Photochromic behavior of spiropyrans: the effect of substituent
Spiropyrans are among the most promising organic p hotochromic dyes. However, spiropyrans are very sensitive dyes and there are m any independent factors that can affect the performance of these dyes. The effect of substituen t on the optical absorption spectra, fading kinetic, and also the dy...
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2014
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iium-402522017-09-27T03:40:44Z http://irep.iium.edu.my/40252/ Photochromic behavior of spiropyrans: the effect of substituent Nadir, Najiah Wahid, Zaharah Zainuddin, Mat Tarmizi Mohamed Islam, Noor Zalikha TK Electrical engineering. Electronics Nuclear engineering TK452 Electric apparatus and materials. Electric circuits. Electric networks Spiropyrans are among the most promising organic p hotochromic dyes. However, spiropyrans are very sensitive dyes and there are m any independent factors that can affect the performance of these dyes. The effect of substituen t on the optical absorption spectra, fading kinetic, and also the dye stability of spiropyrans in diphenyl ether by UV irradiation has been investigated. The 6-nitro BIPS displayed greater ab sorbance intensity of 0.740% at 600nm compared to 8-ethoxy-6-nitro BIPS of 0.651% at 620n m. Furthermore, 6-nitro BIPS is less stable as it has higher rate constant of 0.1003s -1 and thus lower half-life time (50% decay of the photochromic effect) of 6.9s, in contrast to 8-etho xy-6-nitro BIPS of 0.0594s -1 and 11.7s respectively. Trans Tech Publications, Switzerland 2014 Article PeerReviewed application/pdf en http://irep.iium.edu.my/40252/1/Photochromic_behavior_of_spiropyrans_The_effect_of__substituent.pdf application/pdf en http://irep.iium.edu.my/40252/4/40252_Photochromic%20behavior%20of%20spiropyrans.SCOPUS.pdf Nadir, Najiah and Wahid, Zaharah and Zainuddin, Mat Tarmizi and Mohamed Islam, Noor Zalikha (2014) Photochromic behavior of spiropyrans: the effect of substituent. Advanced Materials Research, 925 (2014). pp. 323-328. ISSN 1022-6680 |
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TK Electrical engineering. Electronics Nuclear engineering TK452 Electric apparatus and materials. Electric circuits. Electric networks |
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TK Electrical engineering. Electronics Nuclear engineering TK452 Electric apparatus and materials. Electric circuits. Electric networks Nadir, Najiah Wahid, Zaharah Zainuddin, Mat Tarmizi Mohamed Islam, Noor Zalikha Photochromic behavior of spiropyrans: the effect of substituent |
description |
Spiropyrans are among the most promising organic p
hotochromic dyes. However,
spiropyrans are very sensitive dyes and there are m
any independent factors that can affect the
performance of these dyes. The effect of substituen
t on the optical absorption spectra, fading
kinetic, and also the dye stability of spiropyrans
in diphenyl ether by UV irradiation has been
investigated. The 6-nitro BIPS displayed greater ab
sorbance intensity of 0.740% at 600nm
compared to 8-ethoxy-6-nitro BIPS of 0.651% at 620n
m. Furthermore, 6-nitro BIPS is less stable as
it has higher rate constant of 0.1003s
-1
and thus lower half-life time (50% decay of the
photochromic effect) of 6.9s, in contrast to 8-etho
xy-6-nitro BIPS of 0.0594s
-1
and 11.7s
respectively. |
format |
Article |
author |
Nadir, Najiah Wahid, Zaharah Zainuddin, Mat Tarmizi Mohamed Islam, Noor Zalikha |
author_facet |
Nadir, Najiah Wahid, Zaharah Zainuddin, Mat Tarmizi Mohamed Islam, Noor Zalikha |
author_sort |
Nadir, Najiah |
title |
Photochromic behavior of spiropyrans: the effect of
substituent |
title_short |
Photochromic behavior of spiropyrans: the effect of
substituent |
title_full |
Photochromic behavior of spiropyrans: the effect of
substituent |
title_fullStr |
Photochromic behavior of spiropyrans: the effect of
substituent |
title_full_unstemmed |
Photochromic behavior of spiropyrans: the effect of
substituent |
title_sort |
photochromic behavior of spiropyrans: the effect of
substituent |
publisher |
Trans Tech Publications, Switzerland |
publishDate |
2014 |
url |
http://irep.iium.edu.my/40252/ http://irep.iium.edu.my/40252/1/Photochromic_behavior_of_spiropyrans_The_effect_of__substituent.pdf http://irep.iium.edu.my/40252/4/40252_Photochromic%20behavior%20of%20spiropyrans.SCOPUS.pdf |
first_indexed |
2023-09-18T20:57:44Z |
last_indexed |
2023-09-18T20:57:44Z |
_version_ |
1777410417217241088 |