Electron beam crosslinked natural rubber/multiwalled carbon nanotube nanocomposite
The physical properties of the rubber blends are influenced by vulcanization and filler distribution. Normally, rubbers are vulcanized by systems based on sulfur or peroxide with the most common filler carbon black. Radiation can also produce crosslink densities like those obtained by sulphur cu...
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iium-230912013-06-19T01:29:59Z http://irep.iium.edu.my/23091/ Electron beam crosslinked natural rubber/multiwalled carbon nanotube nanocomposite Khalid, Mohammad Ismail, Ahmad Faris Yusof, Faridah Ratnam, Chantara Thevy Walvekar , Rashmi Gangasa Al-Khatib, Ma An Fahmi Rashid TP248.13 Biotechnology The physical properties of the rubber blends are influenced by vulcanization and filler distribution. Normally, rubbers are vulcanized by systems based on sulfur or peroxide with the most common filler carbon black. Radiation can also produce crosslink densities like those obtained by sulphur curing, but the net effects, are similar, though not identical. The type of crosslink formed in this method (–C–C–) give rise to better mechanical properties at higher temperature. This work reports on the investigations carried out on natural rubber (SMR) filled with the multiwall carbon nanotubes (MWCNTs). This system of SMR/MWCNTs was subjected to different radiation dosages and compared with nonradiated samples in order to determine the improvement in mechanical properties of the rubber system in the presence of MWCNTs and irradiation dosages. The amount of MWCNTs in this study was varied from 1 to 7 Phr and the irradiation doses were varied from 50 to 200 KGy. Mechanical properties, especially, tensile strength (TS), elongation at break had been studied as a function of irradiation dose and degree of loading with MWCNTs. Gel fraction indicated an increase in the degree of crosslink with the increase in the MWCT and radiation dosage. XRD was carried out to check the increase in the crytallinty of the nanocomposite system. The overall results obtained indicate significant improvement in the mechanical and thermal properties by radiation crosslinking in presence of MWCNTs. These results were further supported by TEM micrograph and nanoindentation. 2010 Conference or Workshop Item PeerReviewed application/pdf en http://irep.iium.edu.my/23091/1/pp184.pdf Khalid, Mohammad and Ismail, Ahmad Faris and Yusof, Faridah and Ratnam, Chantara Thevy and Walvekar , Rashmi Gangasa and Al-Khatib, Ma An Fahmi Rashid (2010) Electron beam crosslinked natural rubber/multiwalled carbon nanotube nanocomposite. In: IIUM Research, Innovation & Invention Exhibition (IRIIE 2010), 26 - 27 January 2010, Kuala Lumpur. http://www.iium.edu.my/irie/10/ |
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TP248.13 Biotechnology |
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TP248.13 Biotechnology Khalid, Mohammad Ismail, Ahmad Faris Yusof, Faridah Ratnam, Chantara Thevy Walvekar , Rashmi Gangasa Al-Khatib, Ma An Fahmi Rashid Electron beam crosslinked natural rubber/multiwalled carbon nanotube nanocomposite |
description |
The physical properties of the rubber blends are influenced by vulcanization and filler distribution.
Normally, rubbers are vulcanized by systems based on sulfur or peroxide with the most common filler
carbon black. Radiation can also produce crosslink densities like those obtained by sulphur curing, but the
net effects, are similar, though not identical. The type of crosslink formed in this method (–C–C–) give
rise to better mechanical properties at higher temperature. This work reports on the investigations carried
out on natural rubber (SMR) filled with the multiwall carbon nanotubes (MWCNTs). This system of
SMR/MWCNTs was subjected to different radiation dosages and compared with nonradiated samples in
order to determine the improvement in mechanical properties of the rubber system in the presence of
MWCNTs and irradiation dosages. The amount of MWCNTs in this study was varied from 1 to 7 Phr
and the irradiation doses were varied from 50 to 200 KGy. Mechanical properties, especially, tensile
strength (TS), elongation at break had been studied as a function of irradiation dose and degree of loading
with MWCNTs. Gel fraction indicated an increase in the degree of crosslink with the increase in the
MWCT and radiation dosage. XRD was carried out to check the increase in the crytallinty of the
nanocomposite system. The overall results obtained indicate significant improvement in the mechanical
and thermal properties by radiation crosslinking in presence of MWCNTs. These results were further
supported by TEM micrograph and nanoindentation. |
format |
Conference or Workshop Item |
author |
Khalid, Mohammad Ismail, Ahmad Faris Yusof, Faridah Ratnam, Chantara Thevy Walvekar , Rashmi Gangasa Al-Khatib, Ma An Fahmi Rashid |
author_facet |
Khalid, Mohammad Ismail, Ahmad Faris Yusof, Faridah Ratnam, Chantara Thevy Walvekar , Rashmi Gangasa Al-Khatib, Ma An Fahmi Rashid |
author_sort |
Khalid, Mohammad |
title |
Electron beam crosslinked natural rubber/multiwalled carbon nanotube nanocomposite |
title_short |
Electron beam crosslinked natural rubber/multiwalled carbon nanotube nanocomposite |
title_full |
Electron beam crosslinked natural rubber/multiwalled carbon nanotube nanocomposite |
title_fullStr |
Electron beam crosslinked natural rubber/multiwalled carbon nanotube nanocomposite |
title_full_unstemmed |
Electron beam crosslinked natural rubber/multiwalled carbon nanotube nanocomposite |
title_sort |
electron beam crosslinked natural rubber/multiwalled carbon nanotube nanocomposite |
publishDate |
2010 |
url |
http://irep.iium.edu.my/23091/ http://irep.iium.edu.my/23091/ http://irep.iium.edu.my/23091/1/pp184.pdf |
first_indexed |
2023-09-18T20:35:00Z |
last_indexed |
2023-09-18T20:35:00Z |
_version_ |
1777408986682753024 |