6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate
The title compound, C22H20N2O4·2CHCl3, a new Schiff base compound, lies across a crystallographic inversion centre. An intramolecular O-HN hydrogen bond generates a six-membered ring, producing an S(6) ring motif. Intermolecular bifurcated C-HO hydrogen bonds involving the two O atoms of the Schiff...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009
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| Subjects: | |
| Online Access: | http://irep.iium.edu.my/12809/ http://irep.iium.edu.my/12809/ http://irep.iium.edu.my/12809/ http://irep.iium.edu.my/12809/1/6_6_dimethoxy_2_p_phenylenebis.pdf |
| Summary: | The title compound, C22H20N2O4·2CHCl3, a new Schiff base compound, lies across a crystallographic inversion centre. An intramolecular O-HN hydrogen bond generates a six-membered ring, producing an S(6) ring motif. Intermolecular bifurcated C-HO hydrogen bonds involving the two O atoms of the Schiff base ligand and the H atom of the chloroform solvent of crystallization, generate an R21(5) ring motif. The crystal structure is stabilized by intermolecular C-H and - interactions [centroid to centroid distance = 3.6158 (10) Å]. In the crystal structure, molecules are stacked down the c axis. |
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