Photochromic behavior of spiropyrans: the effect of substituent

Spiropyrans are among the most promising organic p hotochromic dyes. However, spiropyrans are very sensitive dyes and there are m any independent factors that can affect the performance of these dyes. The effect of substituen t on the optical absorption spectra, fading kinetic, and also the dy...

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Main Authors: Nadir, Najiah, Wahid, Zaharah, Zainuddin, Mat Tarmizi, Mohamed Islam, Noor Zalikha
Format: Article
Language:English
English
Published: Trans Tech Publications, Switzerland 2014
Subjects:
Online Access:http://irep.iium.edu.my/40252/
http://irep.iium.edu.my/40252/1/Photochromic_behavior_of_spiropyrans_The_effect_of__substituent.pdf
http://irep.iium.edu.my/40252/4/40252_Photochromic%20behavior%20of%20spiropyrans.SCOPUS.pdf
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spelling iium-402522017-09-27T03:40:44Z http://irep.iium.edu.my/40252/ Photochromic behavior of spiropyrans: the effect of substituent Nadir, Najiah Wahid, Zaharah Zainuddin, Mat Tarmizi Mohamed Islam, Noor Zalikha TK Electrical engineering. Electronics Nuclear engineering TK452 Electric apparatus and materials. Electric circuits. Electric networks Spiropyrans are among the most promising organic p hotochromic dyes. However, spiropyrans are very sensitive dyes and there are m any independent factors that can affect the performance of these dyes. The effect of substituen t on the optical absorption spectra, fading kinetic, and also the dye stability of spiropyrans in diphenyl ether by UV irradiation has been investigated. The 6-nitro BIPS displayed greater ab sorbance intensity of 0.740% at 600nm compared to 8-ethoxy-6-nitro BIPS of 0.651% at 620n m. Furthermore, 6-nitro BIPS is less stable as it has higher rate constant of 0.1003s -1 and thus lower half-life time (50% decay of the photochromic effect) of 6.9s, in contrast to 8-etho xy-6-nitro BIPS of 0.0594s -1 and 11.7s respectively. Trans Tech Publications, Switzerland 2014 Article PeerReviewed application/pdf en http://irep.iium.edu.my/40252/1/Photochromic_behavior_of_spiropyrans_The_effect_of__substituent.pdf application/pdf en http://irep.iium.edu.my/40252/4/40252_Photochromic%20behavior%20of%20spiropyrans.SCOPUS.pdf Nadir, Najiah and Wahid, Zaharah and Zainuddin, Mat Tarmizi and Mohamed Islam, Noor Zalikha (2014) Photochromic behavior of spiropyrans: the effect of substituent. Advanced Materials Research, 925 (2014). pp. 323-328. ISSN 1022-6680
repository_type Digital Repository
institution_category Local University
institution International Islamic University Malaysia
building IIUM Repository
collection Online Access
language English
English
topic TK Electrical engineering. Electronics Nuclear engineering
TK452 Electric apparatus and materials. Electric circuits. Electric networks
spellingShingle TK Electrical engineering. Electronics Nuclear engineering
TK452 Electric apparatus and materials. Electric circuits. Electric networks
Nadir, Najiah
Wahid, Zaharah
Zainuddin, Mat Tarmizi
Mohamed Islam, Noor Zalikha
Photochromic behavior of spiropyrans: the effect of substituent
description Spiropyrans are among the most promising organic p hotochromic dyes. However, spiropyrans are very sensitive dyes and there are m any independent factors that can affect the performance of these dyes. The effect of substituen t on the optical absorption spectra, fading kinetic, and also the dye stability of spiropyrans in diphenyl ether by UV irradiation has been investigated. The 6-nitro BIPS displayed greater ab sorbance intensity of 0.740% at 600nm compared to 8-ethoxy-6-nitro BIPS of 0.651% at 620n m. Furthermore, 6-nitro BIPS is less stable as it has higher rate constant of 0.1003s -1 and thus lower half-life time (50% decay of the photochromic effect) of 6.9s, in contrast to 8-etho xy-6-nitro BIPS of 0.0594s -1 and 11.7s respectively.
format Article
author Nadir, Najiah
Wahid, Zaharah
Zainuddin, Mat Tarmizi
Mohamed Islam, Noor Zalikha
author_facet Nadir, Najiah
Wahid, Zaharah
Zainuddin, Mat Tarmizi
Mohamed Islam, Noor Zalikha
author_sort Nadir, Najiah
title Photochromic behavior of spiropyrans: the effect of substituent
title_short Photochromic behavior of spiropyrans: the effect of substituent
title_full Photochromic behavior of spiropyrans: the effect of substituent
title_fullStr Photochromic behavior of spiropyrans: the effect of substituent
title_full_unstemmed Photochromic behavior of spiropyrans: the effect of substituent
title_sort photochromic behavior of spiropyrans: the effect of substituent
publisher Trans Tech Publications, Switzerland
publishDate 2014
url http://irep.iium.edu.my/40252/
http://irep.iium.edu.my/40252/1/Photochromic_behavior_of_spiropyrans_The_effect_of__substituent.pdf
http://irep.iium.edu.my/40252/4/40252_Photochromic%20behavior%20of%20spiropyrans.SCOPUS.pdf
first_indexed 2023-09-18T20:57:44Z
last_indexed 2023-09-18T20:57:44Z
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