Synthesis, NMR spectroscopy and crystal structures studies of 2-amino-N-(2-hydroxy-3-methoxybenzylidene) aniline
The reaction of o–vanillin 1 with o-phenylenediamine 2PD, in dichloromethane at low conditions produced novel amino benzeneamine: 2-amino-N-(2-hydroxy-3-methoxybenzylidene) aniline 2. Intermediate 2 is isolated and obtained as single crystals and the structure was determined and studied by x-ray cr...
| Main Authors: | , , |
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| Format: | Conference or Workshop Item |
| Language: | English |
| Published: |
2009
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| Subjects: | |
| Online Access: | http://irep.iium.edu.my/5354/ http://irep.iium.edu.my/5354/ http://irep.iium.edu.my/5354/2/IEEE_Proceedings-Mohammad%5B1extract%5D.pdf |
| Summary: | The reaction of o–vanillin 1 with o-phenylenediamine
2PD, in dichloromethane at low conditions produced novel amino benzeneamine: 2-amino-N-(2-hydroxy-3-methoxybenzylidene) aniline 2. Intermediate 2 is isolated and obtained as single crystals and the structure was determined and studied by x-ray crystallography. The complete assignments of 2 were made using FTIR, HRMS, 1D and 2D NMR including APT, COSY, HMQC and HMBC in CDCl3 and will be discussed. |
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