Effects of polar cosolvents on cocoa butter extraction using supercritical carbon dioxide

Cocoa butter was successfully extracted from cocoa liquor by supercritical carbondi oxide (SC-CO2) at 35 MPa, 60 oC and 2 mL/min with 5%, 15% and 25% cosolvents. The extraction yield of tryglicerides (TG) and fatty acid (FA) compositions were significantly influenced by the concentration of polar c...

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Main Authors: Asep, E. K., Jinap, Selamat, Jahurul, Md. Haque Akanda, Sarker, Md. Zaidul Islam, Singh, H.
Format: Article
Language:English
Published: ACS Publications 2013
Subjects:
Online Access:http://irep.iium.edu.my/17980/
http://irep.iium.edu.my/17980/
http://irep.iium.edu.my/17980/
http://irep.iium.edu.my/17980/1/effects_of_polar.pdf
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spelling iium-179802016-12-15T07:30:48Z http://irep.iium.edu.my/17980/ Effects of polar cosolvents on cocoa butter extraction using supercritical carbon dioxide Asep, E. K. Jinap, Selamat Jahurul, Md. Haque Akanda Sarker, Md. Zaidul Islam Singh, H. QD Chemistry Cocoa butter was successfully extracted from cocoa liquor by supercritical carbondi oxide (SC-CO2) at 35 MPa, 60 oC and 2 mL/min with 5%, 15% and 25% cosolvents. The extraction yield of tryglicerides (TG) and fatty acid (FA) compositions were significantly influenced by the concentration of polar cosolvents. The SC-CO2 extraction efficiency was increased with cosolvent significantly. Ethanol was found to be the best cosolvent for cocoa butter extraction using SC-CO2 followed by isopropanol and acetone. The triglycerides of POP, POS and SOS were contained in the extracted cocoa butter with POS being the major component. Where palmitic, stearic and oleic were the main fatty acids in the cocoa butter samples, with stearic being the highest component. The lower molecular weight (MW) of TGs and FAs showed the higher selectivity compared to the high MW of TGs and FAs. Thus, they were fractionated during the first stage of SC-CO2 process. ACS Publications 2013 Article PeerReviewed application/pdf en http://irep.iium.edu.my/17980/1/effects_of_polar.pdf Asep, E. K. and Jinap, Selamat and Jahurul, Md. Haque Akanda and Sarker, Md. Zaidul Islam and Singh, H. (2013) Effects of polar cosolvents on cocoa butter extraction using supercritical carbon dioxide. Innovative Food Science & Emerging Technologies, 20. pp. 152-160. ISSN 1466-8564 (Unpublished) http://pubs.acs.org/action/showLargeCover?issue=362308336 jf-2012-00464b
repository_type Digital Repository
institution_category Local University
institution International Islamic University Malaysia
building IIUM Repository
collection Online Access
language English
topic QD Chemistry
spellingShingle QD Chemistry
Asep, E. K.
Jinap, Selamat
Jahurul, Md. Haque Akanda
Sarker, Md. Zaidul Islam
Singh, H.
Effects of polar cosolvents on cocoa butter extraction using supercritical carbon dioxide
description Cocoa butter was successfully extracted from cocoa liquor by supercritical carbondi oxide (SC-CO2) at 35 MPa, 60 oC and 2 mL/min with 5%, 15% and 25% cosolvents. The extraction yield of tryglicerides (TG) and fatty acid (FA) compositions were significantly influenced by the concentration of polar cosolvents. The SC-CO2 extraction efficiency was increased with cosolvent significantly. Ethanol was found to be the best cosolvent for cocoa butter extraction using SC-CO2 followed by isopropanol and acetone. The triglycerides of POP, POS and SOS were contained in the extracted cocoa butter with POS being the major component. Where palmitic, stearic and oleic were the main fatty acids in the cocoa butter samples, with stearic being the highest component. The lower molecular weight (MW) of TGs and FAs showed the higher selectivity compared to the high MW of TGs and FAs. Thus, they were fractionated during the first stage of SC-CO2 process.
format Article
author Asep, E. K.
Jinap, Selamat
Jahurul, Md. Haque Akanda
Sarker, Md. Zaidul Islam
Singh, H.
author_facet Asep, E. K.
Jinap, Selamat
Jahurul, Md. Haque Akanda
Sarker, Md. Zaidul Islam
Singh, H.
author_sort Asep, E. K.
title Effects of polar cosolvents on cocoa butter extraction using supercritical carbon dioxide
title_short Effects of polar cosolvents on cocoa butter extraction using supercritical carbon dioxide
title_full Effects of polar cosolvents on cocoa butter extraction using supercritical carbon dioxide
title_fullStr Effects of polar cosolvents on cocoa butter extraction using supercritical carbon dioxide
title_full_unstemmed Effects of polar cosolvents on cocoa butter extraction using supercritical carbon dioxide
title_sort effects of polar cosolvents on cocoa butter extraction using supercritical carbon dioxide
publisher ACS Publications
publishDate 2013
url http://irep.iium.edu.my/17980/
http://irep.iium.edu.my/17980/
http://irep.iium.edu.my/17980/
http://irep.iium.edu.my/17980/1/effects_of_polar.pdf
first_indexed 2023-09-18T20:27:01Z
last_indexed 2023-09-18T20:27:01Z
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