S-Quinolin-2-ylmethyldithiocarbazate
In the title compound, C11H11N2S2, there is an intramolecular N—H...N [2.778(2) Angstrom] hydrogen bond linking the quinoline N atom and the imino N atom. The planar quinoline ring system forms an angle of 67.7(1)deg with the dithiocarbazate group. Bond angles for both S—C—S [115.66 (8)deg] and N—C—...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2007
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| Subjects: | |
| Online Access: | http://irep.iium.edu.my/44882/ http://irep.iium.edu.my/44882/ http://irep.iium.edu.my/44882/ http://irep.iium.edu.my/44882/1/SQ2MDTC_%5BActa_Cryst._E63%2C_o3137-o3138%5D.pdf |
| Summary: | In the title compound, C11H11N2S2, there is an intramolecular N—H...N [2.778(2) Angstrom] hydrogen bond linking the quinoline N atom and the imino N atom. The planar quinoline ring system forms an angle of 67.7(1)deg with the dithiocarbazate group. Bond angles for both S—C—S [115.66 (8)deg] and N—C—S [119.05 (11)deg] are comparable with cis–trans S-methyldithiocarbazate but differ from those found in trans–cis S-methyldithiocarbazate and trans–cis S-benzyldithiocarbazate. This is due to the N—H..N hydrogen bond that exists only in the cis–trans conformation found for the title compound. |
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