Ionic conductivity of PEMA-LiClO4 polymer electrolytes

Solid polymer electrolytes comprised of various weight percent ratios of poly(ethyl methacrylate) (PEMA) and lithium perchlorate (LiClO4) salt were prepared via solution casting technique using N,N-dimethylformamide (DMF) as the solvent. The conductivity values of the electrolytes were determined vi...

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Main Authors:	Amir, Shahrul, Othman, Raihan, Subban, Ri Hanum Yahaya, Mohamed, Nor Sabirin
Format:	Article
Language:	English
Published:	Penerbit UKM 2011
Subjects:	QC Physics TJ807 Renewable energy sources TK2896 Production of electricity by direct energy conversion TP250 Industrial electrochemistry
Online Access:	http://irep.iium.edu.my/2908/ http://irep.iium.edu.my/2908/ http://irep.iium.edu.my/2908/1/Sains_Malaysiana_S.N._Amir.pdf

id	iium-2908
recordtype	eprints
spelling	iium-29082011-12-27T07:00:42Z http://irep.iium.edu.my/2908/ Ionic conductivity of PEMA-LiClO4 polymer electrolytes Amir, Shahrul Othman, Raihan Subban, Ri Hanum Yahaya Mohamed, Nor Sabirin QC Physics TJ807 Renewable energy sources TK2896 Production of electricity by direct energy conversion TP250 Industrial electrochemistry Solid polymer electrolytes comprised of various weight percent ratios of poly(ethyl methacrylate) (PEMA) and lithium perchlorate (LiClO4) salt were prepared via solution casting technique using N,N-dimethylformamide (DMF) as the solvent. The conductivity values of the electrolytes were determined via impedance spectroscopy. The conductivity of the PEMA-LiClO4 electrolytes increased with increasing salt concentration and the highest conductivity obtained was in the order of 10-6 S cm-1 at salt concentration of 20 wt%. The conductivity decreased for higher salt concentration. In order to understand the conductivity behavior, XRD and dielectric studies were done. The results showed that the conductivity was influenced by the fraction of amorphous region and number of charge carriers in the system. The transference number measurement was also performed on the highest conducting electrolyte systems. The result of the measurement indicated that the systems were ionic conductors. Penerbit UKM 2011-07 Article PeerReviewed application/pdf en cc_by_nc http://irep.iium.edu.my/2908/1/Sains_Malaysiana_S.N._Amir.pdf Amir, Shahrul and Othman, Raihan and Subban, Ri Hanum Yahaya and Mohamed, Nor Sabirin (2011) Ionic conductivity of PEMA-LiClO4 polymer electrolytes. Sains Malaysiana, 40 (7). pp. 701-705. ISSN 0126-6039 http://www.ukm.my/jsm/
repository_type	Digital Repository
institution_category	Local University
institution	International Islamic University Malaysia
building	IIUM Repository
collection	Online Access
language	English
topic	QC Physics TJ807 Renewable energy sources TK2896 Production of electricity by direct energy conversion TP250 Industrial electrochemistry
spellingShingle	QC Physics TJ807 Renewable energy sources TK2896 Production of electricity by direct energy conversion TP250 Industrial electrochemistry Amir, Shahrul Othman, Raihan Subban, Ri Hanum Yahaya Mohamed, Nor Sabirin Ionic conductivity of PEMA-LiClO4 polymer electrolytes
description	Solid polymer electrolytes comprised of various weight percent ratios of poly(ethyl methacrylate) (PEMA) and lithium perchlorate (LiClO4) salt were prepared via solution casting technique using N,N-dimethylformamide (DMF) as the solvent. The conductivity values of the electrolytes were determined via impedance spectroscopy. The conductivity of the PEMA-LiClO4 electrolytes increased with increasing salt concentration and the highest conductivity obtained was in the order of 10-6 S cm-1 at salt concentration of 20 wt%. The conductivity decreased for higher salt concentration. In order to understand the conductivity behavior, XRD and dielectric studies were done. The results showed that the conductivity was influenced by the fraction of amorphous region and number of charge carriers in the system. The transference number measurement was also performed on the highest conducting electrolyte systems. The result of the measurement indicated that the systems were ionic conductors.
format	Article
author	Amir, Shahrul Othman, Raihan Subban, Ri Hanum Yahaya Mohamed, Nor Sabirin
author_facet	Amir, Shahrul Othman, Raihan Subban, Ri Hanum Yahaya Mohamed, Nor Sabirin
author_sort	Amir, Shahrul
title	Ionic conductivity of PEMA-LiClO4 polymer electrolytes
title_short	Ionic conductivity of PEMA-LiClO4 polymer electrolytes
title_full	Ionic conductivity of PEMA-LiClO4 polymer electrolytes
title_fullStr	Ionic conductivity of PEMA-LiClO4 polymer electrolytes
title_full_unstemmed	Ionic conductivity of PEMA-LiClO4 polymer electrolytes
title_sort	ionic conductivity of pema-liclo4 polymer electrolytes
publisher	Penerbit UKM
publishDate	2011
url	http://irep.iium.edu.my/2908/ http://irep.iium.edu.my/2908/ http://irep.iium.edu.my/2908/1/Sains_Malaysiana_S.N._Amir.pdf
first_indexed	2023-09-18T20:10:35Z
last_indexed	2023-09-18T20:10:35Z
_version_	1777407450841874432

Ionic conductivity of PEMA-LiClO4 polymer electrolytes

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