Porosity development in activated carbon from palm kernel and coconut shell by chemical activation method

Several series of activated carbons have been prepared by chemical activation with phosphoric acid from palm kernel and coconut shells to study the effect of preparation variables such as precursor, precursor size, pretreatment, impregnation condition and ratio and finally the carbonization temperat...

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Main Authors: Rahman, Md. Mokhlesur, Adil, Mohammad, Yusof, Alias Mohd
Format: Article
Language:English
Published: Research Journal of Chemistry and Environment 2012
Subjects:
Online Access:http://irep.iium.edu.my/27411/
http://irep.iium.edu.my/27411/
http://irep.iium.edu.my/27411/1/Research_Journal_Chem_and_Environment_%28AC--_December-2012%29.pdf
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spelling iium-274112013-04-01T12:06:15Z http://irep.iium.edu.my/27411/ Porosity development in activated carbon from palm kernel and coconut shell by chemical activation method Rahman, Md. Mokhlesur Adil, Mohammad Yusof, Alias Mohd QD Chemistry Several series of activated carbons have been prepared by chemical activation with phosphoric acid from palm kernel and coconut shells to study the effect of preparation variables such as precursor, precursor size, pretreatment, impregnation condition and ratio and finally the carbonization temperature on specific surface area and pore distribution of the resulting active carbon. Both precursors showed similar N2 adsorption isotherms, an upward deviation at high relative pressure, revealing the presence of mesorpores when carbonized at 5000 C with H3PO4. The bigger hysteresis loop indicates higher mesoporosity in coconut shell derived carbon whereas palm kernel shell derived carbon showed a higher macroporosity nature Prolong sinking of the precursor in H3PO4 impregnation solution followed by carbonization at moderate temperature (450-500 0C) produces carbon of high surface area with a higher macroporosity. The lowering of precursor size favors micropore development and semi-drying of the impregnation chemical prior to carbonization diminishes the macroporosity to a great extent. Thus an appropriate choice of preparation variables enables us to produce high surface area of micro and mesoporous activated carbon. Research Journal of Chemistry and Environment 2012-12-10 Article PeerReviewed application/pdf en http://irep.iium.edu.my/27411/1/Research_Journal_Chem_and_Environment_%28AC--_December-2012%29.pdf Rahman, Md. Mokhlesur and Adil, Mohammad and Yusof, Alias Mohd (2012) Porosity development in activated carbon from palm kernel and coconut shell by chemical activation method. Research Journal of Chemistry and Environment, 16 (4). pp. 189-191. ISSN 0972-0626 http://www.chemenviron.net/Contents.php
repository_type Digital Repository
institution_category Local University
institution International Islamic University Malaysia
building IIUM Repository
collection Online Access
language English
topic QD Chemistry
spellingShingle QD Chemistry
Rahman, Md. Mokhlesur
Adil, Mohammad
Yusof, Alias Mohd
Porosity development in activated carbon from palm kernel and coconut shell by chemical activation method
description Several series of activated carbons have been prepared by chemical activation with phosphoric acid from palm kernel and coconut shells to study the effect of preparation variables such as precursor, precursor size, pretreatment, impregnation condition and ratio and finally the carbonization temperature on specific surface area and pore distribution of the resulting active carbon. Both precursors showed similar N2 adsorption isotherms, an upward deviation at high relative pressure, revealing the presence of mesorpores when carbonized at 5000 C with H3PO4. The bigger hysteresis loop indicates higher mesoporosity in coconut shell derived carbon whereas palm kernel shell derived carbon showed a higher macroporosity nature Prolong sinking of the precursor in H3PO4 impregnation solution followed by carbonization at moderate temperature (450-500 0C) produces carbon of high surface area with a higher macroporosity. The lowering of precursor size favors micropore development and semi-drying of the impregnation chemical prior to carbonization diminishes the macroporosity to a great extent. Thus an appropriate choice of preparation variables enables us to produce high surface area of micro and mesoporous activated carbon.
format Article
author Rahman, Md. Mokhlesur
Adil, Mohammad
Yusof, Alias Mohd
author_facet Rahman, Md. Mokhlesur
Adil, Mohammad
Yusof, Alias Mohd
author_sort Rahman, Md. Mokhlesur
title Porosity development in activated carbon from palm kernel and coconut shell by chemical activation method
title_short Porosity development in activated carbon from palm kernel and coconut shell by chemical activation method
title_full Porosity development in activated carbon from palm kernel and coconut shell by chemical activation method
title_fullStr Porosity development in activated carbon from palm kernel and coconut shell by chemical activation method
title_full_unstemmed Porosity development in activated carbon from palm kernel and coconut shell by chemical activation method
title_sort porosity development in activated carbon from palm kernel and coconut shell by chemical activation method
publisher Research Journal of Chemistry and Environment
publishDate 2012
url http://irep.iium.edu.my/27411/
http://irep.iium.edu.my/27411/
http://irep.iium.edu.my/27411/1/Research_Journal_Chem_and_Environment_%28AC--_December-2012%29.pdf
first_indexed 2023-09-18T20:40:44Z
last_indexed 2023-09-18T20:40:44Z
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