Phosphoric acid activated carbon as borderline and soft metal ions scavenger

Three activated carbons have been prepared, two from oil-palm shell and one from coconut shell, by the phosphoric acid activation process. Adsorption isotherms of copper(II) were determined to evaluate and compare the performance of experimental carbons. The obtained data are fitted very well to L...

Full description

Bibliographic Details
Main Authors:	Rahman, Md. Mokhlesur, Shamsudin, Siti Hadijah, Miskon, Mohd Fuad, Yunus, Kamaruzzaman, Mohd Yusof, Alias
Format:	Article
Language:	English
Published:	Taylor & Francis 2015
Subjects:	QD Chemistry
Online Access:	http://irep.iium.edu.my/44644/ http://irep.iium.edu.my/44644/ http://irep.iium.edu.my/44644/ http://irep.iium.edu.my/44644/1/Green_chemistry_letters_and_reviews_2015.pdf

id	iium-44644
recordtype	eprints
spelling	iium-446442019-04-09T09:47:31Z http://irep.iium.edu.my/44644/ Phosphoric acid activated carbon as borderline and soft metal ions scavenger Rahman, Md. Mokhlesur Shamsudin, Siti Hadijah Miskon, Mohd Fuad Yunus, Kamaruzzaman Mohd Yusof, Alias QD Chemistry Three activated carbons have been prepared, two from oil-palm shell and one from coconut shell, by the phosphoric acid activation process. Adsorption isotherms of copper(II) were determined to evaluate and compare the performance of experimental carbons. The obtained data are fitted very well to Langmuir and Freundlich adsorption models. All prepared activated carbons show 4–7-fold high adsorption capacity (qmax 19.5–23/18.6– 21 mg g−1) than that of the commercial ones (qmax 5.6/2.9 mg g−1) under the conducted experimental conditions. The mechanism of adsorption was evaluated from the competitive adsorption of copper(II) and calcium(II) in a binary solution depending on their behaviour as Lewis acid and assessed as inner-sphere complexation. The competitive adsorption of copper(II) with other borderline and soft metal ions was evaluated by the best scavenger using a solution of ternary solute of copper(II), nickel(II) and lead(II). The adsorption selectivity order is determined as follows: Pb > Cu≫Ni. Taylor & Francis 2015-09-04 Article PeerReviewed application/pdf en http://irep.iium.edu.my/44644/1/Green_chemistry_letters_and_reviews_2015.pdf Rahman, Md. Mokhlesur and Shamsudin, Siti Hadijah and Miskon, Mohd Fuad and Yunus, Kamaruzzaman and Mohd Yusof, Alias (2015) Phosphoric acid activated carbon as borderline and soft metal ions scavenger. Green Chemistry Letters and Reviews, 8 (2). pp. 9-20. ISSN 1751-7192 (O), 1751-8253 (P) http://www.tandfonline.com/doi/full/10.1080/17518253.2015.1058974 10.1080/17518253.2015.1058974
repository_type	Digital Repository
institution_category	Local University
institution	International Islamic University Malaysia
building	IIUM Repository
collection	Online Access
language	English
topic	QD Chemistry
spellingShingle	QD Chemistry Rahman, Md. Mokhlesur Shamsudin, Siti Hadijah Miskon, Mohd Fuad Yunus, Kamaruzzaman Mohd Yusof, Alias Phosphoric acid activated carbon as borderline and soft metal ions scavenger
description	Three activated carbons have been prepared, two from oil-palm shell and one from coconut shell, by the phosphoric acid activation process. Adsorption isotherms of copper(II) were determined to evaluate and compare the performance of experimental carbons. The obtained data are fitted very well to Langmuir and Freundlich adsorption models. All prepared activated carbons show 4–7-fold high adsorption capacity (qmax 19.5–23/18.6– 21 mg g−1) than that of the commercial ones (qmax 5.6/2.9 mg g−1) under the conducted experimental conditions. The mechanism of adsorption was evaluated from the competitive adsorption of copper(II) and calcium(II) in a binary solution depending on their behaviour as Lewis acid and assessed as inner-sphere complexation. The competitive adsorption of copper(II) with other borderline and soft metal ions was evaluated by the best scavenger using a solution of ternary solute of copper(II), nickel(II) and lead(II). The adsorption selectivity order is determined as follows: Pb > Cu≫Ni.
format	Article
author	Rahman, Md. Mokhlesur Shamsudin, Siti Hadijah Miskon, Mohd Fuad Yunus, Kamaruzzaman Mohd Yusof, Alias
author_facet	Rahman, Md. Mokhlesur Shamsudin, Siti Hadijah Miskon, Mohd Fuad Yunus, Kamaruzzaman Mohd Yusof, Alias
author_sort	Rahman, Md. Mokhlesur
title	Phosphoric acid activated carbon as borderline and soft metal ions scavenger
title_short	Phosphoric acid activated carbon as borderline and soft metal ions scavenger
title_full	Phosphoric acid activated carbon as borderline and soft metal ions scavenger
title_fullStr	Phosphoric acid activated carbon as borderline and soft metal ions scavenger
title_full_unstemmed	Phosphoric acid activated carbon as borderline and soft metal ions scavenger
title_sort	phosphoric acid activated carbon as borderline and soft metal ions scavenger
publisher	Taylor & Francis
publishDate	2015
url	http://irep.iium.edu.my/44644/ http://irep.iium.edu.my/44644/ http://irep.iium.edu.my/44644/ http://irep.iium.edu.my/44644/1/Green_chemistry_letters_and_reviews_2015.pdf
first_indexed	2023-09-18T21:03:27Z
last_indexed	2023-09-18T21:03:27Z
_version_	1777410776748785664

Phosphoric acid activated carbon as borderline and soft metal ions scavenger

Similar Items