1-(Biphenyl-4-ylcarbonyl)-3-(2-chloro-4-nitrophenyl)thiourea
The benzene rings of the biphenyl group in the title compound, C20H14ClN3O3S, are nearly coplanar [maximum deviation = 0.20 (3) Å]. The mean plane of the biphenyl group forms a dihedral angle of 5.24 (7)° with the aromatic ring of the nitrochlorobenzene group. Intramolecular N-HCl, N-HO and C-HS hyd...
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International Union of Crystallography
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iium-253752012-08-08T01:39:06Z http://irep.iium.edu.my/25375/ 1-(Biphenyl-4-ylcarbonyl)-3-(2-chloro-4-nitrophenyl)thiourea Mohd Yusof , Mohd Sukeri Mohd Yamin, Bohari Ngah, Nurziana QD Chemistry The benzene rings of the biphenyl group in the title compound, C20H14ClN3O3S, are nearly coplanar [maximum deviation = 0.20 (3) Å]. The mean plane of the biphenyl group forms a dihedral angle of 5.24 (7)° with the aromatic ring of the nitrochlorobenzene group. Intramolecular N-HCl, N-HO and C-HS hydrogen bonds stabilize the cis-trans conformation of the molecule. In the crystal, molecules are linked by C-HO and C-HS hydrogen bonds into mutually interwoven corrugated layers parallel to (10-2). International Union of Crystallography 2012 Article PeerReviewed application/pdf en http://irep.iium.edu.my/25375/1/sendreprint_rz2737_baru154.pdf Mohd Yusof , Mohd Sukeri and Mohd Yamin, Bohari and Ngah, Nurziana (2012) 1-(Biphenyl-4-ylcarbonyl)-3-(2-chloro-4-nitrophenyl)thiourea. Acta Crystallographica Section E Structure Reports Online, E68 (5). o1485. ISSN 1600-5368 http://journals.iucr.org/e/issues/2012/05/00/rz2737/index.html 10.1107/S1600536812016686 |
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QD Chemistry Mohd Yusof , Mohd Sukeri Mohd Yamin, Bohari Ngah, Nurziana 1-(Biphenyl-4-ylcarbonyl)-3-(2-chloro-4-nitrophenyl)thiourea |
description |
The benzene rings of the biphenyl group in the title compound, C20H14ClN3O3S, are nearly coplanar [maximum deviation = 0.20 (3) Å]. The mean plane of the biphenyl group forms a dihedral angle of 5.24 (7)° with the aromatic ring of the nitrochlorobenzene group. Intramolecular N-HCl, N-HO and C-HS hydrogen bonds stabilize the cis-trans conformation of the molecule. In the crystal, molecules are linked by C-HO and C-HS hydrogen bonds into mutually interwoven corrugated layers parallel to (10-2). |
format |
Article |
author |
Mohd Yusof , Mohd Sukeri Mohd Yamin, Bohari Ngah, Nurziana |
author_facet |
Mohd Yusof , Mohd Sukeri Mohd Yamin, Bohari Ngah, Nurziana |
author_sort |
Mohd Yusof , Mohd Sukeri |
title |
1-(Biphenyl-4-ylcarbonyl)-3-(2-chloro-4-nitrophenyl)thiourea |
title_short |
1-(Biphenyl-4-ylcarbonyl)-3-(2-chloro-4-nitrophenyl)thiourea |
title_full |
1-(Biphenyl-4-ylcarbonyl)-3-(2-chloro-4-nitrophenyl)thiourea |
title_fullStr |
1-(Biphenyl-4-ylcarbonyl)-3-(2-chloro-4-nitrophenyl)thiourea |
title_full_unstemmed |
1-(Biphenyl-4-ylcarbonyl)-3-(2-chloro-4-nitrophenyl)thiourea |
title_sort |
1-(biphenyl-4-ylcarbonyl)-3-(2-chloro-4-nitrophenyl)thiourea |
publisher |
International Union of Crystallography |
publishDate |
2012 |
url |
http://irep.iium.edu.my/25375/ http://irep.iium.edu.my/25375/ http://irep.iium.edu.my/25375/ http://irep.iium.edu.my/25375/1/sendreprint_rz2737_baru154.pdf |
first_indexed |
2023-09-18T20:37:54Z |
last_indexed |
2023-09-18T20:37:54Z |
_version_ |
1777409168888561664 |