iium.edu.my/58191/3/58191_The%20influence%20of%20irradiated%20recycled%20polypropylene_scopus.pdf Lazim, Nurul Hakimah and Samat, Noorasikin (2019) The influence of irradiated recycled polypropylene compatibilizer on the impact fracture behavior of recycled polypropylene/microcrystalline cellulose composites. Polymer Composites, 40. E24-E34. ISSN 0272-8397 E-ISSN 1548-0569 https://onlinelibrary.wiley.com/doi/full/10.1002/pc.24430 10.1002/pc.24430 |
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Digital Repository |
| institution_category |
Local University |
| institution |
International Islamic University Malaysia |
| building |
IIUM Repository |
| collection |
Online Access |
| language |
English English English |
| topic |
TP1080 Polymers, plastics and their manufacture |
| spellingShingle |
TP1080 Polymers, plastics and their manufacture Lazim, Nurul Hakimah Samat, Noorasikin The influence of irradiated recycled polypropylene compatibilizer on the impact fracture behavior of recycled polypropylene/microcrystalline cellulose composites |
| description |
The poor compatibility between a thermoplastic matrix and natural fiber reinforcement has been a limitation in the optimization of natural fiber-filled composites. Electron beam irradiation is used to modify the structure of materials. However, most researches have focused on the effect of irradiation after the fabrication of composites. Hence, this study was aimed at investigating the effect of irradiated recycled polypropylene (i-rPP) as a compatibilizer in recycled polypropylene (rPP) composites. The rPP were irradiated at different doses before the compounding process. The rPP matrices were prepared by mixing the unirradiated and irradiated rPP at ratios of 90:10 and 50:50, before they were compounded with different amounts of microcrystalline cellulose (MCC) fibers (5, 20, and 40 wt%). Radiation crosslinking, functional groups, radical formations, thermal, and impact strength characterizations were carried out. The results showed that the simultaneous incorporation of the i-rPP and MCC fibers significantly improved the impact resistance of the rPP. The synergistic combination of a higher MCC content (40 wt%) and low irradiation dose (10 kGy) at a ratio of 50:50 caused a higher degree of crosslinking and a lower radical concentration. The thermal stability was acceptable and the sub-impact fracture surface analysis revealed the effects of crack blunting. |
| format |
Article |
| author |
Lazim, Nurul Hakimah Samat, Noorasikin |
| author_facet |
Lazim, Nurul Hakimah Samat, Noorasikin |
| author_sort |
Lazim, Nurul Hakimah |
| title |
The influence of irradiated recycled polypropylene compatibilizer on the impact fracture behavior of recycled polypropylene/microcrystalline cellulose composites |
| title_short |
The influence of irradiated recycled polypropylene compatibilizer on the impact fracture behavior of recycled polypropylene/microcrystalline cellulose composites |
| title_full |
The influence of irradiated recycled polypropylene compatibilizer on the impact fracture behavior of recycled polypropylene/microcrystalline cellulose composites |
| title_fullStr |
The influence of irradiated recycled polypropylene compatibilizer on the impact fracture behavior of recycled polypropylene/microcrystalline cellulose composites |
| title_full_unstemmed |
The influence of irradiated recycled polypropylene compatibilizer on the impact fracture behavior of recycled polypropylene/microcrystalline cellulose composites |
| title_sort |
influence of irradiated recycled polypropylene compatibilizer on the impact fracture behavior of recycled polypropylene/microcrystalline cellulose composites |
| publisher |
John Wiley and Sons Inc. |
| publishDate |
2019 |
| url |
http://irep.iium.edu.my/58191/ http://irep.iium.edu.my/58191/ http://irep.iium.edu.my/58191/ http://irep.iium.edu.my/58191/1/58191_The%20influence%20of%20irradiated%20recycled%20polypropylene_article.pdf http://irep.iium.edu.my/58191/2/58191_The%20influence%20of%20irradiated%20recycled%20polypropylene_wos.pdf http://irep.iium.edu.my/58191/3/58191_The%20influence%20of%20irradiated%20recycled%20polypropylene_scopus.pdf |
| first_indexed |
2023-09-18T21:22:16Z |
| last_indexed |
2023-09-18T21:22:16Z |
| _version_ |
1777411960566972416 |