2-[1-(2-hydroxy-3-methoxybenzyl)-1H-benzimidazol-2-yl]-6-methoxyphenol monohydrate

2-[1-(2-hydroxy-3-methoxybenzyl)-1H-benzimidazol-2-yl]-6-methoxyphenol monohydrate

The asymmetric unit of the title compound, C22H20N2O4·H2O, comprises a substituted benzimidazole molecule and a water molecule of crystallization. The dihedral angles between the benzimidazole ring system and the two outer benzene rings are 16.54 (4) and 86.13 (4)°. The dihedral angle between the tw...

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Main Authors: Al-Douh, Mohammed Hadi, Osman, Hasnah, Abd Hamid, Shafida, Kia, Reza, Fun, Hoong-Kun
Format: Article
Language:English
Published: International Union of Crystallography 2009
Subjects:
QD Chemistry
Online Access:http://irep.iium.edu.my/10409/
http://irep.iium.edu.my/10409/
http://irep.iium.edu.my/10409/
http://irep.iium.edu.my/10409/1/lh2793.pdf
id iium-10409
recordtype eprints
spelling iium-104092018-09-20T02:03:51Z http://irep.iium.edu.my/10409/ 2-[1-(2-hydroxy-3-methoxybenzyl)-1H-benzimidazol-2-yl]-6-methoxyphenol monohydrate Al-Douh, Mohammed Hadi Osman, Hasnah Abd Hamid, Shafida Kia, Reza Fun, Hoong-Kun QD Chemistry The asymmetric unit of the title compound, C22H20N2O4·H2O, comprises a substituted benzimidazole molecule and a water molecule of crystallization. The dihedral angles between the benzimidazole ring system and the two outer benzene rings are 16.54 (4) and 86.13 (4)°. The dihedral angle between the two hydroxy-substituted benzene rings is 82.20 (5)°. In the crystal structure, intermolecular O-H...O hydrogen bonds, involving the hydroxy groups and water molecules, form R44(8) ring motifs, and link symmetry-related molecules into extended chains along the c axis. The crystal structure is further stabilized by weak intermolecular C-H...O hydrogen bonds, weak C-H...[pi] and [pi]-[pi] stacking [centroid-centroid = 3.6495 (6)-3.7130 (6) Å] interactions. Intramolecular O-H...O and O-H...N interactions are also present. International Union of Crystallography 2009 Article PeerReviewed application/pdf en http://irep.iium.edu.my/10409/1/lh2793.pdf Al-Douh, Mohammed Hadi and Osman, Hasnah and Abd Hamid, Shafida and Kia, Reza and Fun, Hoong-Kun (2009) 2-[1-(2-hydroxy-3-methoxybenzyl)-1H-benzimidazol-2-yl]-6-methoxyphenol monohydrate. Acta Crystallographica Section E Structure Reports Online, E65 (4). o913-o914. ISSN 1600-5368 http://journals.iucr.org/e/issues/2009/04/00/issconts.html 10.1107/S1600536809010769
repository_type Digital Repository
institution_category Local University
institution International Islamic University Malaysia
building IIUM Repository
collection Online Access
language English
topic QD Chemistry
spellingShingle QD Chemistry
Al-Douh, Mohammed Hadi
Osman, Hasnah
Abd Hamid, Shafida
Kia, Reza
Fun, Hoong-Kun
2-[1-(2-hydroxy-3-methoxybenzyl)-1H-benzimidazol-2-yl]-6-methoxyphenol monohydrate
description The asymmetric unit of the title compound, C22H20N2O4·H2O, comprises a substituted benzimidazole molecule and a water molecule of crystallization. The dihedral angles between the benzimidazole ring system and the two outer benzene rings are 16.54 (4) and 86.13 (4)°. The dihedral angle between the two hydroxy-substituted benzene rings is 82.20 (5)°. In the crystal structure, intermolecular O-H...O hydrogen bonds, involving the hydroxy groups and water molecules, form R44(8) ring motifs, and link symmetry-related molecules into extended chains along the c axis. The crystal structure is further stabilized by weak intermolecular C-H...O hydrogen bonds, weak C-H...[pi] and [pi]-[pi] stacking [centroid-centroid = 3.6495 (6)-3.7130 (6) Å] interactions. Intramolecular O-H...O and O-H...N interactions are also present.
format Article
author Al-Douh, Mohammed Hadi
Osman, Hasnah
Abd Hamid, Shafida
Kia, Reza
Fun, Hoong-Kun
author_facet Al-Douh, Mohammed Hadi
Osman, Hasnah
Abd Hamid, Shafida
Kia, Reza
Fun, Hoong-Kun
author_sort Al-Douh, Mohammed Hadi
title 2-[1-(2-hydroxy-3-methoxybenzyl)-1H-benzimidazol-2-yl]-6-methoxyphenol monohydrate
title_short 2-[1-(2-hydroxy-3-methoxybenzyl)-1H-benzimidazol-2-yl]-6-methoxyphenol monohydrate
title_full 2-[1-(2-hydroxy-3-methoxybenzyl)-1H-benzimidazol-2-yl]-6-methoxyphenol monohydrate
title_fullStr 2-[1-(2-hydroxy-3-methoxybenzyl)-1H-benzimidazol-2-yl]-6-methoxyphenol monohydrate
title_full_unstemmed 2-[1-(2-hydroxy-3-methoxybenzyl)-1H-benzimidazol-2-yl]-6-methoxyphenol monohydrate
title_sort 2-[1-(2-hydroxy-3-methoxybenzyl)-1h-benzimidazol-2-yl]-6-methoxyphenol monohydrate
publisher International Union of Crystallography
publishDate 2009
url http://irep.iium.edu.my/10409/
http://irep.iium.edu.my/10409/
http://irep.iium.edu.my/10409/
http://irep.iium.edu.my/10409/1/lh2793.pdf
first_indexed 2023-09-18T20:19:51Z
last_indexed 2023-09-18T20:19:51Z
_version_ 1777408033675018240

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