Crystal structure of benzyltriphenylphosphonium chloride monohydrate

The title compound, Ph3(PhCH2)P+ Cl-·H2O, was obtained unintentionally as the product of an attempted synthesis of a silver dithiocarbamate complex using benzyltriphenyl- phosphonium as the counter-ion. The asymmetric unit consists of a phosphonium cation and a chloride anion, and a water molecule o...

Full description

Bibliographic Details
Main Authors:	Ahmad, Jimmy, Abdul Halim, Siti Nadiah, How, Fiona Ni Foong
Format:	Article
Language:	English English English
Published:	International Union of Crystallography 2015
Subjects:	QD Chemistry
Online Access:	http://irep.iium.edu.my/43139/ http://irep.iium.edu.my/43139/ http://irep.iium.edu.my/43139/ http://irep.iium.edu.my/43139/1/Acta_E71_o410-o411.pdf http://irep.iium.edu.my/43139/4/43139_Crystal%20structure%20of%20benzyltriphenylphosphonium_SCOPUS.pdf http://irep.iium.edu.my/43139/5/43139_Crystal%20structure%20of%20benzyltriphenylphosphonium_WOS.pdf

id	iium-43139
recordtype	eprints
spelling	iium-431392017-04-10T03:15:33Z http://irep.iium.edu.my/43139/ Crystal structure of benzyltriphenylphosphonium chloride monohydrate Ahmad, Jimmy Abdul Halim, Siti Nadiah How, Fiona Ni Foong QD Chemistry The title compound, Ph3(PhCH2)P+ Cl-·H2O, was obtained unintentionally as the product of an attempted synthesis of a silver dithiocarbamate complex using benzyltriphenyl- phosphonium as the counter-ion. The asymmetric unit consists of a phosphonium cation and a chloride anion, and a water molecule of crystallization. In the crystal, the chloride ion is linked to the water molecule by an O—H·· ·Cl hydrogen bond. The three units are further linked via C—H·· ·Cl and C— H·· ·O hydrogen bonds and C—H··· JT interactions, forming a three-dimensional structure. International Union of Crystallography 2015 Article PeerReviewed application/pdf en http://irep.iium.edu.my/43139/1/Acta_E71_o410-o411.pdf application/pdf en http://irep.iium.edu.my/43139/4/43139_Crystal%20structure%20of%20benzyltriphenylphosphonium_SCOPUS.pdf application/pdf en http://irep.iium.edu.my/43139/5/43139_Crystal%20structure%20of%20benzyltriphenylphosphonium_WOS.pdf Ahmad, Jimmy and Abdul Halim, Siti Nadiah and How, Fiona Ni Foong (2015) Crystal structure of benzyltriphenylphosphonium chloride monohydrate. Acta Crystallographica Section E Structure Reports Online, 71. o410-o411. ISSN 1600-5368 http://scripts.iucr.org/cgi-bin/paper?su5134 10.1107/S2056989015009159
repository_type	Digital Repository
institution_category	Local University
institution	International Islamic University Malaysia
building	IIUM Repository
collection	Online Access
language	English English English
topic	QD Chemistry
spellingShingle	QD Chemistry Ahmad, Jimmy Abdul Halim, Siti Nadiah How, Fiona Ni Foong Crystal structure of benzyltriphenylphosphonium chloride monohydrate
description	The title compound, Ph3(PhCH2)P+ Cl-·H2O, was obtained unintentionally as the product of an attempted synthesis of a silver dithiocarbamate complex using benzyltriphenyl- phosphonium as the counter-ion. The asymmetric unit consists of a phosphonium cation and a chloride anion, and a water molecule of crystallization. In the crystal, the chloride ion is linked to the water molecule by an O—H·· ·Cl hydrogen bond. The three units are further linked via C—H·· ·Cl and C— H·· ·O hydrogen bonds and C—H··· JT interactions, forming a three-dimensional structure.
format	Article
author	Ahmad, Jimmy Abdul Halim, Siti Nadiah How, Fiona Ni Foong
author_facet	Ahmad, Jimmy Abdul Halim, Siti Nadiah How, Fiona Ni Foong
author_sort	Ahmad, Jimmy
title	Crystal structure of benzyltriphenylphosphonium chloride monohydrate
title_short	Crystal structure of benzyltriphenylphosphonium chloride monohydrate
title_full	Crystal structure of benzyltriphenylphosphonium chloride monohydrate
title_fullStr	Crystal structure of benzyltriphenylphosphonium chloride monohydrate
title_full_unstemmed	Crystal structure of benzyltriphenylphosphonium chloride monohydrate
title_sort	crystal structure of benzyltriphenylphosphonium chloride monohydrate
publisher	International Union of Crystallography
publishDate	2015
url	http://irep.iium.edu.my/43139/ http://irep.iium.edu.my/43139/ http://irep.iium.edu.my/43139/ http://irep.iium.edu.my/43139/1/Acta_E71_o410-o411.pdf http://irep.iium.edu.my/43139/4/43139_Crystal%20structure%20of%20benzyltriphenylphosphonium_SCOPUS.pdf http://irep.iium.edu.my/43139/5/43139_Crystal%20structure%20of%20benzyltriphenylphosphonium_WOS.pdf
first_indexed	2023-09-18T21:01:28Z
last_indexed	2023-09-18T21:01:28Z
_version_	1777410651816198144

Crystal structure of benzyltriphenylphosphonium chloride monohydrate

Similar Items