Enhancement of reflectance of densified vertically aligned carbon nanotube forests

Vertically aligned carbon nanotubes (VACNTs), also known as a carbon nanotube (CNT) forest, are a porous material that is well known for its exceptional optical absorbance property. The reflectance from a VACNT forest has been reported to be as low as 0.045% [1,2]. It is known as the darkest mate...

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Main Authors: Rana, Masud, M Razib, M Asyraf, Saleh, Tanveer, Asan Gani, Abdul Muthalif
Format: Article
Language:English
English
Published: Korean Carbon Society 2016
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Online Access:http://irep.iium.edu.my/50573/
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spelling iium-505732017-03-21T10:00:51Z http://irep.iium.edu.my/50573/ Enhancement of reflectance of densified vertically aligned carbon nanotube forests Rana, Masud M Razib, M Asyraf Saleh, Tanveer Asan Gani, Abdul Muthalif T Technology (General) Vertically aligned carbon nanotubes (VACNTs), also known as a carbon nanotube (CNT) forest, are a porous material that is well known for its exceptional optical absorbance property. The reflectance from a VACNT forest has been reported to be as low as 0.045% [1,2]. It is known as the darkest material on Earth. Because of its remarkable material properties, it has various other applications as gas sensors [3], pressure sensors [4], temperature sensors [5], and strain sensors [6]. Recently, various efforts have been made to mechanically manipulate the vertical structure of the nanotubes in the CNT forest and to conduct their optical characterization [7,8]. Optical reflection from bare VACNTs has also been investigated at different wavelengths by Wąsik et al. [9]. Controlled densification by wetting of the CNT forest is another post processing technique that has been reported by other researchers [10]. A densification process is necessary to make the CNT forest useful as a future electronics interconnect [10]. However, no study has been done so far on the optical behavior of CNT forests densified by a wetting process. In this letter, for the first time, we investigate and explain the nature of the optical reflectance of densified VACNTs. Fig. 1 illustrates how the CNT forest is able to absorb most incident light. It was reported elsewhere that VACNT arrays are highly porous [11]. As a result, when incident light enters the bare CNT forest, it goes through several internal reflection-absorption cycles via individual nanotubes and finally makes its way out of the CNT forest as shown in Fig. 1b. Hence, a very low amount of light bounces back (approximately 0.045%) [1,2]. Mathematically, a simple model can be developed to estimate the final amount of light coming out of a CNT forest after several internal reflections; this process is explained by eq (1): Korean Carbon Society 2016-04-30 Article PeerReviewed application/pdf en http://irep.iium.edu.my/50573/1/%5B67-70%5D-11.pdf application/pdf en http://irep.iium.edu.my/50573/4/50573-Enhancement%20of%20reflectance%20of%20densified%20vertically%20aligned%20carbon%20nanotube%20forests_SCOPUS.pdf Rana, Masud and M Razib, M Asyraf and Saleh, Tanveer and Asan Gani, Abdul Muthalif (2016) Enhancement of reflectance of densified vertically aligned carbon nanotube forests. Carbon Letters, 18. pp. 67-70. ISSN 1976-4251 E-ISSN 2233-4998 http://carbonlett.org/PublishedPaper/year_eachList.asp?page_url=Current_Issues 10.5714/CL.2016.18.067
repository_type Digital Repository
institution_category Local University
institution International Islamic University Malaysia
building IIUM Repository
collection Online Access
language English
English
topic T Technology (General)
spellingShingle T Technology (General)
Rana, Masud
M Razib, M Asyraf
Saleh, Tanveer
Asan Gani, Abdul Muthalif
Enhancement of reflectance of densified vertically aligned carbon nanotube forests
description Vertically aligned carbon nanotubes (VACNTs), also known as a carbon nanotube (CNT) forest, are a porous material that is well known for its exceptional optical absorbance property. The reflectance from a VACNT forest has been reported to be as low as 0.045% [1,2]. It is known as the darkest material on Earth. Because of its remarkable material properties, it has various other applications as gas sensors [3], pressure sensors [4], temperature sensors [5], and strain sensors [6]. Recently, various efforts have been made to mechanically manipulate the vertical structure of the nanotubes in the CNT forest and to conduct their optical characterization [7,8]. Optical reflection from bare VACNTs has also been investigated at different wavelengths by Wąsik et al. [9]. Controlled densification by wetting of the CNT forest is another post processing technique that has been reported by other researchers [10]. A densification process is necessary to make the CNT forest useful as a future electronics interconnect [10]. However, no study has been done so far on the optical behavior of CNT forests densified by a wetting process. In this letter, for the first time, we investigate and explain the nature of the optical reflectance of densified VACNTs. Fig. 1 illustrates how the CNT forest is able to absorb most incident light. It was reported elsewhere that VACNT arrays are highly porous [11]. As a result, when incident light enters the bare CNT forest, it goes through several internal reflection-absorption cycles via individual nanotubes and finally makes its way out of the CNT forest as shown in Fig. 1b. Hence, a very low amount of light bounces back (approximately 0.045%) [1,2]. Mathematically, a simple model can be developed to estimate the final amount of light coming out of a CNT forest after several internal reflections; this process is explained by eq (1):
format Article
author Rana, Masud
M Razib, M Asyraf
Saleh, Tanveer
Asan Gani, Abdul Muthalif
author_facet Rana, Masud
M Razib, M Asyraf
Saleh, Tanveer
Asan Gani, Abdul Muthalif
author_sort Rana, Masud
title Enhancement of reflectance of densified vertically aligned carbon nanotube forests
title_short Enhancement of reflectance of densified vertically aligned carbon nanotube forests
title_full Enhancement of reflectance of densified vertically aligned carbon nanotube forests
title_fullStr Enhancement of reflectance of densified vertically aligned carbon nanotube forests
title_full_unstemmed Enhancement of reflectance of densified vertically aligned carbon nanotube forests
title_sort enhancement of reflectance of densified vertically aligned carbon nanotube forests
publisher Korean Carbon Society
publishDate 2016
url http://irep.iium.edu.my/50573/
http://irep.iium.edu.my/50573/
http://irep.iium.edu.my/50573/
http://irep.iium.edu.my/50573/1/%5B67-70%5D-11.pdf
http://irep.iium.edu.my/50573/4/50573-Enhancement%20of%20reflectance%20of%20densified%20vertically%20aligned%20carbon%20nanotube%20forests_SCOPUS.pdf
first_indexed 2023-09-18T21:11:29Z
last_indexed 2023-09-18T21:11:29Z
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