Synthesis, characterization and structural studies of sodium morpholine-4-Carbodithioate and its metal complexes

Synthesis, characterization and structural studies of sodium morpholine-4-Carbodithioate and its metal complexes

Sodium morpholine-4-carbodithioate and four metal complexes were synthesized and characterized using various physico-chemical techniques. The ligand behaved as a uninegatively charged bidentate ligands upon complexation with metal ions with the general formula of Ma(SS)2 and Mb(SS)3, where Ma is Cu(...

Full description

Bibliographic Details
Main Authors: How, Fiona Ni Foong, Ahmad, J., Abdul Halim, S. Nadiah
Format: Conference or Workshop Item
Language:English
Published: 2015
Subjects:
QD Chemistry
Online Access:http://irep.iium.edu.my/46445/
http://irep.iium.edu.my/46445/
http://irep.iium.edu.my/46445/1/46445.pdf
id iium-46445
recordtype eprints
spelling iium-464452016-04-13T04:16:54Z http://irep.iium.edu.my/46445/ Synthesis, characterization and structural studies of sodium morpholine-4-Carbodithioate and its metal complexes How, Fiona Ni Foong Ahmad, J. Abdul Halim, S. Nadiah QD Chemistry Sodium morpholine-4-carbodithioate and four metal complexes were synthesized and characterized using various physico-chemical techniques. The ligand behaved as a uninegatively charged bidentate ligands upon complexation with metal ions with the general formula of Ma(SS)2 and Mb(SS)3, where Ma is Cu(II) and Ni(II) and Mb is Co(III) and Fe(III). All the complexes have crystallographic data for structural comparison. Crystal structure of Iron and cobalt complexes existed in an octahedral coordination geometry with trapped lattice solvent. Nickel and copper complexes crystallized in square planar coordination geometry with no trapped solvent. The PXRD of all the complexes showed that the calculated PXRD data are coincide from the crystal structures of all the metal complexes. 2015 Conference or Workshop Item NonPeerReviewed application/pdf en http://irep.iium.edu.my/46445/1/46445.pdf How, Fiona Ni Foong and Ahmad, J. and Abdul Halim, S. Nadiah (2015) Synthesis, characterization and structural studies of sodium morpholine-4-Carbodithioate and its metal complexes. In: 28th Regional Symposium Malaysian Analytical Sciences (SKAm28), 17-20 August 2015, Weil Hotel, Ipoh, Perak. (Unpublished) http://www.rgscnet.com/news_content.php?id=8
repository_type Digital Repository
institution_category Local University
institution International Islamic University Malaysia
building IIUM Repository
collection Online Access
language English
topic QD Chemistry
spellingShingle QD Chemistry
How, Fiona Ni Foong
Ahmad, J.
Abdul Halim, S. Nadiah
Synthesis, characterization and structural studies of sodium morpholine-4-Carbodithioate and its metal complexes
description Sodium morpholine-4-carbodithioate and four metal complexes were synthesized and characterized using various physico-chemical techniques. The ligand behaved as a uninegatively charged bidentate ligands upon complexation with metal ions with the general formula of Ma(SS)2 and Mb(SS)3, where Ma is Cu(II) and Ni(II) and Mb is Co(III) and Fe(III). All the complexes have crystallographic data for structural comparison. Crystal structure of Iron and cobalt complexes existed in an octahedral coordination geometry with trapped lattice solvent. Nickel and copper complexes crystallized in square planar coordination geometry with no trapped solvent. The PXRD of all the complexes showed that the calculated PXRD data are coincide from the crystal structures of all the metal complexes.
format Conference or Workshop Item
author How, Fiona Ni Foong
Ahmad, J.
Abdul Halim, S. Nadiah
author_facet How, Fiona Ni Foong
Ahmad, J.
Abdul Halim, S. Nadiah
author_sort How, Fiona Ni Foong
title Synthesis, characterization and structural studies of sodium morpholine-4-Carbodithioate and its metal complexes
title_short Synthesis, characterization and structural studies of sodium morpholine-4-Carbodithioate and its metal complexes
title_full Synthesis, characterization and structural studies of sodium morpholine-4-Carbodithioate and its metal complexes
title_fullStr Synthesis, characterization and structural studies of sodium morpholine-4-Carbodithioate and its metal complexes
title_full_unstemmed Synthesis, characterization and structural studies of sodium morpholine-4-Carbodithioate and its metal complexes
title_sort synthesis, characterization and structural studies of sodium morpholine-4-carbodithioate and its metal complexes
publishDate 2015
url http://irep.iium.edu.my/46445/
http://irep.iium.edu.my/46445/
http://irep.iium.edu.my/46445/1/46445.pdf
first_indexed 2023-09-18T21:06:08Z
last_indexed 2023-09-18T21:06:08Z
_version_ 1777410945865220096

Similar Items