Cyclization vs. Cyclization/Dimerization in o-Amidostilbene Radical Cation Cascade Reactions: the Amide question

The n-butyramido, isobutyramido, benzamido, and furancarboxamido functions profoundly modulate the electronics of the stilbene olefinic and NH groups and the corresponding radical cations in ways that influence the efficiency of the cyclization due presumably to conformational and stereoelectronic...

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Main Authors:	Chin , Hui Kee, Ariffin, Azhar, Awang , Khalijah, Ibrahim Ali , Noorbatcha, Takeya, Koichi, Morita, Hiroshi, Chuan , Gee Lim, Thomas, Noel Francis
Format:	Article
Language:	English
Published:	MDPI 2011
Subjects:	QD Chemistry
Online Access:	http://irep.iium.edu.my/2047/ http://irep.iium.edu.my/2047/ http://irep.iium.edu.my/2047/ http://irep.iium.edu.my/2047/1/molecules-16-07267.pdf

id	iium-2047
recordtype	eprints
spelling	iium-20472012-05-06T09:56:01Z http://irep.iium.edu.my/2047/ Cyclization vs. Cyclization/Dimerization in o-Amidostilbene Radical Cation Cascade Reactions: the Amide question Chin , Hui Kee Ariffin, Azhar Awang , Khalijah Ibrahim Ali , Noorbatcha Takeya, Koichi Morita, Hiroshi Chuan , Gee Lim Thomas, Noel Francis QD Chemistry The n-butyramido, isobutyramido, benzamido, and furancarboxamido functions profoundly modulate the electronics of the stilbene olefinic and NH groups and the corresponding radical cations in ways that influence the efficiency of the cyclization due presumably to conformational and stereoelectronic factors. For example, isobutyramidostilbene undergoes FeCl3 promoted cyclization to produce only indoline, while n-butyramidostilbene, under the same conditions, produces both indoline and bisindoline. Keywords: stilbene; indoline; bisindoline; FeCl3 MDPI 2011-08-25 Article PeerReviewed application/pdf en http://irep.iium.edu.my/2047/1/molecules-16-07267.pdf Chin , Hui Kee and Ariffin, Azhar and Awang , Khalijah and Ibrahim Ali , Noorbatcha and Takeya, Koichi and Morita, Hiroshi and Chuan , Gee Lim and Thomas, Noel Francis (2011) Cyclization vs. Cyclization/Dimerization in o-Amidostilbene Radical Cation Cascade Reactions: the Amide question. Molecules , 16 (9). pp. 7267-7287. ISSN 1420-3049 http://www.mdpi.com/1420-3049/16/9/7267 DOI:10.3390/molecules16097267
repository_type	Digital Repository
institution_category	Local University
institution	International Islamic University Malaysia
building	IIUM Repository
collection	Online Access
language	English
topic	QD Chemistry
spellingShingle	QD Chemistry Chin , Hui Kee Ariffin, Azhar Awang , Khalijah Ibrahim Ali , Noorbatcha Takeya, Koichi Morita, Hiroshi Chuan , Gee Lim Thomas, Noel Francis Cyclization vs. Cyclization/Dimerization in o-Amidostilbene Radical Cation Cascade Reactions: the Amide question
description	The n-butyramido, isobutyramido, benzamido, and furancarboxamido functions profoundly modulate the electronics of the stilbene olefinic and NH groups and the corresponding radical cations in ways that influence the efficiency of the cyclization due presumably to conformational and stereoelectronic factors. For example, isobutyramidostilbene undergoes FeCl3 promoted cyclization to produce only indoline, while n-butyramidostilbene, under the same conditions, produces both indoline and bisindoline. Keywords: stilbene; indoline; bisindoline; FeCl3
format	Article
author	Chin , Hui Kee Ariffin, Azhar Awang , Khalijah Ibrahim Ali , Noorbatcha Takeya, Koichi Morita, Hiroshi Chuan , Gee Lim Thomas, Noel Francis
author_facet	Chin , Hui Kee Ariffin, Azhar Awang , Khalijah Ibrahim Ali , Noorbatcha Takeya, Koichi Morita, Hiroshi Chuan , Gee Lim Thomas, Noel Francis
author_sort	Chin , Hui Kee
title	Cyclization vs. Cyclization/Dimerization in o-Amidostilbene Radical Cation Cascade Reactions: the Amide question
title_short	Cyclization vs. Cyclization/Dimerization in o-Amidostilbene Radical Cation Cascade Reactions: the Amide question
title_full	Cyclization vs. Cyclization/Dimerization in o-Amidostilbene Radical Cation Cascade Reactions: the Amide question
title_fullStr	Cyclization vs. Cyclization/Dimerization in o-Amidostilbene Radical Cation Cascade Reactions: the Amide question
title_full_unstemmed	Cyclization vs. Cyclization/Dimerization in o-Amidostilbene Radical Cation Cascade Reactions: the Amide question
title_sort	cyclization vs. cyclization/dimerization in o-amidostilbene radical cation cascade reactions: the amide question
publisher	MDPI
publishDate	2011
url	http://irep.iium.edu.my/2047/ http://irep.iium.edu.my/2047/ http://irep.iium.edu.my/2047/ http://irep.iium.edu.my/2047/1/molecules-16-07267.pdf
first_indexed	2023-09-18T20:09:34Z
last_indexed	2023-09-18T20:09:34Z
_version_	1777407386698383360

Cyclization vs. Cyclization/Dimerization in o-Amidostilbene Radical Cation Cascade Reactions: the Amide question

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